scholarly journals Processible nanomaterials with high conductivity and magnetizability. Preparation and properties of maghemite/polyaniline nanocomposite films

2000 ◽  
Vol 72 (1-2) ◽  
pp. 157-162 ◽  
Author(s):  
Ben Zhong Tang ◽  
Yanhou Geng ◽  
Qunhui Sun ◽  
Xi Xiang Zhang ◽  
Xiabin Jing

A versatile process employing anionic surfactants has been developed for the preparation of processible nanocomposite films with electrical conductivity and magnetic susceptibility. Maghemite (γFe2O3) nanoclusters (~10 nm in size) are coated with 4-dodecyl-benzenesulfonic acid, and polyaniline (PAn) chains are doped with 10-camphorsulfonic acid. The coated nanoclusters and doped polymers are soluble in common solvents, and casting the solutions readily gives free-standing nanocomposite films with nanocluster contents as high as ~50 wt %. The γFe2O3/PAn nanocomposites show high conductivity (82–237 S cm -1 ) and magnetizability (up to ~35 emu/g γFe2O3).

1993 ◽  
Vol 318 ◽  
Author(s):  
F. A. Modine ◽  
D. Lubben ◽  
J. B. Bates

ABSTRACTThin films of pure CaF2 and nanocomposite mixtures of Al2O3 with CaF2 were sublimated on Al2O3 substrates. Interdigital electrodes allowed in situ measurements of the electrical conduction of films as a function of thickness, deposition rate, composition, time, and temperature. The electrical conductivity in pure CaF2 adjacent to an Al2O3 interface sometimes exceeded the bulk CaF2 conductivity (i.e., value at more than 50 nm distance) by as much as a factor of 6700 at 200°C. The high conductivity is characterized by an activation energy of 0.6 ± 0.1 eV, which is significantly lower than the activation energy of about 1.0 eV for conduction in the bulk. However, this high conductivity is thermally unstable and diminishes in time. A high but stable conductivity was obtained in CaF2 films containing about 10 mole percent Al2O3 as a dispersed second phase. At 200°C, a 2-phase film gave a factor of 360 enhancement over the measured bulk CaF2 conductivity and a factor of 7 improvement over the best previously reported conductivity for CaF2-Al203 composite materials. The origin of enhanced conduction in CaF2 is attributed to ion transport along dislocations. Dislocations anneal with a characteristic log of time dependence that is recognizable in the annealing behavior of the electrical conductivity. Presumably, the addition of a dispersed second phase of Al2O3 to CaF2 serves both to generate and to pin dislocations; the electrical conductance is thereby enhanced and stabilized.


Agriculture ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 114
Author(s):  
Katarzyna Pentoś ◽  
Krzysztof Pieczarka ◽  
Kamil Serwata

Soil spatial variability mapping allows the delimitation of the number of soil samples investigated to describe agricultural areas; it is crucial in precision agriculture. Electrical soil parameters are promising factors for the delimitation of management zones. One of the soil parameters that affects yield is soil compaction. The objective of this work was to indicate electrical parameters useful for the delimitation of management zones connected with soil compaction. For this purpose, the measurement of apparent soil electrical conductivity and magnetic susceptibility was conducted at two depths: 0.5 and 1 m. Soil compaction was measured for a soil layer at 0–0.5 m. Relationships between electrical soil parameters and soil compaction were modelled with the use of two types of neural networks—multilayer perceptron (MLP) and radial basis function (RBF). Better prediction quality was observed for RBF models. It can be stated that in the mathematical model, the apparent soil electrical conductivity affects soil compaction significantly more than magnetic susceptibility. However, magnetic susceptibility gives additional information about soil properties, and therefore, both electrical parameters should be used simultaneously for the delimitation of management zones.


RSC Advances ◽  
2015 ◽  
Vol 5 (94) ◽  
pp. 76783-76787 ◽  
Author(s):  
H. L. Wang ◽  
X. K. Ning ◽  
Z. J. Wang

Au–LaNiO3 (Au–LNO) nanocomposite films with 3.84 at% Au were firstly fabricated by one-step chemical solution deposition (CSD), and their electrical properties were investigated.


2019 ◽  
Vol 832 ◽  
pp. 55-58 ◽  
Author(s):  
Kensaku Kanomata ◽  
Takafumi Deguchi ◽  
Teng Ma ◽  
Takumi Haseyama ◽  
Masanori Miura ◽  
...  

2001 ◽  
Vol 11 (4) ◽  
pp. 1133-1140 ◽  
Author(s):  
Ralf Müllmann ◽  
Uta Ernet ◽  
Bernd D. Mosel ◽  
Hellmut Eckert ◽  
Reinhard K. Kremer ◽  
...  

Author(s):  
Н.П. Степанов ◽  
В.Ю. Наливкин ◽  
А.К. Гильфанов ◽  
А.А. Калашников ◽  
Е.Н. Трубицына

Solid solutions Bi2Te3-Sb2Te3 continue to be the subject of numerous and versatile experimental studies due to their practical importance for thermoelectric materials science. In this regard, the problem of studying the regularities of changes in the state of the electronic system of these semiconductors from composition and temperature remains urgent. This paper presents the results of studying the temperature dependences of the magnetic susceptibility of Bi2Te3-Sb2Te3 crystals containing 10, 25, 40, 50, 60 mol. % Sb2Te3. The correlation of the behavior of the temperature dependences of the magnetic susceptibility and electrical conductivity is analyzed.


2018 ◽  
Vol 67 (8) ◽  
pp. 1118-1127
Author(s):  
Dejan P Kepić ◽  
Ivan S Ristić ◽  
Milena T Marinović-Cincović ◽  
Davor B Peruško ◽  
Zdenko Špitálsky ◽  
...  

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