Critical evaluation of stability constants for alpha-hydroxycarboxylic acid complexes with protons and metal ions and the accompanying enthalpy changesPart I: Aromatic ortho-hydroxycarboxylic acids (Technical Report)

1997 ◽  
Vol 69 (2) ◽  
pp. 329-382 ◽  
Author(s):  
L. H. J. Lajunen ◽  
R. Portanova ◽  
J. Piispanen ◽  
M. Tolazzi
Keyword(s):  
Metal Ions ◽  
Stability Constants ◽  
Critical Evaluation ◽  
Hydroxycarboxylic Acid ◽  
Hydroxycarboxylic Acids ◽  
Technical Report

Critical evaluation of stability constants for alpha-hydroxycarboxylic acid complexes with protons and metal ions and the accompanying enthalpy changes. Part II. Aliphatic 2-hydroxycarboxylic acids (IUPAC Technical Report)

2003 ◽  
Vol 75 (4) ◽  
pp. 495-540 ◽  
Author(s):  
R. Portanova ◽  
L. H. J. Lajunen ◽  
M. Tolazzi ◽  
J. Piispanen
Keyword(s):  
Aqueous Solutions ◽  
Metal Ions ◽  
Stability Constants ◽  
Critical Evaluation ◽  
Hydroxycarboxylic Acid ◽  
Enthalpy Changes ◽  
Hydroxycarboxylic Acids ◽  
Technical Report

Stability constants for different aliphatic 2-hydroxycarboxylic acid complexes in aqueous solutions with protons and metal ions published between 1960 and the end of 1994 have been critically evaluated.

Critical evaluation of stability constants and thermodynamic functions of metal complexes of crown ethers (IUPAC Technical Report)

2003 ◽  
Vol 75 (1) ◽  
pp. 71-102 ◽  
Author(s):  
Francoise Arnaud-Neu ◽  
Rita Delgado ◽  
Sílvia Chaves
Keyword(s):  
Metal Ions ◽  
Metal Complexes ◽  
Stability Constants ◽  
Crown Ethers ◽  
Thermodynamic Functions ◽  
Critical Evaluation ◽  
Earth Metal ◽  
Published Data ◽  
Technical Report ◽  
Alkaline Earth Metal Ions

Stability constants and thermodynamic functions of metal complexes of crown ethers in various solvents published between 1971 and the beginning of 2000 have been critically evaluated. The most studied crown ethers have been selected: 1,4,7,10 tetraoxacyclododecane (12C4), 1,4,7,10,13 pentaoxacyclopentadecane (15C5), and 1,4,7,10,13,16 hexaoxacyclooctadecane (18C6). The metal ions chosen are: alkali and alkaline earth metal ions, Ag+, Tl+, Cd2+, and Pb2+. The solvents considered are: water, methanol, ethanol, and their mixtures, as well as acetonitrile, N,N'-dimethylformamide, dimethylsulfoxide, and propylene carbonate. The published data have been examined and grouped into two categories, “accepted” and “rejected”. The “accepted” values were considered as: (i) recommended (R), when the standard deviations (s.d.) on the constant K or on ΔrH were inferior to 0.05 lg unit or inferior to 1 kJ mol−1, respectively; (ii) provisional (P), when s.d. is superior to 0.05 and inferior to 0.2 for lg K or s.d. is superior to 1 and inferior to 2 kJ mol−1 for ΔrH; (iii) recommended 1 (R1), if the values were obtained by a single research group, but were considered reliable in comparison with related systems, and considering that the research team usually presents R-level values for other similar systems.

Critical evaluation of stability constants of phosphonic acids (IUPAC Technical Report)

2002 ◽  
Vol 74 (11) ◽  
pp. 2227 ◽  
Author(s):  
Konstantin Popov ◽  
Hannu Rönkkömäki ◽  
Lauri H. J. Lajunen
Keyword(s):  
Stability Constants ◽  
Critical Evaluation ◽  
Phosphonic Acids ◽  
Technical Report

The following reference citations were incorrect: Page 1643: replace 93SC with 93SK Page 1657: replace H+: 98KK with H+: 98KA Page 1657: replace Cu2+: 98KK with Cu2+: 98KA Page 1668: replace 90S with 90SW Page 1673: replace 68BE with 67BE Page 1666: replace 95WJ J.M. Wagener and N.V. Jarvis. S. Afr. J. Chem. 28, 85 (1995) with 95WJ J.M. Wagener and N.V. Jarvis. S. Afr. J. Chem. 48, 85 (1995) Page 1666: replace 95I with 95IU Page 1668: replace 90K A T. Kiss with 90KA T. Kiss

scholarly journals Critical evaluation of stability constants of metal complexes of complexones for biomedical and environmental applications* (IUPAC Technical Report)

2005 ◽  
Vol 77 (8) ◽  
pp. 1445-1495 ◽  
Author(s):  
Giorgio Anderegg ◽  
Francoise Arnaud-Neu ◽  
Rita Delgado ◽  
Judith Felcman ◽  
Konstantin Popov
Keyword(s):  
Experimental Data ◽  
Stability Constant ◽  
Metal Complexes ◽  
Stability Constants ◽  
Critical Evaluation ◽  
Iminodiacetic Acid ◽  
Quality Data ◽  
Tetraacetic Acid ◽  
Diacetic Acid ◽  
Technical Report

Available experimental data on stability constants of proton (hydron) and metal complexes for seven complexones of particular biomedical and environmental interest: iminodiacetic acid [2,2'-azanediyldiacetic acid, IDA], (methylimino)diacetic acid [2,2'-(methylazanediyl)diacetic acid, MIDA]; 2,2',2'',2'''-{[(carboxymethyl)azanediyl]bis[(ethane-1,2-diyl)nitrilo]}tetraacetic acid (DTPA), 3,6,9,12-tetrakis(carboxymethyl)-3,6,9,12-tetraazatetradecanedioic acid (TTHA); 2,2',2''-(1,4,7-triazonane-1,4,7-triyl)triacetic acid (NOTA); 2,2',2'',2'''-(1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrayl)tetraacetic acid (DOTA); 2,2',2'',2'''-(1,4,8,11-tetraazacyclotetradecane-1,4,8,11-tetrayl)tetraacetic acid (TETA), published in 1945-2000, have been critically evaluated. Some typical errors in stability constant measurements for particular complexones are summarized. Higher quality data are selected and presented as “Recommended” or “Provisional”.

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