ChemInform Abstract: Critical Evaluation of Stability Constants for Metal Complexes in Solution: Critical Evaluation of Stability Constants for α- Hydroxycarboxylic Acid Complexes with Protons and Metal Ions and the Accompanying Enthalpy Changes. Part 1.

ChemInform ◽  
2010 ◽  
Vol 28 (30) ◽  
pp. no-no
Author(s):  
L. H. J. LAJUNEN ◽  
R. PORTANOVA ◽  
J. PIISPANEN ◽  
M. TOLAZZI
Keyword(s):  
Metal Ions ◽  
Metal Complexes ◽  
Stability Constants ◽  
Critical Evaluation ◽  
Hydroxycarboxylic Acid ◽  
Enthalpy Changes

Critical evaluation of stability constants for alpha-hydroxycarboxylic acid complexes with protons and metal ions and the accompanying enthalpy changes. Part II. Aliphatic 2-hydroxycarboxylic acids (IUPAC Technical Report)

2003 ◽  
Vol 75 (4) ◽  
pp. 495-540 ◽  
Author(s):  
R. Portanova ◽  
L. H. J. Lajunen ◽  
M. Tolazzi ◽  
J. Piispanen
Keyword(s):  
Aqueous Solutions ◽  
Metal Ions ◽  
Stability Constants ◽  
Critical Evaluation ◽  
Hydroxycarboxylic Acid ◽  
Enthalpy Changes ◽  
Hydroxycarboxylic Acids ◽  
Technical Report

Stability constants for different aliphatic 2-hydroxycarboxylic acid complexes in aqueous solutions with protons and metal ions published between 1960 and the end of 1994 have been critically evaluated.

Critical evaluation of stability constants and thermodynamic functions of metal complexes of crown ethers (IUPAC Technical Report)

2003 ◽  
Vol 75 (1) ◽  
pp. 71-102 ◽  
Author(s):  
Francoise Arnaud-Neu ◽  
Rita Delgado ◽  
Sílvia Chaves
Keyword(s):  
Metal Ions ◽  
Metal Complexes ◽  
Stability Constants ◽  
Crown Ethers ◽  
Thermodynamic Functions ◽  
Critical Evaluation ◽  
Earth Metal ◽  
Published Data ◽  
Technical Report ◽  
Alkaline Earth Metal Ions

Stability constants and thermodynamic functions of metal complexes of crown ethers in various solvents published between 1971 and the beginning of 2000 have been critically evaluated. The most studied crown ethers have been selected: 1,4,7,10 tetraoxacyclododecane (12C4), 1,4,7,10,13 pentaoxacyclopentadecane (15C5), and 1,4,7,10,13,16 hexaoxacyclooctadecane (18C6). The metal ions chosen are: alkali and alkaline earth metal ions, Ag+, Tl+, Cd2+, and Pb2+. The solvents considered are: water, methanol, ethanol, and their mixtures, as well as acetonitrile, N,N'-dimethylformamide, dimethylsulfoxide, and propylene carbonate. The published data have been examined and grouped into two categories, “accepted” and “rejected”. The “accepted” values were considered as: (i) recommended (R), when the standard deviations (s.d.) on the constant K or on ΔrH were inferior to 0.05 lg unit or inferior to 1 kJ mol−1, respectively; (ii) provisional (P), when s.d. is superior to 0.05 and inferior to 0.2 for lg K or s.d. is superior to 1 and inferior to 2 kJ mol−1 for ΔrH; (iii) recommended 1 (R1), if the values were obtained by a single research group, but were considered reliable in comparison with related systems, and considering that the research team usually presents R-level values for other similar systems.

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