Characterizing Corn and Cattle Manure Derived Biochars Relevant to Their Use as Soil Additives

2018 ◽  
Vol 61 (4) ◽  
pp. 1335-1349 ◽  
Author(s):  
Md S. Borhan ◽  
Shafiqur Rahman ◽  
Niloy Chandra Sarker

Abstract. Biomass-derived biochars have shown potential for improving soil properties as a whole that are conducive to plant growth with reduced environmental pollution. Four types of biomass, namely, corn stover (CS), dried distillers’ grains and solubles (DDGS), dairy manure (DM), and beef feedlot manure (BFM), were transformed to biochar through pyrolysis at 400°C with 1, 2, or 3 h residence time. The biochars were characterized by proximate analysis (volatile matter (VM), ash, and fixed carbon (FC)), ultimate analysis (total carbon (TC), hydrogen (H), nitrogen (N), sulfur (S), and oxygen (O)), and thermogravimetric analysis (pH, electrical conductivity (EC) and bulk density (BD)). Scanning electron microscopy (SEM), energy dispersion spectroscopy (EDXS), and Fourier transform infrared radiation (FTIR) spectroscopy were used to categorize pore size, functional groups, and mineralogical properties related to potential use in environmental remediation. The highest heating value (HV) was measured with CS (28 to 29 MJ kg-1), and the lowest HV was measured with BFM (~5 MJ kg-1). The greatest organic carbon (OC) content was obtained with CS (68%), followed by DDGS (63%), DM (44%), and BFM (15.4%) biochars. The SEM images showed the macrocellular morphology of the original shape of the biomass particles, which consisted mainly of aggregate microspheres 2 to 10 µm in size. The surface functional groups of all four biochars were dominated by hydroxyl, methyl, methylene, aromatic carbonyl/carboxylic, and alkene groups. The CS and DDGS biochars showed higher TC (76%), FC (61%), OC (67%), water holding capacity, and mineral contents and outperformed the DM and BFM biochars as the best soil amendments. Keywords: Beef feedlot manure, Corn stover, Dairy manure, Dried distillers’ grains and solubles.

2020 ◽  
Vol 4 (3) ◽  
Author(s):  
Nicholas A Lancaster ◽  
Chris R Muegge ◽  
Jose R R Carvalho ◽  
Rodrigo C Lopes ◽  
Rafael S Narumiya ◽  
...  

Abstract The objective of this study was to determine the effect of soybean hulls (SBH) and/or calcium oxide (CaO) on rumen pH, digestibility, and performance of steers fed diets containing dried distillers grains with solubles (DDGS). In experiment 1, Angus × Simmental steers (n = 112, body weight [BW] = 364 ± 7.8 kg) were allotted to 1 of 4 diets arranged as a 2 × 2 factorial and placed in 16 pens (7 steers/pen, 4 pens/treatment, and 28 steers/treatment). Factors were SBH (0% or 30% of diet dry matter [DM]) and CaO (0% or 1%) inclusion. Basal diets contained 20% corn stover, 30% DDGS, and 4% supplement. Diets with SBH contained 14.1% or 15.0% corn and diets without SBH contained 43.9% or 44.8% corn. In experiment two, four steers (BW = 510 ± 9.8 kg) were allotted to a 4 × 4 Latin square (21 d periods) to determine the effects of CaO and SBH on ruminal pH, volatile fatty acid (VFA), nutrient digestibility, and digestion kinetics. Statistical analyses were conducted using the MIXED procedure of SAS. In experiment 1, BW did not differ among treatments (P ≥ 0.46). Overall carcass-adjusted gain did not differ due to SBH or CaO inclusion (P ≥ 0.13); however, there was an interaction (P = 0.01) where CaO improved gain in steers fed no SBH, but not in steers fed SBH. Steers fed SBH consumed more DM than steers not fed SBH (P = 0.02) and an interaction tended to occur (P = 0.06) where CaO increased dry matter intake in steers fed no SBH, but not in steers fed SBH. Calcium oxide increased hot carcass weight and yield grade (interaction; P ≤ 0.04) and tended to increase fat thickness (interaction; P = 0.08) in steers fed no SBH, but not in steers fed SBH. Dressing percentage, longissimus muscle area, % kidney, pelvic, heart fat, and marbling score did not differ among treatments (P ≥ 0.14). Total VFA concentrations were greater with SBH inclusion and with CaO addition (P < 0.01). Digestibility of DM, neutral detergent fiber (NDF), and acid detergent fiber (ADF) was greater with CaO addition (P ≤ 0.04) and NDF and ADF digestibility were greater with SBH inclusion (P < 0.001). Inclusion of SBH did not affect (P ≥ 0.26) rate of digestion (kd) or passage (kp). Addition of CaO tended to increase mean retention time (P = 0.09). An interaction between SBH inclusion and CaO addition occurred for kd (P = 0.01), where CaO increased kd in steers fed SBH, but decreased kd when steers were fed no SBH. Total N excretion tended to be lower with SBH inclusion and CaO addition (P = 0.07). In conclusion, CaO enhances performance of cattle fed corn, DDGS, and corn stover diets, but not when corn is partially replaced by a fiber-based energy feed.


2019 ◽  
Vol 3 (4) ◽  
pp. 1296-1314
Author(s):  
Nicholas A Lancaster ◽  
Chris R Muegge ◽  
Jose R Reis de Carvalho ◽  
Rodrigo Cistolo Lopes ◽  
Rafael S Narumiya ◽  
...  

Abstract Three experiments were conducted to determine the effectiveness of calcium hydroxide (Ca(OH)2) addition and roughage inclusion on digestibility, performance, and carcass characteristics of steers fed 60% dried distillers grains with solubles (DGS). Statistical analyses for studies were conducted using the MIXED procedures of SAS. In experiment 1, 48 steers (353.5 ± 7.55 kg) were allotted to individual pens and fed 1 of 3 diets (dry matter [DM] basis) containing 60% dried DGS, 20% corn silage, and 4% supplement with: 1) 14.5% corn and no Ca(OH)2; 2) 14% corn and 2% Ca(OH)2; and 3) 14.5% additional corn silage and no Ca(OH)2. Steers fed Ca(OH)2 consumed the least (P = 0.03) and steers fed added corn silage consumed the most and had the least gain:feed (P = 0.02). Gain and carcass quality were not affected by treatment (P ≥ 0.48). In experiment 2, 112 steers (375.3 ± 19.25 kg) were allotted to pens (four pens per treatment; seven steers per pen) arranged as a 2 × 2 factorial (roughage × Ca(OH)2) and fed one of four diets (DM basis) containing 60% dried DGS, 17% corn silage, and 4% supplement with: 1) 17.5% corn silage and no Ca(OH)2; 2) 17% corn silage and 2% Ca(OH)2; 3) 17.25% corn stover and no Ca(OH)2; and 4) 17% corn stover and 2% Ca(OH)2. Added stover decreased average daily gain (ADG) compared to added corn silage (P = 0.04). Ca(OH)2 increased ADG when steers were fed stover, but not when steers were fed only corn silage (P = 0.05; interaction). In experiment 3, six ruminally cannulated steers (initial body weight = 352 ± 14.8 kg) were randomly allotted to a 6 × 6 Latin square design to determine the effects of roughage inclusion (corn, corn silage, stover) and Ca(OH)2 addition (0% or 2%) on ruminal characteristics. Feeding stover decreased total volatile fatty acid(s) (VFA) concentration and DM digestibility compared to corn silage or corn (P < 0.01), whereas Ca(OH)2 resulted in greater total VFA concentrations and DM digestibility (P ≤ 0.02). Stover increased rate of DM degradation (Kd) and rate of particle outflow from the rumen (P ≤ 0.04) but decreased extent of DM digestion and mean retention time (P ≤ 0.02) compared to corn or silage. Ca(OH)2 increased Kd (P < 0.01) and tended to increase (P = 0.06) liquid passage rate. In conclusion, added roughage did not improve performance of cattle fed 60% dried DGS. Ca(OH)2 may decrease intake and maintain performance of cattle fed 60% dried DGS with corn silage as the roughage source and increases ADG when corn stover replaces a portion of the corn silage.


2021 ◽  
Vol 99 (Supplement_2) ◽  
pp. 12-13
Author(s):  
Jordan Adams ◽  
Rodney Farris ◽  
Scott Clawson ◽  
Earl Ward ◽  
Paul Beck

Abstract We evaluated the effects of supplementing dried distillers’ grains cubes (DDGS) and re-implantation of steers (n = 149; BW = 238 ± 13.8 kg) grazing tall fescue (Festuca arundinacea)/bermudagrass (Cynodon dactylon) pastures (n = 9 pastures, 7.2 ± 2.90 ha) from 14 April to 17 September 2020 (n = 155 d) in a split-plot design on steer performance and forage production. Main plot supplemental treatments (n = 3 pastures/treatment) included 1) Fertilized Control (FC), no supplementation on fertilized pastures (112 kg N/ha); 2) Fertilized Supplement (FS), supplemental DDGS fed at 2.9 kg 3-d/wk on fertilized pastures; and 3) Supplement (S), supplemented DDGS at 0.75% BW/d on unfertilized pastures prorated for 5-d/wk feeding. Steers were previously implanted during receiving with 40 mg trenbolone acetate and 8 mg estradiol (REV-G; Revalor G, Merck Animal Health). On July 7, steers in each pasture were randomly assigned to one of three re-implant treatments: 1) no re-implant; 2) REV-G; or 3) 200 mg progesterone and 20 mg estradiol (Synovex S, Zoetis Animal Health). Steers in FS and S gained more (P < 0.01) than FC throughout the trial and final BW was greater (P < 0.01) for FS and S compared with FC. Unexpectedly, re-implanting had no effect on ADG (P = 0.57) or BW (P = 0.34), but statistical power may be lacking. Supplemental efficiency was greater in the late summer for FS (P = 0.05) compared to S. Fertilizing pastures in FS and FC did not affect biomass (P = 0.39), however, CP was increased (P = 0.01) and acid and neutral detergent fibers tended to decrease (P = 0.06) relative to S in the early summer (April, May, June, and July), but did not differ in late summer (August and September). Based upon our analysis, DDGS is a suitable supplement and can replace N fertilizer for steers grazing introduced pastures.


2020 ◽  
Vol 98 (Supplement_3) ◽  
pp. 128-128
Author(s):  
Hannah Speer ◽  
Hannah Riley ◽  
Robert Cushman ◽  
Harvey Freetly ◽  
Mary Drewnoski

Abstract Spring-born heifers (n = 1,012) weaned at 148 ± 17 d were used in a 3-yr study to evaluate performance in winter development systems which utilized cover crop and corn residue grazing. Heifers were assigned to 1 of 3 treatments: grazing corn residue with dried distillers grains (CD) or wheat midds (CW) supplementation, or grazing late summer planted oat-brassica cover crop followed by corn residue supplemented dried distillers grains (CC). Grazing of corn residue (CD and CW) and cover crop (CC) began in early November. Supplementation during the corn residue phase was adjusted to target ~55% of mature BW (338 kg) at breeding. After 63 d, CC were moved to corn residue; on d 77 CD and CW began receiving grower ration. In mid-February (d 98), heifers were comingled and managed in a single group. Breeding season began in June and lasted for 29 d. Prior to corn residue grazing, ADG of CC was greater (0.76 kg/d; P< 0.01) than CD or CW (0.58 kg/d and 0.49 kg/d, respectively). Gain during the last 35 d of the winter period for CC was 0.13 kg/d less than CW (P< 0.01) but not different from CD. Overall winter ADG was greater (P< 0.05) for CC (0.62 kg/d) than CD (0.53 kg/d) or CW (0.50 kg/d). Percent of mature BW prior to breeding was 52% for CC and 50% for CD and CW. May reproductive tract scores did not differ (P=0.26) between CC and CW but were greater (P< 0.05) in CC than CD. Pregnancy rates were affected by treatment (P< 0.01), with CC (76%) being greater than CD (68%) and CW (64%). Utilizing oat-brassica cover crops early in the winter followed by a lower rate of gain while grazing corn residue appear to be effective for developing beef heifers. USDA is an equal opportunity employer and provider.


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