The One-Pot Three Components of Iodone, Schiff Base and Epoxide for Synthesis of Iodohydrins

2012 ◽  
Vol 28 (2) ◽  
pp. 749-755
Author(s):  
ABOLGHASEM SHAMELI ◽  
ABDOL HAMID RAEISI ◽  
BAHRAM POURHASAN ◽  
HOSSEIN NAEIMI ◽  
MOHAMMAD MEHDI GHANBARI
Keyword(s):  
One Pot ◽  
The One ◽  
2020 ◽  
Vol 44 (7) ◽  
pp. 2986-2995 ◽  
Author(s):  
Lidan Lan ◽  
Fei Liu ◽  
Yi Dan ◽  
Long Jiang

A facile fabrication method was developed for the one-pot synthesis of 1,3,5-triformylbenzene (TFB)-4,4′4′′-triaminotriphenylamine (TPA) and 1,3,5-triformylbenzene-terephthalaldehyde (TA) under ambient conditions via a Schiff-base reaction.


2015 ◽  
Vol 44 (33) ◽  
pp. 14918-14924 ◽  
Author(s):  
Oksana V. Nesterova ◽  
Eduard N. Chygorin ◽  
Vladimir N. Kokozay ◽  
Irina V. Omelchenko ◽  
Oleg V. Shishkin ◽  
...  

An Fe/Mn Schiff base complex with an unprecedented metal core type for a heterometallic compound, has been prepared by the one-pot direct synthesis method and magnetostructurally characterized.


RSC Advances ◽  
2016 ◽  
Vol 6 (94) ◽  
pp. 91999-92006 ◽  
Author(s):  
Milad Kazemnejadi ◽  
Ali Reza Sardarian

A new polymeric Cu(ii) Schiff base complex catalyst is developed, which shows high catalytic activity in the preparation of 5-substituted 1H-tetrazoles under mild and green conditions.


2018 ◽  
Author(s):  
Huong T. D. Nguyen ◽  
Y B. N. Tran ◽  
Hung N. Nguyen ◽  
Tranh C. Nguyen ◽  
Felipe Gándara ◽  
...  

<p>Three novel lanthanide metal˗organic frameworks (Ln-MOFs), namely MOF-590, -591, and -592 were constructed from a naphthalene diimide tetracarboxylic acid. Gas adsorption measurements of MOF-591 and -592 revealed good adsorption of CO<sub>2</sub> (low pressure, at room temperature) and moderate CO<sub>2</sub> selectivity over N<sub>2</sub> and CH<sub>4</sub>. Accordingly, breakthrough measurements were performed on a representative MOF-592, in which the separation of CO<sub>2</sub> from binary mixture containing N<sub>2</sub> and CO<sub>2</sub> was demonstrated without any loss in performance over three consecutive cycles. Moreover, MOF-590, MOF-591, and MOF-592 exhibited catalytic activity in the one-pot synthesis of styrene carbonate from styrene and CO<sub>2</sub> under mild conditions (1 atm CO<sub>2</sub>, 80 °C, and solvent-free). Among the new materials, MOF-590 revealed a remarkable efficiency with exceptional conversion (96%), selectivity (95%), and yield (91%). </p><br>


2020 ◽  
Vol 24 (4) ◽  
pp. 465-471 ◽  
Author(s):  
Zita Rádai ◽  
Réka Szabó ◽  
Áron Szigetvári ◽  
Nóra Zsuzsa Kiss ◽  
Zoltán Mucsi ◽  
...  

The phospha-Brook rearrangement of dialkyl 1-aryl-1-hydroxymethylphosphonates (HPs) to the corresponding benzyl phosphates (BPs) has been elaborated under solid-liquid phase transfer catalytic conditions. The best procedure involved the use of triethylbenzylammonium chloride as the catalyst and Cs2CO3 as the base in acetonitrile as the solvent at room temperature. The substrate dependence of the rearrangement has been studied, and the mechanism of the transformation under discussion was explored by quantum chemical calculations. The key intermediate is an oxaphosphirane. The one-pot version starting with the Pudovik reaction has also been developed. The conditions of this tandem transformation were the same, as those for the one-step HP→BP conversion.


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