scholarly journals Stereochemistry of Radical Polymerization of Vinyl Esters in the Presence of Lewis Acid

2000 ◽  
Vol 32 (8) ◽  
pp. 707-710 ◽  
Author(s):  
Kazunobu Yamada ◽  
Tamaki Nakano ◽  
Yoshio Okamoto
Keyword(s):  
Radical Polymerization ◽  
Lewis Acid ◽  
Vinyl Esters

Efficient Lewis Acid-Catalyzed Stereocontrolled Radical Polymerization of Acrylamides

2001 ◽  
Vol 123 (29) ◽  
pp. 7180-7181 ◽  
Author(s):  
Yutaka Isobe ◽  
Daigo Fujioka ◽  
Shigeki Habaue ◽  
Yoshio Okamoto
Keyword(s):  
Radical Polymerization ◽  
Lewis Acid ◽  
Acid Catalyzed

scholarly journals Mechanistic Investigation of ε-Thiono-Caprolactone Radical Polymerization: An Interesting Tool to Insert Weak Bonds into Poly(vinyl esters)

2021 ◽  
Author(s):  
Christopher M. Plummer ◽  
Noémie Gil ◽  
Pierre-Emmanuel Dufils ◽  
D. James Wilson ◽  
Catherine Lefay ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Vinyl Esters ◽  
Mechanistic Investigation

The Bis(allyl)bismuth Cation: A Reagent for Direct Allyl Transfer by Lewis Acid Activation and Controlled Radical Polymerization

2012 ◽  
Vol 51 (52) ◽  
pp. 13011-13015 ◽  
Author(s):  
Crispin Lichtenberg ◽  
Fangfang Pan ◽  
Thomas P. Spaniol ◽  
Ulli Englert ◽  
Jun Okuda
Keyword(s):  
Radical Polymerization ◽  
Lewis Acid ◽  
Controlled Radical Polymerization ◽  
Acid Activation

Lewis acid-surfactant complex catalyzed polymerization in aqueous dispersed media: cationic or radical polymerization?

2020 ◽  
Vol 11 (36) ◽  
pp. 5757-5766
Author(s):  
Aurélie Destephen ◽  
Luis Lezama ◽  
Nicholas Ballard
Keyword(s):  
Radical Polymerization ◽  
Lewis Acid ◽  
Surfactant Complex ◽  
Dispersed Media ◽  
Aqueous Dispersed Media ◽  
Catalyzed Polymerization

Evidence is presented that shows Lewis acid-surfactant complex catalyzed polymerization proceeds via a radical, not a cationic, mechanism.

Biocompatible Phosphorus-based Monomers for Radical Polymerization

2009 ◽  
Vol 1235 ◽  
Author(s):  
Claudia Dworak ◽  
Christian Heller ◽  
Franz Varga ◽  
Robert Liska
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Radical Polymerization ◽  
Hydrolytic Degradation ◽  
Future Application ◽  
Vinyl Esters ◽  
Degradation Behavior ◽  
Scanning Calorimetry ◽  
Phosphorus Containing

AbstractNovel biocompatible and biodegradable monomers based on phosphorus-containing vinyl esters and vinyl carbamates for radical photopolymerization were prepared. By photo-Differential Scanning Calorimetry (photo-DSC) the reactivity of the mono-, di- and trifunctional monomers was investigated. Furthermore, their cytotoxicity, mechanical properties and hydrolytic degradation behavior were evaluated, aiming at a future application of our compounds in the biomedical area.

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