Asymmetric Polymerization of 1-(3-Pyridyl)dibenzosuberyl Methacrylate and Chiral Recognition by the Obtained Optically Active Polymer Having Single-Handed Helical Conformation
Herein we present the precise design and synthesis of a novel polymer backbone that induces a helical structure through asymmetric polymerization reactions of a phthalimide-based monomer catalyzed by a planar-chiral cyclopentadienyl–ruthenium complex.
Inspired by the skin biofunction of protecting the body from microorganism invasion, artificially manufacturing human skin in vitro with promising antibacterial capability and cell affinity is urgently required in wound...