scholarly journals Mechanistic Studies on the Lipase-Catalyzed Ring-Opening Polymerization of Lactones

1997 ◽  
Vol 29 (3) ◽  
pp. 299-301 ◽  
Author(s):  
Hiroshi Uyama ◽  
Shuhei Namekawa ◽  
Shiro Kobayash
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Mechanistic Studies

Mechanistic Studies on Ring-Opening Polymerization of Benzoxazines: A Mechanistically Based Catalyst Design

2011 ◽  
Vol 44 (12) ◽  
pp. 4616-4622 ◽  
Author(s):  
Chao Liu ◽  
Dongmei Shen ◽  
Rosa María Sebastián ◽  
Jordi Marquet ◽  
Rainer Schönfeld
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Catalyst Design ◽  
Mechanistic Studies

scholarly journals Photocatalyst-Independent Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides: Stereocontrol and Mechanism

2021 ◽  
Author(s):  
Yongliang Zhong ◽  
quanyou feng ◽  
xiaoqian wang ◽  
Lei Yang ◽  
Rong Tong
Keyword(s):  
Molecular Weight ◽  
Ring Opening ◽  
Precious Metal ◽  
Ring Opening Polymerization ◽  
Oxidative Status ◽  
Mechanistic Studies ◽  
Glass Transition Temperatures ◽  
Molecular Weights ◽  
Molecular Weight Distributions ◽  
Weight Distributions

Photoredox ring-opening polymerization of <i>O</i>-carboxyanhydrides allows for the synthesis of polyesters with precisely controlled molecular weights, molecular weight distributions, and tacticities. While powerful, obviating the use of precious metal-based photocatalysts would be attractive from the perspective of simplifying the protocol and enabling unexpected reactivity. Herein, we report the Co and Zn catalysts that are activated by external light to mediate efficient ring-opening polymerization of <i>O</i>-carboxyanhydrides, without the use of exogenous precious metal-based photocatalysts. Our methods allow for the synthesis of isotactic polyesters with high molecular weights (>200 kDa) and narrow molecular weight distributions (<i>M</i><sub>w</sub>/<i>M</i><sub>n</sub> < 1.1). Mechanistic studies indicate that light activates the oxidative status of Co<sup>III</sup> intermediate that is generated from the regioselective ring-opening of the <i>O</i>-carboxyanhydride. We also demonstrate that the use of Zn or Hf complexes together with Co can allow for stereoselective photoredox ring-opening polymerizations of multiple racemic <i>O</i>-carboxyanhydrides to synthesize syndiotactic and stereoblock copolymers, which vary widely in their glass transition temperatures.

scholarly journals Photocatalyst-Independent Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides: Stereocontrol and Mechanism

2021 ◽  
Author(s):  
Yongliang Zhong ◽  
quanyou feng ◽  
xiaoqian wang ◽  
Lei Yang ◽  
Rong Tong
Keyword(s):  
Molecular Weight ◽  
Ring Opening ◽  
Precious Metal ◽  
Ring Opening Polymerization ◽  
Oxidative Status ◽  
Mechanistic Studies ◽  
Glass Transition Temperatures ◽  
Molecular Weights ◽  
Molecular Weight Distributions ◽  
Weight Distributions

Photoredox ring-opening polymerization of <i>O</i>-carboxyanhydrides allows for the synthesis of polyesters with precisely controlled molecular weights, molecular weight distributions, and tacticities. While powerful, obviating the use of precious metal-based photocatalysts would be attractive from the perspective of simplifying the protocol and enabling unexpected reactivity. Herein, we report the Co and Zn catalysts that are activated by external light to mediate efficient ring-opening polymerization of <i>O</i>-carboxyanhydrides, without the use of exogenous precious metal-based photocatalysts. Our methods allow for the synthesis of isotactic polyesters with high molecular weights (>200 kDa) and narrow molecular weight distributions (<i>M</i><sub>w</sub>/<i>M</i><sub>n</sub> < 1.1). Mechanistic studies indicate that light activates the oxidative status of Co<sup>III</sup> intermediate that is generated from the regioselective ring-opening of the <i>O</i>-carboxyanhydride. We also demonstrate that the use of Zn or Hf complexes together with Co can allow for stereoselective photoredox ring-opening polymerizations of multiple racemic <i>O</i>-carboxyanhydrides to synthesize syndiotactic and stereoblock copolymers, which vary widely in their glass transition temperatures.

scholarly journals Photocatalyst-Independent Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides: Stereocontrol and Mechanism

2020 ◽  
Author(s):  
Yongliang Zhong ◽  
quanyou feng ◽  
xiaoqian wang ◽  
Lei Yang ◽  
Rong Tong
Keyword(s):  
Molecular Weight ◽  
Ring Opening ◽  
Precious Metal ◽  
Ring Opening Polymerization ◽  
Oxidative Status ◽  
Mechanistic Studies ◽  
Glass Transition Temperatures ◽  
Molecular Weights ◽  
Molecular Weight Distributions ◽  
Weight Distributions

Photoredox ring-opening polymerization of <i>O</i>-carboxyanhydrides allows for the synthesis of polyesters with precisely controlled molecular weights, molecular weight distributions, and tacticities. While powerful, obviating the use of precious metal-based photocatalysts would be attractive from the perspective of simplifying the protocol and enabling unexpected reactivity. Herein, we report the Co and Zn catalysts that are activated by external light to mediate efficient ring-opening polymerization of <i>O</i>-carboxyanhydrides, without the use of exogenous precious metal-based photocatalysts. Our methods allow for the synthesis of isotactic polyesters with high molecular weights (>200 kDa) and narrow molecular weight distributions (<i>M</i><sub>w</sub>/<i>M</i><sub>n</sub> < 1.1). Mechanistic studies indicate that light activates the oxidative status of Co<sup>III</sup> intermediate that is generated from the regioselective ring-opening of the <i>O</i>-carboxyanhydride. We also demonstrate that the use of Zn or Hf complexes together with Co can allow for stereoselective photoredox ring-opening polymerizations of multiple racemic <i>O</i>-carboxyanhydrides to synthesize syndiotactic and stereoblock copolymers, which vary widely in their glass transition temperatures.

scholarly journals Photocatalyst-Independent Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides: Stereocontrol and Mechanism

2020 ◽  
Author(s):  
Yongliang Zhong ◽  
quanyou feng ◽  
xiaoqian wang ◽  
Lei Yang ◽  
Rong Tong
Keyword(s):  
Molecular Weight ◽  
Ring Opening ◽  
Precious Metal ◽  
Ring Opening Polymerization ◽  
Oxidative Status ◽  
Mechanistic Studies ◽  
Glass Transition Temperatures ◽  
Molecular Weights ◽  
Molecular Weight Distributions ◽  
Weight Distributions

Photoredox ring-opening polymerization of <i>O</i>-carboxyanhydrides allows for the synthesis of polyesters with precisely controlled molecular weights, molecular weight distributions, and tacticities. While powerful, obviating the use of precious metal-based photocatalysts would be attractive from the perspective of simplifying the protocol and enabling unexpected reactivity. Herein, we report the Co and Zn catalysts that are activated by external light to mediate efficient ring-opening polymerization of <i>O</i>-carboxyanhydrides, without the use of exogenous precious metal-based photocatalysts. Our methods allow for the synthesis of isotactic polyesters with high molecular weights (>200 kDa) and narrow molecular weight distributions (<i>M</i><sub>w</sub>/<i>M</i><sub>n</sub> < 1.1). Mechanistic studies indicate that light activates the oxidative status of Co<sup>III</sup> intermediate that is generated from the regioselective ring-opening of the <i>O</i>-carboxyanhydride. We also demonstrate that the use of Zn or Hf complexes together with Co can allow for stereoselective photoredox ring-opening polymerizations of multiple racemic <i>O</i>-carboxyanhydrides to synthesize syndiotactic and stereoblock copolymers, which vary widely in their glass transition temperatures.

A Recommender System for Inverse Design of Polycarbonates and Polyesters

2020 ◽  
Author(s):  
Nathaniel Park ◽  
Dmitry Yu. Zubarev ◽  
James L. Hedrick ◽  
Vivien Kiyek ◽  
Christiaan Corbet ◽  
...  
Keyword(s):  
Ring Opening ◽  
High Performance ◽  
Recommendation System ◽  
Polymeric Materials ◽  
Monomer Conversion ◽  
Design Strategy ◽  
Ring Opening Polymerization ◽  
Inverse Design ◽  
False Negatives ◽  
Accelerate Development

The convergence of artificial intelligence and machine learning with material science holds significant promise to rapidly accelerate development timelines of new high-performance polymeric materials. Within this context, we report an inverse design strategy for polycarbonate and polyester discovery based on a recommendation system that proposes polymerization experiments that are likely to produce materials with targeted properties. Following recommendations of the system driven by the historical ring-opening polymerization results, we carried out experiments targeting specific ranges of monomer conversion and dispersity of the polymers obtained from cyclic lactones and carbonates. The results of the experiments were in close agreement with the recommendation targets with few false negatives or positives obtained for each class.<br>

Bisurea and Bisthiourea H-Bonding Organocatalysts for Ring-Opening Polymerization: Cues for the Catalyst Design

2019 ◽  
Vol 52 (23) ◽  
pp. 9232-9237 ◽  
Author(s):  
Rukshika S. Hewawasam ◽  
U. L. D. Inush Kalana ◽  
Nayanthara U. Dharmaratne ◽  
Thomas J. Wright ◽  
Timothy J. Bannin ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Catalyst Design
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