The Nature of the Active Catalyst in Late Transition Metal-Mediated Ring-Opening Polymerization (ROP) Reactions:  Mechanistic Studies of the Platinum-Catalyzed ROP of Silicon-Bridged [1]Ferrocenophanes

2001 ◽  
Vol 123 (7) ◽  
pp. 1355-1364 ◽  
Author(s):  
Karen Temple ◽  
Frieder Jäkle ◽  
J. B. Sheridan ◽  
Ian Manners
Keyword(s):  
Transition Metal ◽  
Ring Opening ◽  
Active Catalyst ◽  
Ring Opening Polymerization ◽  
Late Transition Metal ◽  
Mechanistic Studies ◽  
Late Transition

Physical insights into mechanistic processes in organometallic chemistry: an introduction

2019 ◽  
Vol 220 ◽  
pp. 10-27 ◽  
Author(s):  
Robert H. Morris
Keyword(s):  
Transition Metal ◽  
Organometallic Chemistry ◽  
Metal Hydride ◽  
Late Transition Metal ◽  
Mechanistic Studies ◽  
Homogeneous Catalysts ◽  
Transition Metal Hydride ◽  
Late Transition

Mechanistic studies of late transition metal hydride homogeneous catalysts – 3d versus 4d metals.

Cationic Late-Transition-Metal Complexes Catalyze the Ring Opening of Aziridines with Amines

Synthesis ◽  
2011 ◽  
Vol 44 (01) ◽  
pp. 27-36 ◽  
Author(s):  
Christoph Schneider ◽  
Alex Marti ◽  
Saravanan Peruncheralathan
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Ring Opening ◽  
Late Transition Metal ◽  
Late Transition

Hydrosilylation as an efficient tool for polymer synthesis and modification with methacrylates

RSC Advances ◽  
2015 ◽  
Vol 5 (8) ◽  
pp. 5879-5885 ◽  
Author(s):  
Nuttapol Risangud ◽  
Zhijian Li ◽  
Athina Anastasaki ◽  
Paul Wilson ◽  
Kristian Kempe ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Polymer Synthesis ◽  
Late Transition Metal ◽  
Efficient Tool ◽  
Silicon Compounds ◽  
Late Transition

Hydrosilylation is a well-established reaction for the preparation of organo-silicon compounds, in which vinyl groups react with silanes (Si–H) usually catalysed by late transition metal complexes, most often Pt(ii) complexes.

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