scholarly journals Efficient Immobilization of Protein on Monodispersed Colloidal Silica Particles Modified by Copolymers of Maleic Anhydride and Styrene or Methyl Methacrylate

1995 ◽  
Vol 27 (1) ◽  
pp. 98-100 ◽  
Author(s):  
Kohji Yoshinaga ◽  
Kimihiko Kondo ◽  
Akihiko Kondo
Keyword(s):  
Maleic Anhydride ◽  
Methyl Methacrylate ◽  
Colloidal Silica ◽  
Silica Particles

Reactions of macroions with ester and carboxylic groups of polymers

1987 ◽  
Vol 52 (9) ◽  
pp. 2194-2203
Author(s):  
Miloslav Kučera ◽  
Dušan Kimmer ◽  
Karla Majerová ◽  
Josef Majer
Keyword(s):  
Maleic Anhydride ◽  
Acrylic Acid ◽  
Methyl Methacrylate ◽  
Bond Formation ◽  
Covalent Bond ◽  
The Other ◽  
Poly Methyl Methacrylate ◽  
Other Hand ◽  
Carboxylic Groups ◽  
Poly Acrylic Acid

In the reaction of dianions with poly(methyl methacrylate), only an insignificant amount of insoluble crosslinked product is obtained. If, however, the concentration of grafting dianions approaches that of ester groups, the amount of poly(methyl methacrylate) which may thus be crosslinked becomes quite significant. Dications, too, can bring about crosslinking of only an insignificant number of poly(methyl methacrylate) chains. Carboxylic groups in poly(acrylic acid) react with dianions and dications in an anhydrous medium similarly to ester groups. On the other hand, in the presence of a cocatalytic amount of water dications are more readily bound to carboxylic groups, forming a covalent bond. The relatively highest efficiency was observed in the bond formation between dication and the poly[styrene-alt-(maleic anhydride)], both in an anhydrous medium and in the presence of H2O.

Colloidal Silica/Poly(Methacrylsiloxane) Nanocomposite Particles: Synthesis, Characterization, and Application in Toners.

2014 ◽  
Vol 1663 ◽  
Author(s):  
Dmitry Fomitchev ◽  
Russell Lewis ◽  
Hairuo Tu ◽  
Li Cheng ◽  
Hajime Kambara ◽  
...  
Keyword(s):  
Particle Size ◽  
Colloidal Silica ◽  
Silica Particles ◽  
Laser Printer ◽  
Mass Ratio ◽  
One Pot ◽  
New Class ◽  
New Material ◽  
Hydrophobic Treatment ◽  
Hydrophobic Material

ABSTRACTWe report on a new class of materials for laser printer toner applications. These materials were prepared from methacrysilane-in-water emulsions stabilized with colloidal silica particles. In this elegant system, the colloidal silica particles reside at the water/oil interface helping to emulsify the oil droplet, self-organizing into a raspberry-like morphology. The emulsion formation is followed by free-radical polymerization, hydrophobic treatment, and drying steps. This one pot synthesis in water affords a hydrophobic material with a particle size in the range of 80 to 300 nm. The particle size could be fine-tuned by changing the oil-to-silica mass ratio or by using colloidal silica particles of different sizes. Results of material characterization by solid-state NMR, electron microscopy, and particle size measurements methods will be presented. Examples of possible extensions of the synthesis towards materials with methacrylsilane partially substituted with other methacrylates will be provided. Application of the new material in toners will be described as will the comparison of its performance with the incumbent material - hydrophobic colloidal silica.

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