scholarly journals Synthesis and Cation-Binding Property of Copolymers with Benzo-19-crown-6 Units via Cationic Cyclocopolymerizations of 1,2-Bis[2-(2-vinyloxyethoxy)ethoxy]-benzene with Phenyl Vinyl Ether, 4-Methoxystyrene, and 9-Vinylcarbazole

1995 ◽  
Vol 27 (8) ◽  
pp. 862-866
Author(s):  
Toyoji Kakuchi ◽  
Toshitaka Watanabe ◽  
Shigeyuki Matsunami ◽  
Osamu Haba ◽  
Yasushi Morimoto ◽  
...  
Keyword(s):  
Vinyl Ether ◽  
Cation Binding ◽  
Binding Property ◽  
Phenyl Vinyl

Carbon−Oxygen Bond Strength in Diphenyl Ether and Phenyl Vinyl Ether:  An Experimental and Computational Study

1997 ◽  
Vol 101 (30) ◽  
pp. 5404-5411 ◽  
Author(s):  
Wibo van Scheppingen ◽  
Edwin Dorrestijn ◽  
Isabel Arends ◽  
Peter Mulder ◽  
Hans-Gert Korth
Keyword(s):  
Bond Strength ◽  
Vinyl Ether ◽  
Computational Study ◽  
Diphenyl Ether ◽  
Oxygen Bond ◽  
Phenyl Vinyl

scholarly journals The phenyl vinyl ether–methanol complex: a model system for quantum chemistry benchmarking

2018 ◽  
Vol 14 ◽  
pp. 1642-1654 ◽  
Author(s):  
Dominic Bernhard ◽  
Fabian Dietrich ◽  
Mariyam Fatima ◽  
Cristóbal Pérez ◽  
Hannes C Gottschalk ◽  
...  
Keyword(s):  
Vinyl Ether ◽  
Quantum Chemical Calculations ◽  
Quantum Chemical ◽  
Noncovalent Interactions ◽  
Cluster Method ◽  
Correct Prediction ◽  
Electronically Excited ◽  
Ether Oxygen ◽  
London Dispersion ◽  
Phenyl Vinyl

The structure of the isolated aggregate of phenyl vinyl ether and methanol is studied by combining a multi-spectroscopic approach and quantum-chemical calculations in order to investigate the delicate interplay of noncovalent interactions. The complementary results of vibrational and rotational spectroscopy applied in molecular beam experiments reveal the preference of a hydrogen bond of the methanol towards the ether oxygen (OH∙∙∙O) over the π-docking motifs via the phenyl and vinyl moieties, with an additional less populated OH∙∙∙P(phenyl)-bound isomer detected only by microwave spectroscopy. The correct prediction of the energetic order of the isomers using quantum-chemical calculations turns out to be challenging and succeeds with a sophisticated local coupled cluster method. The latter also yields a quantification as well as a visualization of London dispersion, which prove to be valuable tools for understanding the role of dispersion on the docking preferences. Beyond the structural analysis of the electronic ground state (S0), the electronically excited (S1) state is analyzed, in which a destabilization of the OH∙∙∙O structure compared to the S0 state is observed experimentally and theoretically.

ChemInform Abstract: SURFACE PHOTOCHEMISTRY: SEMICONDUCTOR-PHOTOINDUCED DIMERIZATION OF PHENYL VINYL ETHER

1985 ◽  
Vol 16 (7) ◽  
Author(s):  
A. M. DRAPER ◽  
M. ILYAS ◽  
P. DE MAYO ◽  
V. RAMAMURTHY
Keyword(s):  
Vinyl Ether ◽  
Phenyl Vinyl

Cyclopolymerization of α,ω-Diepoxide with Monoepoxy Comonomer. Synthesis and Cation-Binding Property Of Copolymers with Dibenz0-19-Cr0Wn-6 Units

1994 ◽  
Vol 31 (6) ◽  
pp. 751-759
Author(s):  
Toyoji Kakuchi ◽  
Hisaho Hashimoto ◽  
Yasuhiro Harada ◽  
Toshifumi Satoh ◽  
Kazuaki Yokota
Keyword(s):  
Cation Binding ◽  
Binding Property

Crowned polyacetylene: 3. Synthesis and cation-binding property of polyphenylacetylene with azacrown cavity by cyclopolymerization of α,ω-bis(4′-ethynylphenoxy)oligooxyethylene containing a pyridyl unit

Polymer ◽  
1997 ◽  
Vol 38 (5) ◽  
pp. 1233-1238 ◽  
Author(s):  
Toyoji Kakuchi ◽  
Toshitaka Watanabe ◽  
Shigeyuki Matsunami ◽  
Hiroyuki Kamimura ◽  
Osamu Haba ◽  
...  
Keyword(s):  
Cation Binding ◽  
Binding Property

ChemInform Abstract: THE STEREOSELECTIVE PHOTOCYCLOADDITION OF INDENE AND PHENYL VINYL ETHER TO ALPHA-NAPHTHONITRILE

1974 ◽  
Vol 5 (13) ◽  
pp. no-no
Author(s):  
C. PAC ◽  
K. MIZUNO ◽  
T. SUGIOKA ◽  
H. SAKURAI
Keyword(s):  
Vinyl Ether ◽  
Phenyl Vinyl

Cyclopolymerization of divinyl ethers. Synthesis and the cation-binding property of poly(crown ethers)

1992 ◽  
Vol 25 (19) ◽  
pp. 4854-4858 ◽  
Author(s):  
Toyoji Kakuchi ◽  
Osamu Haba ◽  
Kazuaki Yokota
Keyword(s):  
Crown Ethers ◽  
Cation Binding ◽  
Binding Property
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