Surface photochemistry: cadmium sulfide-mediated dimerization of phenyl vinyl ether. The dark reaction

1985 ◽  
Vol 107 (18) ◽  
pp. 5093-5099 ◽  
Author(s):  
Mohammad Ilyas ◽  
Paul De Mayo
Keyword(s):  
Cadmium Sulfide ◽  
Vinyl Ether ◽  
Dark Reaction ◽  
Phenyl Vinyl

Carbon−Oxygen Bond Strength in Diphenyl Ether and Phenyl Vinyl Ether:  An Experimental and Computational Study

1997 ◽  
Vol 101 (30) ◽  
pp. 5404-5411 ◽  
Author(s):  
Wibo van Scheppingen ◽  
Edwin Dorrestijn ◽  
Isabel Arends ◽  
Peter Mulder ◽  
Hans-Gert Korth
Keyword(s):  
Bond Strength ◽  
Vinyl Ether ◽  
Computational Study ◽  
Diphenyl Ether ◽  
Oxygen Bond ◽  
Phenyl Vinyl

scholarly journals The phenyl vinyl ether–methanol complex: a model system for quantum chemistry benchmarking

2018 ◽  
Vol 14 ◽  
pp. 1642-1654 ◽  
Author(s):  
Dominic Bernhard ◽  
Fabian Dietrich ◽  
Mariyam Fatima ◽  
Cristóbal Pérez ◽  
Hannes C Gottschalk ◽  
...  
Keyword(s):  
Vinyl Ether ◽  
Quantum Chemical Calculations ◽  
Quantum Chemical ◽  
Noncovalent Interactions ◽  
Cluster Method ◽  
Correct Prediction ◽  
Electronically Excited ◽  
Ether Oxygen ◽  
London Dispersion ◽  
Phenyl Vinyl

The structure of the isolated aggregate of phenyl vinyl ether and methanol is studied by combining a multi-spectroscopic approach and quantum-chemical calculations in order to investigate the delicate interplay of noncovalent interactions. The complementary results of vibrational and rotational spectroscopy applied in molecular beam experiments reveal the preference of a hydrogen bond of the methanol towards the ether oxygen (OH∙∙∙O) over the π-docking motifs via the phenyl and vinyl moieties, with an additional less populated OH∙∙∙P(phenyl)-bound isomer detected only by microwave spectroscopy. The correct prediction of the energetic order of the isomers using quantum-chemical calculations turns out to be challenging and succeeds with a sophisticated local coupled cluster method. The latter also yields a quantification as well as a visualization of London dispersion, which prove to be valuable tools for understanding the role of dispersion on the docking preferences. Beyond the structural analysis of the electronic ground state (S0), the electronically excited (S1) state is analyzed, in which a destabilization of the OH∙∙∙O structure compared to the S0 state is observed experimentally and theoretically.

ChemInform Abstract: SURFACE PHOTOCHEMISTRY: SEMICONDUCTOR-PHOTOINDUCED DIMERIZATION OF PHENYL VINYL ETHER

1985 ◽  
Vol 16 (7) ◽  
Author(s):  
A. M. DRAPER ◽  
M. ILYAS ◽  
P. DE MAYO ◽  
V. RAMAMURTHY
Keyword(s):  
Vinyl Ether ◽  
Phenyl Vinyl

ChemInform Abstract: THE STEREOSELECTIVE PHOTOCYCLOADDITION OF INDENE AND PHENYL VINYL ETHER TO ALPHA-NAPHTHONITRILE

1974 ◽  
Vol 5 (13) ◽  
pp. no-no
Author(s):  
C. PAC ◽  
K. MIZUNO ◽  
T. SUGIOKA ◽  
H. SAKURAI
Keyword(s):  
Vinyl Ether ◽  
Phenyl Vinyl

Photosensitized cyclodimerization of phenyl vinyl ether

1972 ◽  
pp. 2 ◽  
Author(s):  
Satoshi Kuwata ◽  
Yasuo Shigemitsu ◽  
Yoshinobu Odaira
Keyword(s):  
Vinyl Ether ◽  
Phenyl Vinyl

scholarly journals Thermodynamics of Vinyl Ethers. XXIV. Relative Stabilities and Structures of Some Isomeric Derivatives of Phenyl Vinyl Ether.

1980 ◽  
Vol 34b ◽  
pp. 203-208 ◽  
Author(s):  
Esko Taskinen ◽  
Börje Egestad ◽  
Lars Ernster ◽  
P. Halonen ◽  
Hans Glaumann
Keyword(s):  
Vinyl Ether ◽  
Vinyl Ethers ◽  
Relative Stabilities ◽  
Derivatives Of ◽  
Phenyl Vinyl
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