scholarly journals Structure and Elastic Properties of Networks Formed by Random Cross-Linking of Star Polymers

1986 ◽  
Vol 18 (3) ◽  
pp. 263-268 ◽  
Author(s):  
Jean Pierre Queslel ◽  
James E Mark
Soft Matter ◽  
2021 ◽  
Author(s):  
Yiğitcan Sümbelli ◽  
Sibel Emir Diltemiz ◽  
Mehmet Girayhan Say ◽  
Özlem Biçen Ünlüer ◽  
Arzu Ersöz ◽  
...  

A new cross-linking method maintaining structural stability and elastic properties.


2020 ◽  
Vol 11 (45) ◽  
pp. 7178-7184
Author(s):  
Jongmin Park ◽  
Stefan J. D. Smith ◽  
Colin D. Wood ◽  
Xavier Mulet ◽  
Myungeun Seo

Hyper-cross-linking of a core of block polymer micelles produces core cross-linked polymer with a spacious hyper-cross-linked core, which is solution-processible.


2017 ◽  
Vol 6 (9) ◽  
pp. 963-968 ◽  
Author(s):  
Yoshiki Shibuya ◽  
Hung V.-T. Nguyen ◽  
Jeremiah A. Johnson
Keyword(s):  

Young’s modulus for Polythene, cross-linked by pile irradiation, has been measured by both static and dynamic means. Below about 115°C (the usual melting-point) the modulus decreases with temperature. Above this temperature it increases again, in agreement with the theory of rubber-like elasticity, except for very high degrees of cross-linking, corresponding to a glass-like structure. The effect of radiation is both to produce cross-linking, and to destroy crystallinity. The latter effect predominates below about 4% cross-linking, and a more flexible material is obtained at room temperature. The observed elastic properties below 115°C are ascribed in part to the attraction of neighbouring chains; the activation energy required to break these attractive forces is estimated at about 0·25 eV.


2006 ◽  
Vol 128 (47) ◽  
pp. 15111-15113 ◽  
Author(s):  
Haifeng Gao ◽  
Shigeki Ohno ◽  
Krzysztof Matyjaszewski
Keyword(s):  

2009 ◽  
Vol 1234 ◽  
Author(s):  
Jack F. Douglas

AbstractSimplified models of flexible chain and stiff fiber networks are introduced to address how the network elasticity becomes modified when the cross-linking is thermoreversible in nature and changes in the stability of the network with deformation. These idealized models apparently able to capture many aspects of the elastic properties of real networks.


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