Preparation of Polymer-Bound Dinitrogen Complexes by Direct Reactions of Polymer–Metal Complexes with Molecular Nitrogen

Yoshimi Kurimura; Yasuhide Uchino; Fumihiko Ohta; Chikako Saito; Mikio Koide; Eishun Tsuchida

doi:10.1295/polymj.13.247

Preparation of Polymer-Bound Dinitrogen Complexes by Direct Reactions of Polymer–Metal Complexes with Molecular Nitrogen

Polymer Journal ◽

10.1295/polymj.13.247 ◽

1981 ◽

Vol 13 (3) ◽

pp. 247-253 ◽

Cited By ~ 6

Author(s):

Yoshimi Kurimura ◽

Yasuhide Uchino ◽

Fumihiko Ohta ◽

Chikako Saito ◽

Mikio Koide ◽

...

Keyword(s):

Metal Complexes ◽

Molecular Nitrogen ◽

Dinitrogen Complexes ◽

Direct Reactions ◽

Polymer Metal

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Polymer–metal complexes as a catalyst for the growth of carbon nanostructures

Carbon ◽

10.1016/j.carbon.2009.06.055 ◽

2009 ◽

Vol 47 (13) ◽

pp. 3137-3139 ◽

Cited By ~ 8

Author(s):

Olena Shafranska ◽

Andriy Voronov ◽

Ananiy Kohut ◽

Xiang-Fa Wu ◽

Iskander S. Akhatov

Keyword(s):

Metal Complexes ◽

Carbon Nanostructures ◽

Polymer Metal

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Application of Polymer-Metal Complexes to Environmentally-Benign Catalysis

Kobunshi ◽

10.1295/kobunshi.54.83 ◽

2005 ◽

Vol 54 (2) ◽

pp. 83-83

Author(s):

Yoichi YAMADA ◽

Yasuhiro UOZUMI

Keyword(s):

Metal Complexes ◽

Environmentally Benign ◽

Polymer Metal

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Photocatalytic reduction of molecular nitrogen to ammonia catalysed by dinitrogen complexes of ruthenium aminipolycarboxylates

Journal of Photochemistry and Photobiology A Chemistry ◽

10.1016/1010-6030(92)85177-v ◽

1992 ◽

Vol 68 (2) ◽

pp. 137-146 ◽

Cited By ~ 8

Author(s):

M.M. Taqui Khan ◽

R.C. Bhardwaj ◽

C. Bhardwaj ◽

N. Nageswara Rao

Keyword(s):

Molecular Nitrogen ◽

Photocatalytic Reduction ◽

Dinitrogen Complexes

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Polysilane–Metal Complexes for Organic Semiconductors

High Performance Polymers ◽

10.1177/0954008306081193 ◽

2007 ◽

Vol 19 (5-6) ◽

pp. 501-509 ◽

Cited By ~ 4

Author(s):

Liviu Sacarescu ◽

Rodinel Ardeleanu ◽

Gabriela Sacarescu ◽

Mihaela Simionescu ◽

Ionel Mangalagiu

Keyword(s):

Metal Complexes ◽

Organic Semiconductors ◽

Low Temperatures ◽

Gel Permeation Chromatography ◽

Chemical Structures ◽

Gel Permeation ◽

Coupling Procedure ◽

Polymer Metal ◽

Wurtz Coupling ◽

Polymer Metal Complex

New polysilane-metal complexes structures were obtained by the polycondensation reaction of α,ω-bis(chloromethyl)-polymethylphenylsilane with the Ni (II) complex of bis(salicylidene)ethylenedia-mine (salen). The chloro-functionalized polysilane was obtained by a modified Wurtz coupling procedure at low temperatures. To obtain the polymer-metal complex the resulted macroligand was complexed with metal cations. This structure is characterized by a highly localized electroactivitry in the redox moiety combined with a specific σ conjugative effect in the polysilane chain. Infrared, 1H NMR and UV-vis spectral analysis as well as gel permeation chromatography and thermogravimetric analysis were used to investigate the new chemical structures.

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