Nanospheres with Tunable Size and Chirality from Helical Polymer–Metal Complexes

2012 ◽  
Vol 134 (47) ◽  
pp. 19374-19383 ◽  
Author(s):  
Félix Freire ◽  
José Manuel Seco ◽  
Emilio Quiñoá ◽  
Ricardo Riguera
Keyword(s):  
Metal Complexes ◽  
Helical Polymer ◽  
Polymer Metal

scholarly journals A general route to chiral nanostructures from helical polymers: P/M switch via dynamic metal coordination

2017 ◽  
Vol 8 (24) ◽  
pp. 3740-3745 ◽  
Author(s):  
Sandra Arias ◽  
Manuel Núñez-Martínez ◽  
Emilio Quiñoá ◽  
Ricardo Riguera ◽  
Félix Freire
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes ◽  
Metal Coordination ◽  
Helical Polymers ◽  
Helical Polymer ◽  
Dynamic Coordination ◽  
Polymer Metal ◽  
Chiral Nanostructures

Macroscopically enantiomeric chiral nanospheres made from P or M helical polymer metal complexes can be obtained via dynamic coordination chemistry.

scholarly journals The role of the secondary structure of helical poly(phenylacetylene)s in the formation of nanoparticles from polymer–metal complexes (HPMCs)

Nanoscale ◽  
2017 ◽  
Vol 9 (45) ◽  
pp. 17752-17757 ◽  
Author(s):  
Rafael Rodríguez ◽  
Sandra Arias ◽  
Emilio Quiñoá ◽  
Ricardo Riguera ◽  
Félix Freire
Keyword(s):  
Secondary Structure ◽  
Metal Complexes ◽  
Helical Polymers ◽  
Helical Polymer ◽  
Polymer Metal

The secondary structure of chiral helical polymers forming helical polymer–metal complexes (HPMCs) plays a major role in their subsequent nanostructuration.

Polymer–metal complexes as a catalyst for the growth of carbon nanostructures

Carbon ◽  
2009 ◽  
Vol 47 (13) ◽  
pp. 3137-3139 ◽  
Author(s):  
Olena Shafranska ◽  
Andriy Voronov ◽  
Ananiy Kohut ◽  
Xiang-Fa Wu ◽  
Iskander S. Akhatov
Keyword(s):  
Metal Complexes ◽  
Carbon Nanostructures ◽  
Polymer Metal

scholarly journals Application of Polymer-Metal Complexes to Environmentally-Benign Catalysis

Kobunshi ◽  
2005 ◽  
Vol 54 (2) ◽  
pp. 83-83
Author(s):  
Yoichi YAMADA ◽  
Yasuhiro UOZUMI
Keyword(s):  
Metal Complexes ◽  
Environmentally Benign ◽  
Polymer Metal

Polysilane–Metal Complexes for Organic Semiconductors

2007 ◽  
Vol 19 (5-6) ◽  
pp. 501-509 ◽  
Author(s):  
Liviu Sacarescu ◽  
Rodinel Ardeleanu ◽  
Gabriela Sacarescu ◽  
Mihaela Simionescu ◽  
Ionel Mangalagiu
Keyword(s):  
Metal Complexes ◽  
Organic Semiconductors ◽  
Low Temperatures ◽  
Gel Permeation Chromatography ◽  
Chemical Structures ◽  
Gel Permeation ◽  
Coupling Procedure ◽  
Polymer Metal ◽  
Wurtz Coupling ◽  
Polymer Metal Complex

New polysilane-metal complexes structures were obtained by the polycondensation reaction of α,ω-bis(chloromethyl)-polymethylphenylsilane with the Ni (II) complex of bis(salicylidene)ethylenedia-mine (salen). The chloro-functionalized polysilane was obtained by a modified Wurtz coupling procedure at low temperatures. To obtain the polymer-metal complex the resulted macroligand was complexed with metal cations. This structure is characterized by a highly localized electroactivitry in the redox moiety combined with a specific σ conjugative effect in the polysilane chain. Infrared, 1H NMR and UV-vis spectral analysis as well as gel permeation chromatography and thermogravimetric analysis were used to investigate the new chemical structures.

Polymers and polymer-metal complexes containing pendent 2,2':6',2"-terpyridinyl ligands

1988 ◽  
Vol 21 (7) ◽  
pp. 1985-1991 ◽  
Author(s):  
Kevin T. Potts ◽  
Douglas A. Usifer
Keyword(s):  
Metal Complexes ◽  
Polymer Metal

Ultrafiltration of Polymer-Metal Complexes for Metal Ion Removal from Wastewaters

2006 ◽  
Vol 235 (1) ◽  
pp. 206-214 ◽  
Author(s):  
Raffaele Molinari ◽  
Pietro Argurio ◽  
Teresa Poerio
Keyword(s):  
Metal Complexes ◽  
Metal Ion ◽  
Metal Ion Removal ◽  
Ion Removal ◽  
Polymer Metal

scholarly journals Catalytic Activity of Polymer-metal Complexes:

Kobunshi ◽  
1973 ◽  
Vol 22 (3) ◽  
pp. 131-138
Author(s):  
Hiroyuki NISHIDA ◽  
Eishun TSUCHIDA
Keyword(s):  
Catalytic Activity ◽  
Metal Complexes ◽  
Polymer Metal
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