scholarly journals Copper Slag Blended Cement: An Environmental Sustainable Approach for Cement Industry in India

2016 ◽  
Vol 11 (1) ◽  
pp. 186-196
Author(s):  
Jagmeet Singh ◽  
Jaspal Singh ◽  
Manpreet Kaur

Indian cement industry is facing environmental issue of emission of carbon dioxide (CO2), a greenhouse gas. Blended cements including supplementary cementitious materials are substitute of Portland cement to reduce CO2 emission. The present paper investigates theappropriateness of copper slag (CS) as supplementary cementitious material. Strength properties and hydration of mixes were determined at different replacement levels of CS with cement. Compressive, flexural and tensile strength of each mix was found out at different curing periods. The hydration of cement was investigated through X-ray diffraction (XRD). The strength test results showed that substitution of up to 20% of CS can significantly replace Portland cement.XRD test results were corresponding to strength test results. The present study encourages the utilization of CS as supplementary cementitious material to make economical and environmentally sustainable blended cement

Author(s):  
Hayder H. Alghazali ◽  
John J. Myers

Sustainability of precast/prestressed concrete plant can be promoted by using supplementary cementitious material and that significantly reduces the embodied energy of precast/ prestressed concrete products. Usually, up to 25% of the cement can be replaced with supplementary cementitious materials (SCM). Increasing the level of replacement to exceed 25% is considered to be High-Volume SCM. Appropriate testing should be conducted to ensure desired performance of the concrete. This context reports the results of an experimental investigation of effect of accelerated curing on abrasion resistance of High Volume Supplementary Cementitious Material – Self Consolidating Concrete (HVSCM-SCC). Different mixes proportion with supplementary cementitious materials such as Fly Ash, Micro Silica, and lime (Up to 75% of cement replacement) were tested. Rheological properties of the HVSCM-SCC were measured. Mechanical properties at different ages 1, 3, 7, 28, 56, and 90 days were monitored. To investigate the abrasion resistance, 12 x 12 x 3.5 in specimens at age of 28, 56, and 90 days were conducted. The results of abrasion resistance of HVSCM-SCC were compared to the same mixes cured in the moist room. The result showed that the accelerated curing has a significant influence on abrasion resistance of concrete at early ages.


2018 ◽  
Vol 937 ◽  
pp. 107-113
Author(s):  
Samina Samrose ◽  
Saifa Anzum ◽  
Samira Mahmud ◽  
Tanvir Manzur

The present research studies the compressive strength of cement mortar cubes prepared from different proportions of supplementary cementitious materials (Fly Ash and Slag) in blended cement. This research aims to find the tentative optimum composition of supplementary cementitious material that shows better performance under tannery wastewater condition, such as that in effluent treatment plants. Synthetic tannery wastewater was simulated in laboratory after collecting wastewater sample from local tannery industry. Eight types of cement compositions (varying supplementary materials proportions) have been chosen. Compressive strength test has been conducted on mortar cubes over a period of three months. Test results revealed that slag addition had shown significantly stronger effects than that of fly ash addition. Also, the combined effect of fly ash and slag and their order of variation on strength were studied. The observations made from this research will be helpful for selection of blended cement proportions in future structures exposed to similar severe conditions.


Author(s):  
Ash Ahmed ◽  
John Kamau

It has been argued that cement is the most energy intensive and expensive material in concrete. It has also been suggested that energy efficiency could be achieved by using Supplementary Cementitious Materials (SCMs), which require less process heating and emit fewer levels of CO2. This paper reviewed studies from different authors on the possibility of using Corn Cob Ash (CCA) as a SCM. The review targeted studies that had applied the quantitative method, with validity and reliability based on empirical data from laboratory experiments. The review covered workability, density, compressive and tensile strengths, gain in strength over time, water absorption and chemical resistance of CCA-replaced concrete. From the findings, it can be concluded that CCA could be used as an effective SCM to replace cement in concrete, with the benefit of a reduction in CO2 emissions that are associated with the production of cement and a mitigation on environmental nuisance that is attributed to the throwing away of corncobs and CCA in landfill, while at the same time improving the properties of wet and hardened concrete.


Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 517
Author(s):  
Abdelmoujib Bahhou ◽  
Yassine Taha ◽  
Yassine El Khessaimi ◽  
Rachid Hakkou ◽  
Arezki Tagnit-Hamou ◽  
...  

This review summarizes the major research and scientific findings on the relevance of using calcined marl as supplementary cementitious material in developing eco-friendly cement for the next generation. Incorporation of calcined marl into cement can result in changes in the properties of these binders, and thus compatibility with other additions could be potential challenging, particularly at higher replacement ratios. From the reviewed literature, a detailed investigation on the characterization of calcined marls, activation methods, influencing parameters, along with studies on the hydration and microstructure was discussed, the overall objective aimed at coming up with the optimal physical and chemical parameters to generate highly reactive marl.


2013 ◽  
Vol 284-287 ◽  
pp. 113-117 ◽  
Author(s):  
Wei Ting Lin ◽  
Ta Yuan Han ◽  
Yuan Chieh Wu ◽  
An Cheng ◽  
Ran Huang ◽  
...  

This study investigates the properties of cement-based composites with addition of various recycled rock wools and compare with the properties of composites containing fly ash and ggbs. The use of recycled rock wool is with a cylindrical and fiber-shape particle less than 75 μm. Based on the chemical composition and particle size distribution, the material properties of recycled rock wool are similar to other pozzolanic materials such as fly ash and ggbs and can be use a supplementary cementitious material. The experimental results show that partially replacing cement with recycled rock wool improves the compressive strength and porestructure, but reduce the flow spread at the high level replacement. Therefore, the test results indicate that recycled rock wool is an effective mineral admixture, with 10 % to 30 % as suitable replacement ratio of cement for the difference water/cementitious ratios.


2014 ◽  
Vol 13 (2) ◽  
pp. 127-134 ◽  
Author(s):  
Oksana Poznyak ◽  
Andryy Melnyk

In this paper the impact of carbonate-containing and sulfate components, zeolite, polypropylene fibers on the properties of modified binding composition and non-autoclaved aerated concrete based on them is investigated. The aerated concrete based on the modified binding composition containing a supplementary cementitious material, that of carbonate-containing salt waste, reinforced with polypropylene fibers is characterized by the compressive strength of 2.7 MPa with the density of 650 kg/m3. The thickness of partitions between pores is 0.16 – 0.21 mm, and the number of pores with the size 0.2-1.0 mm is 76.4%.


2021 ◽  
Vol 11 (9) ◽  
pp. 4028
Author(s):  
Asghar Gholizadeh Vayghan ◽  
Liesbeth Horckmans ◽  
Ruben Snellings ◽  
Arne Peys ◽  
Priscilla Teck ◽  
...  

This research investigated the possibility of using metallurgical slags from the copper and lead industries as partial replacement for cement. The studied slags were fayalitic, having a mainly ferro-silicate composition with minor contents of Al2O3 and CaO. The slags were treated at 1200–1300 °C (to reduce the heavy metal content) and then granulated in water to promote the formation of reactive phases. A full hydration study was carried out to assess the kinetics of reactions, the phases formed during hydration, the reactivity of the slags and their strength activity as supplementary cementitious material (SCM). The batch-leaching behaviour of cementitious mixtures incorporating treated slags was also investigated. The results showed that all three slags have satisfactory leaching behaviour and similar performance in terms of reactivity and contribution to the strength development. All slags were found to have mediocre reactivity and contribution to strength, especially at early ages. Nonetheless, they passed the minimum mechanical performance requirements and were found to qualify for use in cement.


2021 ◽  
Vol 13 (7) ◽  
pp. 3979
Author(s):  
Rosa María Tremiño ◽  
Teresa Real-Herraiz ◽  
Viviana Letelier ◽  
Fernando G. Branco ◽  
José Marcos Ortega

One of the ways of lessening the CO2 emissions of cement industry consists of replacing clinkers with supplementary cementitious materials. The required service life of real construction elements is long, so it is useful to characterize the performance of these materials in the very long term. Here, the influence of incorporating waste glass powder as a supplementary cementitious material, regarding the microstructure and durability of mortars after 1500 hardening days (approximately 4 years), compared with reference mortars without additions, was studied. The percentages of clinker replacement by glass powder were 10% and 20%. The microstructure was studied using impedance spectroscopy and mercury intrusion porosimetry. Differential thermal and X-ray diffraction analyses were performed for assessing the pozzolanic activity of glass powder at the end of the time period studied. Water absorption after immersion, the steady-state diffusion coefficient, and length change were also determined. In view of the results obtained, the microstructure of mortars that incorporated waste glass powder was more refined compared with the reference specimens. The global solid fraction and pores volume were very similar for all of the studied series. The addition of waste glass powder reduced the chloride diffusion coefficient of the mortars, without worsening their behaviour regarding water absorption after immersion.


Author(s):  
Karima Arroudj ◽  
Saida Dorbani ◽  
Mohamed Nadjib Oudjit ◽  
Arezki Tagnit-Hamou

Much of the current research on concrete engineering has been focused on including siliceous additions as supplementary cementitious materials (SCMs). Silica reacts with Calcium hydroxide release during cement hydration, and produces more C-S-H. The latter contributes to increase compactness, mechanical strengths and sustainability of concrete. This paper explores the hydration characteristics of cement paste based on various natural mineral additions, that are very abundant in Algeria and present a high silica content (ground natural pozzolana “PZ” and ground dune sand “DS”). For this purpose, several analyses were carried out on modified cement pastes and mortars. TheseSCMswere introduced by replacement levels of 15, 20 and 25 by weight of cement. We first, studied the effect of these SCMs on the heat of hydration and mechanical strength of mortars at different ages. The evolution of hydration of modified paste was studied, by using Thermal analysis (TG/TDA) at different ages, to analyze the Calcium Hydroxide (CH) content of the modified pastes. It is shown that the CH content of the mixes including SCMs is lower than that of the plain cement paste, indicating that silica reacts with the cement paste through a pozzolanic reaction. Increased pozzolanic activity results in higher amounts of Calcium Silicate Hydrate in the paste, which in turn results in higher compressive strength for modified cement mortars. Due to its crystalline morphology, the ground DS particles present a partial pozzolanic effect, compared to PZ which is semi-crystalline. Modified mortars by 20% DS can be the optimal composition. It presents satisfactory results: good mechanical strength and low heat of hydration. It can lead to an economic and sustainable concrete. Ground DS is very abounded in Africa and free of any impurities and can be a good alternativeSCMsin cement industry.


2018 ◽  
Vol 7 (2.12) ◽  
pp. 446
Author(s):  
L Krishnaraj ◽  
P T. Ravichandran ◽  
M V.A.Karthik ◽  
N Satheeshram Avudaiyappan ◽  
. .

The life of the concrete is strongly influenced by durability parameters. The permeability is one of the main characteristics influencing the durability of concrete. The concrete is more permeable due to the ingress of water, oxygen, chloride, sulphate, and other potential deleterious substances. The durability of concrete is mainly affected by pore structure system of concrete and addingthe supplementary cementitious materials (SCM), such as fly ash, slag cement, and silica fume can be decrease permeability. Crystalline technology enhances the strength of concrete by filling the poresand micro-cracks with non-dissolvable substances. To study the efficiency of crystalline formation in concrete in terms of more permeable should be guaranteed through a specific technique.The effectiveness of crystalline waterproofing system with partial replacement cement by GGBS is studiedin terms of strength and durability. The performance of the two different types of crystalline waterproofing integral admixtures has been studied for compressive strength, Split tensile strength, workability, water permeability, Rapid chloride permeability test and porosity in this paper.The early strength increased in GGBS with crystalline admixture concretes compare to the control concrete. No significant strength reduction is observed in GGBS concretes with crystalline admixture when replaced with 20% and 40% of cement than control concrete.  


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