scholarly journals Topography of thin films containing Ni-Ga intermetallic compounds formed on GaN(0001)

2016 ◽  
Vol 7 ◽  
pp. 1 ◽  
Author(s):  
Justyna Pers ◽  
Miłosz Grodzicki ◽  
Antoni Ciszewski
1989 ◽  
Vol 148 ◽  
Author(s):  
Young K. Kim ◽  
David K. Shuh ◽  
R. Stanley Williams ◽  
Larry P. Sadwick ◽  
Kang L. Wang

ABSTRACTEpitaxial thin films of three different Pt-Ga intermetallic compounds have been grown on GaAs by molecular beam epitaxy (MBE). The resultant films have been annealed at various temperatures and then examined using X-ray two-theta diffraction. Both PtGa2 and PtGa thin films are chemically stable on GaAs under 1 atmosphere of N2 up to 450°C and 600°C, respectively. Thin films of Pt2Ga react with GaAs at temperatures as low as 200°C to form phases with higher Ga concentration.


2009 ◽  
Vol 484 (1-2) ◽  
pp. 335-340 ◽  
Author(s):  
A.S. Ramos ◽  
M.T. Vieira ◽  
J. Morgiel ◽  
J. Grzonka ◽  
S. Simões ◽  
...  

2020 ◽  
Vol 6 (5) ◽  
pp. eaay7685 ◽  
Author(s):  
Volodymyr Smetana ◽  
Steven P. Kelley ◽  
Anja-Verena Mudring ◽  
Robin D. Rogers

Aperiodic formations continue to focus interest in areas ranging from advanced scientific theories to practical everyday applications. Starting from diverse and tightly bonded intermetallic compounds, this world showed an important breakthrough toward the so-called soft systems of meso/macroscale: liquid crystals, thin films, polymers, proteins, etc. This work opens a route for making bulk quasicrystals (QC) in an unprecedented but very common area, with molecular ligands. Since these systems are, to a large extent, transparent, they extend the possible areas of QC application to previously unreachable corners, e.g., photonics. We combined efficient bridging ligands with uranyl pentagonal bonding centers and, unexpectedly, brought the unique attributes of f-element coordination chemistry to an interdisciplinary area of aperiodic formations. Taking advantage of the planar coordination of uranyl ions, we were able to direct the structure expansion solely in two directions with a characteristic snub square tiling, a predicted but previously unobtainable dodecagonal approximant.


1984 ◽  
Vol 55 (12) ◽  
pp. 4208-4218 ◽  
Author(s):  
F. d’Heurle ◽  
C. S. Petersson ◽  
J. E. E. Baglin ◽  
S. J. La Placa ◽  
C. Y. Wong

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4034
Author(s):  
Lukasz Skowronski ◽  
Marek Trzcinski ◽  
Aleksandra Olszewska ◽  
Robert Szczesny

AuSn and AuSn2 thin films (5 nm) were used as precursors during the formation of semiconducting metal oxide nanostructures on a silicon substrate. The nanoparticles were produced in the processes of annealing and oxidation of gold–tin intermetallic compounds under ultra-high vacuum conditions. The formation process and morphology of a mixture of SnO2 and Au@SnOx (the core–shell structure) nanoparticles or Au nanocrystalites were carefully examined by means of spectroscopic ellipsometry (SE), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) combined with energy-dispersive X-ray spectroscopy (EDX). The annealing and oxidation of the thin film of the AuSn intermetallic compound led to the formation of uniformly distributed structures with a size of ∼20–30 nm. All of the synthesized nanoparticles exhibited a strong absorption band at 520–530 nm, which is typical for pure metallic or metal oxide systems.


1990 ◽  
Vol 5 (10) ◽  
pp. 2139-2151 ◽  
Author(s):  
Young K. Kim ◽  
Delroy A. Baugh ◽  
David K. Shuh ◽  
R. Stanley Williams ◽  
Larry P. Sadwick ◽  
...  

Nearly single-phase thin films of three different Pt–Ga intermetallic compounds have been grown on GaAs(001) by co-deposition of Pt and Ga. The resultant films have been annealed at various temperatures and then characterized using x-ray two-theta diffractometry (XRD), Auger electron spectroscopy (AES), and x-ray photoemission spectroscopy (XPS). The XRD results showed that PtGa2 and PtGa thin films are chemically stable on GaAs under one atmosphere of N2 up to 800 °C and 600 °C, respectively, but thin films of Pt2Ga react with GaAs at temperatures as low as 200 °C to form phases with higher Ga concentration PtAs2. The XRD patterns also revealed that the crystallite orientation and texture of the films were dependent on annealing temperature. Segregation of Ga to the surfaces of the films upon annealing was also observed by both AES and XPS. The results demonstrated that the as-deposited films of PtGa2 and PtGa were kinetically stabilized with respect to possible chemical reactions with the GaAs substrates that evolve gaseous As species during open system annealing.


2014 ◽  
Vol 141 (8) ◽  
pp. 084702 ◽  
Author(s):  
G. M. McGuirk ◽  
J. Ledieu ◽  
É. Gaudry ◽  
M.-C. de Weerd ◽  
V. Fournée

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