scholarly journals The Structural Design of Electrode Materials for High Energy Lithium Batteries

2007 ◽  
Vol 40 (13) ◽  
pp. 1150-1158 ◽  
Author(s):  
Michael Thackeray
2018 ◽  
Vol 6 (42) ◽  
pp. 20564-20620 ◽  
Author(s):  
Hailin Zhang ◽  
Hongbin Zhao ◽  
Muhammad Arif Khan ◽  
Wenwen Zou ◽  
Jiaqiang Xu ◽  
...  

This article comprehensively reviews the recent progress in the development of key components of lithium-ion batteries, including positive/negative electrodes, electrolytes and separators. The necessity of developing batteries with high energy/power density and long cycle-life is emphasized both in terms of industrial and academic perspectives.


1999 ◽  
Vol 81-82 ◽  
pp. 150-155 ◽  
Author(s):  
Boone B Owens ◽  
William H Smyrl ◽  
Jun John Xu

RSC Advances ◽  
2015 ◽  
Vol 5 (113) ◽  
pp. 93048-93056 ◽  
Author(s):  
Mohammed Adnan Mezaal ◽  
Limin Qu ◽  
Guanghua Li ◽  
Rui Zhang ◽  
Jiang Xuejiao ◽  
...  

Nickel-rich layered lithium transition-metal oxides have been studied intensively as high-energy positive-electrode materials for lithium batteries because of their high specific capacity and relatively low-cost.


2007 ◽  
Vol T129 ◽  
pp. 57-61 ◽  
Author(s):  
S J Kim ◽  
S H Kim ◽  
D H Kim ◽  
J S Im ◽  
H Y Ahn ◽  
...  

2020 ◽  
Author(s):  
Colin R. Bridges ◽  
Andryj M. Borys ◽  
Vanessa Béland ◽  
Joshua R. Gaffen ◽  
Thomas Baumgartner

Low molecular weight organic molecules that can accept multiple electrons at high<br>reduction potentials are sought after as electrode materials for high-energy sustainable batteries. To date their synthesis has been difficult, and organic scaffolds for electron donors significantly outnumber electron acceptors. Herein, we report two highly electron deficient phosphaviologen derivatives from a phosphorus-bridged 4,4-bipyridine and characterize their electrochemical properties. Phosphaviologen sulfide (PVS) and P-methyl phosphaviologen (PVM) accept two and three electrons at high reduction potentials, respectively. PVM can reversibly accept 3 electrons between 3-3.6 V vs. Li/Li+ with an equivalent molecular weight of 102 g/(mol e-) (262 mAh/g), making it a promising scaffold for sustainable organic electrode materials having high specific energy densities.


2010 ◽  
Vol 12 (11) ◽  
pp. 1618-1621 ◽  
Author(s):  
Donghan Kim ◽  
Sun-Ho Kang ◽  
Mahalingam Balasubramanian ◽  
Christopher S. Johnson

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Chen Li ◽  
Xiong Zhang ◽  
Kai Wang ◽  
Xianzhong Sun ◽  
Yanan Xu ◽  
...  

AbstractLithium-ion capacitors are envisaged as promising energy-storage devices to simultaneously achieve a large energy density and high-power output at quick charge and discharge rates. However, the mismatched kinetics between capacitive cathodes and faradaic anodes still hinder their practical application for high-power purposes. To tackle this problem, the electron and ion transport of both electrodes should be substantially improved by targeted structural design and controllable chemical doping. Herein, nitrogen-enriched graphene frameworks are prepared via a large-scale and ultrafast magnesiothermic combustion synthesis using CO2 and melamine as precursors, which exhibit a crosslinked porous structure, abundant functional groups and high electrical conductivity (10524 S m−1). The material essentially delivers upgraded kinetics due to enhanced ion diffusion and electron transport. Excellent capacities of 1361 mA h g−1 and 827 mA h g−1 can be achieved at current densities of 0.1 A g−1 and 3 A g−1, respectively, demonstrating its outstanding lithium storage performance at both low and high rates. Moreover, the lithium-ion capacitor based on these nitrogen-enriched graphene frameworks displays a high energy density of 151 Wh kg−1, and still retains 86 Wh kg−1 even at an ultrahigh power output of 49 kW kg−1. This study reveals an effective pathway to achieve synergistic kinetics in carbon electrode materials for achieving high-power lithium-ion capacitors.


Author(s):  
Jian Zhao ◽  
He Cheng ◽  
Huanyu Li ◽  
Yan-Jie Wang ◽  
Qingyan Jiang ◽  
...  

Developing advanced negative and positive electrode materials for asymmetric supercapacitors (ASCs) as the electrochemical energy storage can enable the device to reach high energy/power densities resulting from the cooperative effect...


Sign in / Sign up

Export Citation Format

Share Document