scholarly journals Metal Complexes of Isonicotinoyltydrazine and Related Compounds. IV. Composition Formulae and Infrared Absorption Spectra of Metal Complex Crystals of Isonicotinoylhydrazine and Related Compounds

1964 ◽  
Vol 12 (10) ◽  
pp. 1198-1206 ◽  
Author(s):  
Kozo Nagano ◽  
Hisashi Kinoshita ◽  
Akiko Hirakawa
1970 ◽  
Vol 25 (2) ◽  
pp. 142-145 ◽  
Author(s):  
S. P. Tandon ◽  
P. C. Mehta ◽  
R. N. Kapoor

Infrared absorption spectra of four (ethylbenzoyl acetate) [EBA] complexes of trivalent samarium of the general formula XpSm(EBA)q [X = isopropoxy or t-butoxy group; when p=1, q=2 and vice versa] have been studied in the region 4000-250 cm-1 for the first time. About twenty five bands in each complex have been observed and assigned to different modes of vibration. The separation between asymmetric and symmetric CO stretching vibrations indicates that the bonding in all the complexes is nearly the same. The spectra show that the interaction between the two ligand rings is small in five coordinated metal complexes.


1951 ◽  
Vol 23 (2) ◽  
pp. 282-285 ◽  
Author(s):  
O. D. Shreve ◽  
M. R. Heether ◽  
H. B. Knight ◽  
Daniel Swern

1955 ◽  
Vol 23 (7) ◽  
pp. 1354-1354 ◽  
Author(s):  
Masahisa Kobayashi ◽  
Junnosuke Fujita

1969 ◽  
Vol 47 (6) ◽  
pp. 1087-1089 ◽  
Author(s):  
D. M. Wiles ◽  
T. Suprunchuk

In the infrared absorption spectra of thiosemicarbazide (I), aldehyde thiosemicarbazones (II), and N-methyl derivatives of these compounds, the following assignments are proposed: νa(NdH2) absorbs in the vicinity of 3400 cm−1; NaH2 vibrations are observed in the region of 1630 cm−1; there is a significant contribution from ν(NbH) at or near 3170 cm−1. These conclusions probably apply to other thioamides and amides having related structures.


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