The infrared absorption spectra of thiosemicarbazide and related compounds: NH2 and NH vibrations

1969 ◽  
Vol 47 (6) ◽  
pp. 1087-1089 ◽  
Author(s):  
D. M. Wiles ◽  
T. Suprunchuk

In the infrared absorption spectra of thiosemicarbazide (I), aldehyde thiosemicarbazones (II), and N-methyl derivatives of these compounds, the following assignments are proposed: νa(NdH2) absorbs in the vicinity of 3400 cm−1; NaH2 vibrations are observed in the region of 1630 cm−1; there is a significant contribution from ν(NbH) at or near 3170 cm−1. These conclusions probably apply to other thioamides and amides having related structures.

1962 ◽  
Vol 82 (4) ◽  
pp. 578-583 ◽  
Author(s):  
Yoshihiro Nitta ◽  
Junji Ide ◽  
Atsushi Momose ◽  
Yasuo Nakajima

1982 ◽  
Vol 47 (4) ◽  
pp. 1100-1111 ◽  
Author(s):  
Jaroslav Majer ◽  
Vladimír Kadeřábek

Infrared absorption spectra of N-substituted derivatives of 2,4-dinitro- and 2,6-dinitroanilines have been measured and interpreted from the point of view of bond and sterical interactions of the substituted amino groups with the both nitro groups.


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