The infrared absorption spectra of thiosemicarbazide and related compounds: NH2 and NH vibrations
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In the infrared absorption spectra of thiosemicarbazide (I), aldehyde thiosemicarbazones (II), and N-methyl derivatives of these compounds, the following assignments are proposed: νa(NdH2) absorbs in the vicinity of 3400 cm−1; NaH2 vibrations are observed in the region of 1630 cm−1; there is a significant contribution from ν(NbH) at or near 3170 cm−1. These conclusions probably apply to other thioamides and amides having related structures.
1964 ◽
Vol 12
(10)
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pp. 1198-1206
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1982 ◽
Vol 47
(4)
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pp. 1100-1111
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1960 ◽
Vol 81
(6)
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pp. 858-862
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1967 ◽
Vol 71A
(1)
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pp. 53
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1968 ◽
Vol 6
(1)
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pp. 63-67
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1961 ◽
Vol 82
(7)
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pp. 805-813
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