Single-Molecule Electric Switching Induced by Acid-base Reaction

2021 ◽  
Author(s):  
Yuki Yoshihara ◽  
Shintaro Fujii ◽  
Shuhei Higashibayashi ◽  
Manabu Kiguchi ◽  
Tomoaki Nishino
Keyword(s):  
Single Molecule ◽  
Acid Base

Investigation of an Acid–Base and Redox Molecular Switch: From Bulk to the Single-Molecule Level

2007 ◽  
Vol 13 (25) ◽  
pp. 7066-7074 ◽  
Author(s):  
Rabih O. Al-Kaysi ◽  
José Luis Bourdelande ◽  
Iluminada Gallardo ◽  
Gonzalo Guirado ◽  
Jordi Hernando
Keyword(s):  
Single Molecule ◽  
Molecular Switch ◽  
Acid Base ◽  
Single Molecule Level

A Single‐Molecule and Logic Gate via Optical and Acid–Base Control

2020 ◽  
Vol 3 (10) ◽  
pp. 2000163
Author(s):  
Wenkai Zhao ◽  
Dongqing Zou ◽  
Zhaopeng Sun ◽  
Yuqing Xu ◽  
Guomin Ji ◽  
...  
Keyword(s):  
Single Molecule ◽  
Logic Gate ◽  
Acid Base

Single-Molecule Sensing of Interfacial Acid–Base Chemistry

2020 ◽  
Vol 11 (23) ◽  
pp. 10023-10028 ◽  
Author(s):  
Cai-Ping Tao ◽  
Chen-Chen Jiang ◽  
Ya-Hao Wang ◽  
Ju-Fang Zheng ◽  
Yong Shao ◽  
...  
Keyword(s):  
Single Molecule ◽  
Acid Base

Single Molecule Acid-Base Kinetics and Thermodynamics

2004 ◽  
Vol 93 (7) ◽  
Author(s):  
Michael D. Mason ◽  
Krishanu Ray ◽  
Robert D. Grober ◽  
Gerd Pohlers ◽  
James Cameron
Keyword(s):  
Single Molecule ◽  
Acid Base ◽  
Kinetics And Thermodynamics

scholarly journals Single molecule observation of hard–soft-acid–base (HSAB) interaction in engineered Mycobacterium smegmatis porin A (MspA) nanopores

2020 ◽  
Vol 11 (3) ◽  
pp. 879-887 ◽  
Author(s):  
Sha Wang ◽  
Jiao Cao ◽  
Wendong Jia ◽  
Weiming Guo ◽  
Shuanghong Yan ◽  
...  
Keyword(s):  
Single Molecule ◽  
Mycobacterium Smegmatis ◽  
Acid Base ◽  
Soft Acid ◽  
Hsab Theory

The principle of hard–soft-acid–base (HSAB) theory was first validated in single molecule by measurements with engineered Mycobacterium smegmatis porin A (MspA) nanopore reactors.

Folding and catalysis of the hairpin ribozyme

2005 ◽  
Vol 33 (3) ◽  
pp. 461-465 ◽  
Author(s):  
T.J. Wilson ◽  
M. Nahas ◽  
T. Ha ◽  
D.M.J. Lilley
Keyword(s):  
Single Molecule ◽  
Ph Dependence ◽  
Active Form ◽  
Resonance Energy Transfer ◽  
Resonance Energy ◽  
Base Catalysis ◽  
Hairpin Ribozyme ◽  
Acid Base ◽  
Physiological Conditions ◽  
Single Molecule Enzymology

The active form of the hairpin ribozyme is brought about by the interaction of two formally unpaired loops. In a natural molecule, these are present on two adjacent arms of a four-way junction. Although activity can be obtained in molecules lacking this junction, the junction is important in the promotion of the folded state of the ribozyme under physiological conditions, at a rate that is faster than the chemical reaction. Single-molecule fluorescence resonance energy transfer studies show that the junction introduces a discrete intermediate into the folding process, which repeatedly juxtaposes the two loops and thus promotes their docking. Using single-molecule enzymology, the cleavage and ligation rates have been measured directly. The pH dependence of the rates is consistent with a role for nucleobases acting in general acid–base catalysis.

scholarly journals Probing Lewis acid–base interactions in single-molecule junctions

Nanoscale ◽  
2018 ◽  
Vol 10 (38) ◽  
pp. 18131-18134 ◽  
Author(s):  
Xunshan Liu ◽  
Xiaohui Li ◽  
Sara Sangtarash ◽  
Hatef Sadeghi ◽  
Silvio Decurtins ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Single Molecule ◽  
Single Molecules ◽  
Quantum Effects ◽  
Acid Base ◽  
Single Molecule Junctions ◽  
Conceptual Advance

A new and timely conceptual advance in controlling quantum effects in single molecules via Lewis acid–base interactions is reported.

Analysis of acid-base interactions at Al 2 O 3 (11-20) interfaces by means of single molecule force spectroscopy

2017 ◽  
Vol 420 ◽  
pp. 296-302 ◽  
Author(s):  
Bastian Mosebach ◽  
Berkem Ozkaya ◽  
Ignacio Giner ◽  
Adrian Keller ◽  
Guido Grundmeier
Keyword(s):  
Single Molecule ◽  
Force Spectroscopy ◽  
Acid Base ◽  
Single Molecule Force Spectroscopy
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