Dehydrocoupling Reactions of Secondary and Primary Amine–Borane Adducts Catalyzed by Half-sandwich Carbonyl Complexes, [CpMn(CO)3], [(η6-C6H6)Cr(CO)3], and [CpV(CO)4]

2011 ◽  
Vol 40 (2) ◽  
pp. 171-173 ◽  
Author(s):  
Taeko Kakizawa ◽  
Yasuro Kawano ◽  
Kohsuke Naganeyama ◽  
Mamoru Shimoi
Keyword(s):  
Primary Amine ◽  
Carbonyl Complexes ◽  
Half Sandwich

Chlorination of half-sandwich carbonyl complexes: The square-pyramidal cation [(η6-C6Et6)Mo(CO)3Cl]+

Polyhedron ◽  
1988 ◽  
Vol 7 (19-20) ◽  
pp. 2027-2030 ◽  
Author(s):  
W.A. Herrmann ◽  
W.R. Thiel ◽  
E. Herdtweck
Keyword(s):  
Carbonyl Complexes ◽  
Half Sandwich

Hemilability of the primary amine–metal bond in polyamine-(Group 6) metal carbonyl complexes

2002 ◽  
Vol 664 (1-2) ◽  
pp. 214-222 ◽  
Author(s):  
Anne-Cécile Hervé ◽  
Jean-Jacques Yaouanc ◽  
Jean-Claude Clément ◽  
Hervé des Abbayes ◽  
Loı̈c Toupet
Keyword(s):  
Primary Amine ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Bond ◽  
Metal Carbonyl Complexes ◽  
Group 6

Dehydrocoupling Reactions of Borane−Secondary and −Primary Amine Adducts Catalyzed by Group-6 Carbonyl Complexes: Formation of Aminoboranes and Borazines

2009 ◽  
Vol 131 (41) ◽  
pp. 14946-14957 ◽  
Author(s):  
Yasuro Kawano ◽  
Mikio Uruichi ◽  
Mamoru Shimoi ◽  
Seitaro Taki ◽  
Takayuki Kawaguchi ◽  
...  
Keyword(s):  
Primary Amine ◽  
Carbonyl Complexes ◽  
Group 6 ◽  
Amine Adducts

Half-Sandwich Ruthenium Catalyst Bearing an Enantiopure Primary Amine Tethered to an N-Heterocyclic Carbene for Ketone Hydrogenation

ACS Catalysis ◽  
2017 ◽  
Vol 7 (10) ◽  
pp. 6827-6842 ◽  
Author(s):  
Kai Y. Wan ◽  
Molly M. H. Sung ◽  
Alan J. Lough ◽  
Robert H. Morris
Keyword(s):  
Primary Amine ◽  
Ruthenium Catalyst ◽  
Ketone Hydrogenation ◽  
Half Sandwich

MULTIPLE SCATTERING EFFECTS IN THE COBALT K-EDGE EXAFS OF METAL CARBONYL COMPLEXES

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-589-C8-592
Author(s):  
N. BINSTED ◽  
S. L. COOK ◽  
J. EVANS ◽  
R. J. PRICE ◽  
G. N. GREAVES
Keyword(s):  
Multiple Scattering ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Scattering Effects ◽  
Multiple Scattering Effects

Regio-, Stereo- and Enantioselective α-Addition of Carbonyl Nucleo-philes to Allenamides Catalyzed by a Synergistic Copper/Enamine System

2020 ◽  
Author(s):  
Rémi Blieck ◽  
Sebastien Lemouzy ◽  
Marc Taillefer ◽  
Florian Monnier
Keyword(s):  
Catalytic System ◽  
Secondary Amine ◽  
Primary Amine ◽  
Synergistic Catalysis ◽  
Enantioselective Addition ◽  
Amine Catalysts

A dual copper/enamine catalytic system is found to enable an intermolecular enantioselective α-addition of various carbonyl nucleophiles to allenamides. Secondary amine catalysts allowed the highly enantioselective addition of aldehydes, while using primary amine catalysts led to the enantioselective addition of ketoester nucleophiles. The process was found to be highly regio-, stereo- and enantio-selective and represented the first allene hydrofunctionalization using an synergistic catalysis involving copper

Sign in / Sign up

Export Citation Format

Share Document