Half-Sandwich Metal Carbonyl Complexes as Precursors to Functional Materials: From a Near-Infrared-Absorbing Dye to a Single-Molecule Magnet

2017 ◽  
Vol 139 (34) ◽  
pp. 12069-12075 ◽  
Author(s):  
Wenqing Wang ◽  
Jing Li ◽  
Lei Yin ◽  
Yue Zhao ◽  
Zhongwen Ouyang ◽  
...  
Keyword(s):  
Single Molecule ◽  
Near Infrared ◽  
Metal Carbonyl ◽  
Functional Materials ◽  
Carbonyl Complexes ◽  
Single Molecule Magnet ◽  
Metal Carbonyl Complexes ◽  
Half Sandwich

MULTIPLE SCATTERING EFFECTS IN THE COBALT K-EDGE EXAFS OF METAL CARBONYL COMPLEXES

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-589-C8-592
Author(s):  
N. BINSTED ◽  
S. L. COOK ◽  
J. EVANS ◽  
R. J. PRICE ◽  
G. N. GREAVES
Keyword(s):  
Multiple Scattering ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Scattering Effects ◽  
Multiple Scattering Effects

Transition Metal Carbonyl Complexes of an N-Heterocyclic Carbene Stabilized Silyliumylidene Ion

2019 ◽  
Vol 58 (21) ◽  
pp. 14931-14937 ◽  
Author(s):  
Philipp Frisch ◽  
Tibor Szilvási ◽  
Amelie Porzelt ◽  
Shigeyoshi Inoue
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes

scholarly journals Solid‐State Near‐Infrared Circularly Polarized Luminescence from Chiral YbIII‐Single‐Molecule Magnet

2021 ◽  
Author(s):  
Fabrice Pointillart ◽  
Bertrand Lefeuvre ◽  
Carlo Andrea Mattei ◽  
Jessica Flores Gonzalez ◽  
Frédéric Gendron ◽  
...  
Keyword(s):  
Solid State ◽  
Single Molecule ◽  
Near Infrared ◽  
Circularly Polarized ◽  
Single Molecule Magnet ◽  
Circularly Polarized Luminescence ◽  
Polarized Luminescence

Polyoxometalate-supported metal carbonyl derivatives: from synthetic strategies to structural diversity and applications

2019 ◽  
Vol 6 (11) ◽  
pp. 3041-3056 ◽  
Author(s):  
Jingkun Lu ◽  
Peipei He ◽  
Jingyang Niu ◽  
Jingping Wang
Keyword(s):  
Catalytic Properties ◽  
Metal Carbonyl ◽  
Structural Diversity ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Carbonyl Derivatives ◽  
Supported Metal

This review aims to give an overview of the POM-supported metal carbonyl complexes obtained so far, focusing on their structural diversity and potential photochemical and catalytic properties.

Selected strategies for improving sensitivity and reliability of immunoassays

1994 ◽  
Vol 40 (3) ◽  
pp. 347-357 ◽  
Author(s):  
L J Kricka
Keyword(s):  
Drugs Of Abuse ◽  
Metal Carbonyl ◽  
Step Test ◽  
Detection Methods ◽  
Carbonyl Complexes ◽  
Assay Sensitivity ◽  
Metal Carbonyl Complexes ◽  
One Step ◽  
Polymerase Chain ◽  
Catalyzed Reporter Deposition

Abstract Selected recent advances in immunoassay are reviewed. Development has continued on new labels (beta-lactamase, pyrophosphatase, luciferases, photoproteins, pyridopyridazines, europium cryptates, metal carbonyl complexes, porphines, phosphors) and label-detection methods (e.g., chemiluminescence assays, thermometric assays, NADP(+)- and FADP-based coupled assays). Various methods have been explored to increase assay sensitivity, including label amplification via catalyzed reporter deposition (peroxidase label) and immuno-polymerase chain reaction (DNA label). The focus of new immunoassay strategies has been on improved reliability (bispecific antibodies), assay simplification (piezoelectric and surface plasmon resonance immunosensors, phase-modulation fluorescence spectroscopy, polymerized bilayer assemblies), and simultaneous multianalyte testing (e.g., quadruple labeling with lanthanides, one-step test devices for drugs of abuse).

Stereochemistry of epoxide carbonylation using bimetallic Lewis acid/metal carbonyl complexes

2004 ◽  
Vol 76 (3) ◽  
pp. 557-564 ◽  
Author(s):  
Y. D. Y. L. Getzler ◽  
Viswanath Mahadevan ◽  
E. B. Lobkovsky ◽  
G. W. Coates
Keyword(s):  
Lewis Acid ◽  
Kinetic Resolution ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Enantiomerically Pure ◽  
Metal Carbonyl Complexes ◽  
Pure Complex

The stereochemistry of epoxide carbonylation using bimetallic [Lewis acid]+[Co(CO)4]- complexes is reported. The achiral complex [(salph)Al(THF)2][Co(CO)4] stereospecifically carbonylates cis- and trans-2-butene oxide to the trans- and cis-β-lactones, respectively. Preliminary experiments regarding the carbonylative kinetic resolution of racemic trans-2-butene oxide using the enantiomerically pure complex [(R,R-salcy)Al(THF)2][Co(CO)4] are also reported.

Electrospray mass spectrometric studies of some cationic and anionic Group 6 and Group 7 metal carbonyl complexes

1993 ◽  
Vol 447 (1) ◽  
pp. 59-65 ◽  
Author(s):  
Ikhtiar Ahmed ◽  
Alan M. Bond ◽  
Ray Colton ◽  
Mandy Jurcevic ◽  
John C. Traeger ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Mass Spectrometric ◽  
Carbonyl Complexes ◽  
Anionic Group ◽  
Metal Carbonyl Complexes ◽  
Group 6
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