Tailoring Material Properties through Defect Engineering

2010 ◽  
Vol 39 (12) ◽  
pp. 1226-1231 ◽  
Author(s):  
Harry L. Tuller ◽  
Sean R. Bishop
2020 ◽  
Vol 8 (31) ◽  
pp. 15864-15874
Author(s):  
Katharina Rudisch ◽  
Alexandra Davydova ◽  
Lars Riekehr ◽  
Joakim Adolfsson ◽  
Luciano Quaglia Casal ◽  
...  

Composition spread Cu2ZnSnS4 thin films unveil the complicated interplay between process conditions and material properties, pointing to new approaches towards defect engineering.


2011 ◽  
Vol 178-179 ◽  
pp. 158-165 ◽  
Author(s):  
Jasmin Hofstetter ◽  
Jean François Lelièvre ◽  
David P. Fenning ◽  
Mariana I. Bertoni ◽  
Tonio Buonassisi ◽  
...  

The evolution of Fe-related defects is simulated for di erent P di usion gettering (PDG) processes which are applied during silicon solar cell processing. It is shown that the introduction of an extended PDG is bene cial for some as-grown Si materials but not essential for all of them. For mc-Si wafers with an as-grown Fe concentration 14 cm3, a good reduction of the Fei concentration and increase of the electron lifetime is achieved during standard PDG. For mc-Si wafers with a higher as-grown Fe concentration the introduction of defect engineering tools into the solar cell process seems to be advantageous. From comparison of standard PDG with extended PDG it is concluded that the latter leads to a stronger reduction of highly recombination active Fei atoms due to an enhanced segregation gettering e ect. For an as-grown Fe concentration between 1014 cm3 and 1015 cm3, this enhanced Fei reduction results in an appreciable increase in the electron lifetime. However, for an as-grown Fe concentration >1015 cm3, the PDG process needs to be optimized in order to reduce the total Fe concentration within the wafer as the electron lifetime after extended PDG keeps being limited by recombination at precipitated Fe.


Author(s):  
C.L. Briant

Grain boundary segregation is the process by which solute elements in a material diffuse to the grain boundaries, become trapped there, and increase their local concentration at the boundary over that in the bulk. As a result of this process this local concentration of the segregant at the grain boundary can be many orders of magnitude greater than the bulk concentration of the segregant. The importance of this problem lies in the fact that grain boundary segregation can affect many material properties such as fracture, corrosion, and grain growth.One of the best ways to study grain boundary segregation is with Auger electron spectroscopy. This spectroscopy is an extremely surface sensitive technique. When it is used to study grain boundary segregation the sample must first be fractured intergranularly in the high vacuum spectrometer. This fracture surface is then the one that is analyzed. The development of scanning Auger spectrometers have allowed researchers to first image the fracture surface that is created and then to perform analyses on individual grain boundaries.


Author(s):  
Brian Ralph ◽  
Barlow Claire ◽  
Nicola Ecob

This brief review seeks to summarize some of the main property changes which may be induced by altering the grain structure of materials. Where appropriate an interpretation is given of these changes in terms of current theories of grain boundary structure, and some examples from current studies are presented at the end of this paper.


2016 ◽  
Author(s):  
Frank Malgo ◽  
Neveen A T Hamdy ◽  
Alberto M Pereira ◽  
Nienke R Biermasz ◽  
Natasha M Appelman-Dijkstra

2015 ◽  
Vol 10 (2) ◽  
pp. 57-68 ◽  
Author(s):  
Klára Machalická ◽  
Martina Eliášová ◽  
Michal Netušil

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