Molecular Structures on Solid Substrates Probed by Sum Frequency Generation (SFG) Vibration Spectroscopy

2009 ◽  
Vol 38 (5) ◽  
pp. 386-391 ◽  
Author(s):  
Shen Ye ◽  
Masatoshi Osawa
2017 ◽  
Vol 19 (3) ◽  
pp. 2060-2066 ◽  
Author(s):  
Naoki Takeshita ◽  
Masanari Okuno ◽  
Taka-aki Ishibashi

Heterodyne-detected vibrational sum frequency generation spectroscopy was used to investigate molecular structures of DPPC monolayers on water (Langmuir monolayer) and monolayers on a fused silica substrate (Langmuir-Blodgett [LB] monolayer).


2011 ◽  
Vol 12 (7) ◽  
pp. 2434-2439 ◽  
Author(s):  
Anna L. Barnette ◽  
Laura C. Bradley ◽  
Brandon D. Veres ◽  
Edward P. Schreiner ◽  
Yong Bum Park ◽  
...  

Friction ◽  
2021 ◽  
Author(s):  
Zhifeng Liu ◽  
Mengmeng Liu ◽  
Caixia Zhang ◽  
Hongyan Chu ◽  
Liran Ma ◽  
...  

AbstractSum-frequency generation (SFG) vibrational spectroscopy is a second-order nonlinear optical spectroscopy technique. Owing to its interfacial selectivity, SFG vibrational spectroscopy can provide interfacial molecular information, such as molecular orientations and order, which can be obtained directly, or molecular density, which can be acquired indirectly. Interfacial molecular behaviors are considered the basic factors for determining the tribological properties of surfaces. Therefore, owing to its ability to detect the molecular behavior in buried interfaces in situ and in real time, SFG vibrational spectroscopy has become one of the most appealing technologies for characterizing mechanisms at friction interfaces. This paper briefly introduces the development of SFG vibrational spectroscopy and the essential theoretical background, focusing on its application in friction and lubrication interfaces, including film-based, complex oil-based, and water-based lubricating systems. Real-time detection using SFG promotes the nondestructive investigation of molecular structures of friction interfaces in situ with submonolayer interface sensitivity, enabling the investigation of friction mechanisms. This review provides guidance on using SFG to conduct friction analysis, thereby widening the applicability of SFG vibrational spectroscopy.


2012 ◽  
Vol 441 ◽  
pp. 703-707
Author(s):  
Xiao Lin Lu ◽  
Zhan Chen ◽  
Xin Ping Wang

In the last two decades, a nonlinear optical technique - sum frequency generation (SFG) vibrational spectroscopy was developed into a powerful characterization method to probe the molecular structures of various surfaces and interfaces in situ. In this paper, we gave a general introduction of the SFG theory and two case studies to demonstrate the power of the SFG spectroscopy.


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