Natural Rubber/In Situ Silica Nanocomposite of a High Silica Content

2005 ◽  
Vol 34 (5) ◽  
pp. 672-673 ◽  
Author(s):  
Sirilux Poompradub ◽  
Shinzo Kohjiya ◽  
Yuko Ikeda
2010 ◽  
Vol 93-94 ◽  
pp. 525-528 ◽  
Author(s):  
Torpong Sittiphan ◽  
Pattarapan Prasassarakich ◽  
Sirilux Poompradub

In situ silica filling of styrene grafted natural rubber (ST-g-NR) was carried out by using sol-gel reaction of tetraethoxysilane (TEOS). The effects of concentration of catalyst and reaction temperature on the in situ silica content were investigated. ST-g-NR was synthesized via an emulsion polymerization using cumene hydroperoxide (CHPO) and tetraethylene pentamine (TEPA) as initiators. The synthesized ST-g-NR was characterized by a Fourier Transform Infrared Spectroscopy (FTIR) and Proton Nuclear Magnetic Resonance Spectroscopy (1H NMR). The content of in situ silica generated in ST-g-NR matrix was determined by Thermogravimetry Analysis (TGA). In situ silica up to 50 parts per hundred rubbers by weight (phr) was successfully filled in the ST-g-NR matrix. The silica content increased with the increase of n-hexylamine concentration. However, the effect of reaction temperature was insignificant to silica content.


RSC Advances ◽  
2014 ◽  
Vol 4 (102) ◽  
pp. 58816-58825 ◽  
Author(s):  
Bharat P. Kapgate ◽  
Chayan Das

The strong CR/in situ silica interaction causes filler accumulation at the interphase and enhances the compatibility and reinforcement in the NR/CR blend.


2018 ◽  
Vol 92 (2) ◽  
pp. 219-236 ◽  
Author(s):  
Naresh D. Bansod ◽  
Bharat P. Kapgate ◽  
Pradip K. Maji ◽  
Anasuya Bandyopadhyay ◽  
Chayan Das

ABSTRACT Functionalization of non-polar ethylene propylene diene monomer (EPDM) rubber by melt grafting of maleic anhydride (MA) and in situ incorporation of sol–gel derived silica in the MA grafted EPDM has been done to prepare EPDM/silica composites to use dual benefits of both the approaches, which results in adequate rubber–filler compatibility, good filler dispersion, and enhanced composite properties. Controlled growth of silica up to 25 parts per hundred rubber (phr) is carried out with the solution sol–gel process using tetraethoxysilane (TEOS) as a silica precursor. Mechanical and dynamical properties of the composites are found to improve consistently as silica content increases. Furthermore, treatment of maleic anhydride grafted EPDM by γ-aminopropyltrimethoxysilane (γ-APS) results in remarkable improvement in composite properties even at the same silica content. This is attributed to the generation of uniformly dispersed spherically shaped nanosilica throughout the rubber matrix as observed in a transmission electron microscopic (TEM) study. This contributes to enhanced crosslinking density and improved rubber–filler interaction. In fact, the reinforcement effect brought by in situ silica relative to unmodified in situ silica/EPDM composites is found to be much higher than that reported in recent work on EPDM/in situ silica composites even with higher silica loading. The mechanical, rheological, and dynamic mechanical behaviors of all the composites are evaluated and compared in detail.


2009 ◽  
Vol 52 (2) ◽  
pp. 219-227 ◽  
Author(s):  
Benjawan Chaichua ◽  
Pattarapan Prasassarakich ◽  
Sirilux Poompradub

2017 ◽  
Vol 106 (2) ◽  
pp. 510-520 ◽  
Author(s):  
Basam A. E. Ben-Arfa ◽  
Hugo R. Fernandes ◽  
Isabel M. Miranda Salvado ◽  
José M. F. Ferreira ◽  
Robert C. Pullar

Polymer ◽  
2005 ◽  
Vol 46 (12) ◽  
pp. 4440-4446 ◽  
Author(s):  
Shinzo Kohjiya ◽  
Astushi Katoh ◽  
Junichi Shimanuki ◽  
Toshinori Hasegawa ◽  
Yuko Ikeda

2019 ◽  
Vol 342 ◽  
Author(s):  
Jean Gérard ◽  
Sébastien Paradis ◽  
Bernard Thibaut

Variability in the chemical composition of 614 species is described in a database containing measurements of wood polymers (cellulose, lignin and pentosan), as well as overall extraneous components (ethanol-benzene, or hot water extracts and ash, with a focus on silica content). These measurements were taken between 1945 and 1990 using the same standard protocol. In all, 1,194 trees belonging to 614 species, 358 genera and 89 families were measured. At species level, variability (quantified by the coefficient of variation) was rather high for density (27%), much lower for lignin and cellulose (14% and 10%) and much higher for ethanol/benzene extractives, hot water extractives and ash content (81%, 60% and 76%). Considering trees with at least five different specimens, and species with at least 10 different trees, it was possible to investigate within-tree and within-species variability. Large differences were found between trees of a given species for extraneous components, and more than one tree should be needed per species. For density, lignin, pentosan and cellulose, the distribution of values was nearly symmetrical, with mean values of 720 kg/m3 for density, 29.1% for lignin, 15.8% for pentosan, and 42.4% for cellulose. There were clear differences between species for lignin content. For extraneous components, the distribution was very dissymmetrical, with a minority of woods rich in this component composing the high value tail. A high value for any extraneous component, even in only one tree, is sufficient to classify the species in respect of that component. Siliceous woods identified by silica bodies in anatomy have a very high silica content and only those species deserve a silica study.


Sign in / Sign up

Export Citation Format

Share Document