A Novel Noninterpenetrated Open Framework Structure with Extraordinarily Large Cavity Sizes: A New Coordination Polymer Containing a Rigid and Bent Molecular Building Block

2002 ◽  
Vol 31 (8) ◽  
pp. 800-801 ◽  
Author(s):  
Dong Mok Shin ◽  
In Su Lee ◽  
Young Keun Chung
Keyword(s):  
Coordination Polymer ◽  
Building Block ◽  
Large Cavity ◽  
Framework Structure ◽  
Open Framework ◽  
Molecular Building Block ◽  
Open Framework Structure

scholarly journals Mechanochemical Access to Elusive Metal Diphosphinate Coordination Polymer

Crystals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 283 ◽  
Author(s):  
Andrea Ienco ◽  
Giulia Tuci ◽  
Annalisa Guerri ◽  
Ferdinando Costantino
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Crystalline Form ◽  
Framework Structure ◽  
Open Framework ◽  
Metal Organic ◽  
Two Phases ◽  
Bridge Length ◽  
Open Framework Structure

Several binary metal diphosphinate compounds (ML) have been reported for diphosphinate bonded by a single methylene fragment. In case of longer bridges, binary products are difficult to isolate in crystalline form. Here, using a solvent assisted mechano-chemistry synthesis, we report two new ML crystalline phases, one hydrated and one anhydrous. The hydrated phase is a 2D coordination polymer with an open framework structure. Its network displays a new topology for coordination polymers and metal organic frameworks. The thermal behavior of the two phases has been studied. Finally, the importance of the bridge length is discussed in view of known metal diphosphinate compounds.

scholarly journals Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer

Molecules ◽  
2015 ◽  
Vol 20 (5) ◽  
pp. 8020-8032 ◽  
Author(s):  
Ioana Grosu ◽  
Christiane Berghof ◽  
Peter Lönnecke ◽  
Luminita Silaghi-Dumitrescu ◽  
Evamarie Hey-Hawkins
Keyword(s):  
Coordination Polymer ◽  
Building Block ◽  
Diacetic Acid ◽  
Molecular Building Block

A unique uranyl framework containing uranyl pentamers as secondary building units: synthesis, structure, and spectroscopic properties

2020 ◽  
Vol 49 (12) ◽  
pp. 3676-3679 ◽  
Author(s):  
Yugang Zhang ◽  
Lanhua Chen ◽  
Jingwen Guan ◽  
Xia Wang ◽  
Shuao Wang ◽  
...  
Keyword(s):  
Spectroscopic Properties ◽  
Framework Structure ◽  
Open Framework ◽  
Secondary Building Units ◽  
Open Framework Structure ◽  
Framework Compounds

In this work, two uranyl framework compounds consisting of 1,2,4-benzenetricarboxylic ligands have been synthesized, and one of them adopts an open framework structure built from uranyl pentamers.

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