Supramolecular Assemblies Comprised of One-Dimensional Mixed Valence Platinum Complex and Anionic Amphiphiles in Organic Media

1998 ◽  
Vol 27 (7) ◽  
pp. 695-696 ◽  
Author(s):  
Nobuo Kimizuka ◽  
Noriko Oda ◽  
Toyoki Kunitake
Keyword(s):  
Mixed Valence ◽  
Platinum Complex ◽  
Supramolecular Assemblies ◽  
Organic Media ◽  
One Dimensional

scholarly journals Resonance Raman enhancement for photoinduced polaronic states of a quasi-one-dimensional mixed-valence platinum complex

1995 ◽  
Vol 52 (20) ◽  
pp. 14441-14444 ◽  
Author(s):  
J. Takeda ◽  
M. Okada ◽  
S. Kurita ◽  
K. Tanaka ◽  
T. Suemoto
Keyword(s):  
Mixed Valence ◽  
Resonance Raman ◽  
Platinum Complex ◽  
One Dimensional ◽  
Raman Enhancement

Photo-Induced Defect States in a Quasi One-Dimensional Mixed-Valence Platinum Complex

1988 ◽  
Vol 57 (5) ◽  
pp. 1789-1796 ◽  
Author(s):  
Susumu Kurita ◽  
Mikako Haruki ◽  
Kensuke Miyagawa
Keyword(s):  
Mixed Valence ◽  
Platinum Complex ◽  
Defect States ◽  
One Dimensional

EFFECT OF LIPID-PACKAGING ON THE CHARGE TRANSFER CHARACTERISTICS OF ONE-DIMENSIONAL, MIXED-VALENCE PLATINUM COMPLEXES

2002 ◽  
Vol 01 (05n06) ◽  
pp. 391-395 ◽  
Author(s):  
CHANG-SOO LEE ◽  
YASUHIRO HATANAKA ◽  
NOBUO KIMIZUKA
Keyword(s):  
Charge Transfer ◽  
Mixed Valence ◽  
Platinum Complexes ◽  
Organic Media ◽  
One Dimensional ◽  
Transfer Characteristics ◽  
Absorption Characteristics

Lipid-packaged platinum complexes of [ Pt ( en )2][ Pt X2( en )2] (X= Cl , Br , I ) are newly synthesized and their morphology and charge transfer (CT) absorption characteristics are compared in organic media. They show remarkably red-shifted CT absorption characteristics, which are ascribed to the significantly promoted exciton delocalization along the chains.

A one-dimensional chloride-bridged PtII/PtIVmixed-valence complex with a 4-[(4-hydroxyphenyl)diazenyl]benzenesulfonate counter-ion

2015 ◽  
Vol 71 (12) ◽  
pp. 1033-1036 ◽  
Author(s):  
Nobuyuki Matsushita ◽  
Ayako Taira
Keyword(s):  
Valence State ◽  
Title Compound ◽  
Linear Chain ◽  
Mixed Valence ◽  
Chain Structure ◽  
Structural Parameter ◽  
One Dimensional ◽  
Square Planar ◽  
Cl Atoms ◽  
Linear Chain Structure

The title compound,catena-poly[[[bis(ethylenediamine-κ2N,N′)platinum(II)]- μ-chlorido-[bis(ethylenediamine)platinum(IV)]-μ-chlorido] tetrakis{4-[(4-hydroxyphenyl)diazenyl]benzenesulfonate} dihydrate], {[PtIIPtIVCl2(C2H8N2)4](HOC6H4N=NC6H4SO3)4·2H2O}n, has a linear chain structure composed of square-planar [Pt(en)2]2+(en is ethylenediamine) and elongated octahedraltrans-[PtCl2(en)2]2+cations stacked alternately, bridged by Cl atoms, along thebaxis. The Pt atoms are located on an inversion centre, while the Cl atoms are disordered over two sites and form a zigzag ...Cl—PtIV—Cl...PtII... chain, with a PtIV—Cl bond length of 2.3140 (14) Å, an interatomic PtII...Cl distance of 3.5969 (15) Å and a PtIV—Cl...PtIIangle of 170.66 (6)°. The structural parameter indicating the mixed-valence state of the Pt atom, expressed by δ = (PtIV—Cl)/(PtII...Cl), is 0.643.

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