Mixed-Valence State of a One-Dimensional Platinum Complex with a Counter Ion Having Two Alkyl Chains and its Liquid Crystal Phase

2002 ◽  
Vol 379 (1) ◽  
pp. 297-302 ◽  
Author(s):  
Ayako Taira ◽  
Nobuyuki Matsushita
Keyword(s):  
Liquid Crystal ◽  
Valence State ◽  
Mixed Valence ◽  
Platinum Complex ◽  
Crystal Phase ◽  
Liquid Crystal Phase ◽  
One Dimensional ◽  
Alkyl Chains ◽  
Mixed Valence State ◽  
Counter Ion

Counter-ion radius dependence of the mixed-valence state in MX chain platinum complexes

1995 ◽  
Vol 71 (1-3) ◽  
pp. 1933-1934 ◽  
Author(s):  
Nobuyuki Matsushita ◽  
Hiroshi Kitagawa ◽  
Tadaoki Mitani
Keyword(s):  
Valence State ◽  
Mixed Valence ◽  
Platinum Complexes ◽  
Mixed Valence State ◽  
Counter Ion ◽  
Ion Radius

Halogen-bridged one-dimensional NiII-NiIV mixed-valence state and NiIII Mott-Hubbard state

1993 ◽  
Vol 56 (2-3) ◽  
pp. 3461-3468 ◽  
Author(s):  
M. Yamashita ◽  
E. Tsuruta ◽  
K. Inoue ◽  
T. Furuta ◽  
H. Okamoto ◽  
...  
Keyword(s):  
Valence State ◽  
Mixed Valence ◽  
One Dimensional ◽  
Mixed Valence State

Theory for the mixed-valence state

1979 ◽  
Vol 40 (C5) ◽  
pp. C5-374-C5-374 ◽  
Author(s):  
C. M. Varma
Keyword(s):  
Valence State ◽  
Mixed Valence ◽  
Mixed Valence State

MIXED VALENCE STATE OF Sm ON THE SURFACE OF AMORPHOUS La80-xSmxAu20 ALLOYS

1980 ◽  
Vol 41 (C8) ◽  
pp. C8-799-C8-802 ◽  
Author(s):  
G. Krill ◽  
A. Amamou ◽  
A. Berrada ◽  
J. Durand ◽  
N. Hassanain
Keyword(s):  
Valence State ◽  
Mixed Valence ◽  
Mixed Valence State

A one-dimensional chloride-bridged PtII/PtIVmixed-valence complex with a 4-[(4-hydroxyphenyl)diazenyl]benzenesulfonate counter-ion

2015 ◽  
Vol 71 (12) ◽  
pp. 1033-1036 ◽  
Author(s):  
Nobuyuki Matsushita ◽  
Ayako Taira
Keyword(s):  
Valence State ◽  
Title Compound ◽  
Linear Chain ◽  
Mixed Valence ◽  
Chain Structure ◽  
Structural Parameter ◽  
One Dimensional ◽  
Square Planar ◽  
Cl Atoms ◽  
Linear Chain Structure

The title compound,catena-poly[[[bis(ethylenediamine-κ2N,N′)platinum(II)]- μ-chlorido-[bis(ethylenediamine)platinum(IV)]-μ-chlorido] tetrakis{4-[(4-hydroxyphenyl)diazenyl]benzenesulfonate} dihydrate], {[PtIIPtIVCl2(C2H8N2)4](HOC6H4N=NC6H4SO3)4·2H2O}n, has a linear chain structure composed of square-planar [Pt(en)2]2+(en is ethylenediamine) and elongated octahedraltrans-[PtCl2(en)2]2+cations stacked alternately, bridged by Cl atoms, along thebaxis. The Pt atoms are located on an inversion centre, while the Cl atoms are disordered over two sites and form a zigzag ...Cl—PtIV—Cl...PtII... chain, with a PtIV—Cl bond length of 2.3140 (14) Å, an interatomic PtII...Cl distance of 3.5969 (15) Å and a PtIV—Cl...PtIIangle of 170.66 (6)°. The structural parameter indicating the mixed-valence state of the Pt atom, expressed by δ = (PtIV—Cl)/(PtII...Cl), is 0.643.

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