Time-resolved Infrared Spectroscopic Diagnosis of a Bimolecular Chemical Reaction in Room Temperature Solution. The CCl3Radical Produced from Photoexcited trans-Stilbene and Carbon Tetrachloride

1994 ◽  
Vol 23 (11) ◽  
pp. 2131-2134 ◽  
Author(s):  
Koichi Iwata ◽  
Shuichi Kataoka ◽  
Hiro-o Hamaguchi
Keyword(s):  
Carbon Tetrachloride ◽  
Chemical Reaction ◽  
Room Temperature ◽  
Time Resolved ◽  
Trans Stilbene ◽  
Infrared Spectroscopic ◽  
Bimolecular Chemical Reaction ◽  
Temperature Solution

Enhancement of conductivity in nano carbon balls by the addition of carbon tetrachloride via room temperature solution plasma process

RSC Advances ◽  
2016 ◽  
Vol 6 (57) ◽  
pp. 51864-51870 ◽  
Author(s):  
Oi Lun Li ◽  
Hiroki Hayashi ◽  
Takahiro Ishizaki ◽  
Nagahiro Saito
Keyword(s):  
Carbon Tetrachloride ◽  
Room Temperature ◽  
Plasma Zone ◽  
Plasma Process ◽  
Reaction Field ◽  
Temperature Solution ◽  
Nano Carbon

(a) Reaction field in solution plasma zone and dehydrogenation by Cl radicals, (b) enhancement of conductivity of nanocarbon sphere by the addition of CCl4 within benzene.

scholarly journals Time-resolved infrared (TRIR) study on the formation and reactivity of organometallic methane and ethane complexes in room temperature solution

2007 ◽  
Vol 104 (17) ◽  
pp. 6933-6938 ◽  
Author(s):  
A. J. Cowan ◽  
P. Portius ◽  
H. K. Kawanami ◽  
O. S. Jina ◽  
D. C. Grills ◽  
...  
Keyword(s):  
Room Temperature ◽  
Time Resolved ◽  
Temperature Solution

scholarly journals Room-Temperature Solution-Processed 0D/1D Bilayer Electrodes for Translucent CsPbBr3 Perovskite Photovoltaics

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1489
Author(s):  
Bhaskar Parida ◽  
Saemon Yoon ◽  
Dong-Won Kang
Keyword(s):  
Solar Cells ◽  
Indium Tin Oxide ◽  
High Performance ◽  
Room Temperature ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Ambient Air ◽  
Plasma Damage ◽  
Temperature Solution ◽  
Ito Nanoparticles

Materials and processing of transparent electrodes (TEs) are key factors to creating high-performance translucent perovskite solar cells. To date, sputtered indium tin oxide (ITO) has been a general option for a rear TE of translucent solar cells. However, it requires a rather high cost due to vacuum process and also typically causes plasma damage to the underlying layer. Therefore, we introduced TE based on ITO nanoparticles (ITO-NPs) by solution processing in ambient air without any heat treatment. As it reveals insufficient conductivity, Ag nanowires (Ag-NWs) are additionally coated. The ITO-NPs/Ag-NW (0D/1D) bilayer TE exhibits a better figure of merit than sputtered ITO. After constructing CsPbBr3 perovskite solar cells, the device with 0D/1D TE offers similar average visible transmission with the cells with sputtered ITO. More interestingly, the power conversion efficiency of 0D/1D TE device was 5.64%, which outperforms the cell (4.14%) made with sputtered-ITO. These impressive findings could open up a new pathway for the development of low-cost, translucent solar cells with quick processing under ambient air at room temperature.

Chapter Open for the Excited-State Intramolecular Thiol Proton Transfer in the Room-Temperature Solution

2021 ◽  
Author(s):  
Chun-Hsiang Wang ◽  
Zong-Ying Liu ◽  
Chun-Hao Huang ◽  
Chao-Tsen Chen ◽  
Fan-Yi Meng ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Room Temperature ◽  
Temperature Solution

Photophysical properties of N719 and Z907 dyes, benchmark sensitizers for dye-sensitized solar cells, at room and low temperature

2021 ◽  
Vol 23 (10) ◽  
pp. 6182-6189
Author(s):  
Dariusz M. Niedzwiedzki
Keyword(s):  
Solar Cells ◽  
Low Temperature ◽  
Optical Spectroscopy ◽  
Room Temperature ◽  
Photophysical Properties ◽  
Dye Sensitized Solar Cells ◽  
Time Resolved ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Photophysical properties of N719 and Z907, benchmark Ru-dyes used as sensitizers in dye-sensitized solar cells, were studied by static and time-resolved optical spectroscopy at room temperature and 160 K.

Ultraviolet light-emitting diode-assisted highly sensitive room temperature NO2 gas sensor for low-temperature solution-processed ZnO/TiO2 nanorods decorated with plasmonic Au nanoparticles

Nanoscale ◽  
2021 ◽  
Author(s):  
Soon-Hwan Kwon ◽  
Tae-Hyeon Kim ◽  
Sang-Min Kim ◽  
Semi Oh ◽  
Kyoung-Kook Kim
Keyword(s):  
Gas Sensors ◽  
High Performance ◽  
Room Temperature ◽  
Au Nanoparticles ◽  
Light Emitting Diode ◽  
Light Emitting ◽  
No2 Gas Sensor ◽  
Highly Sensitive ◽  
Temperature Solution ◽  
Semiconducting Metal Oxides

Nanostructured semiconducting metal oxides such as SnO2, ZnO, TiO2, and CuO have been widely used to fabricate high performance gas sensors. To improve the sensitivity and stability of gas sensors,...

Influence of Free Surface Environment on the Shear Zone in Metal Cutting

1966 ◽  
Vol 181 (1) ◽  
pp. 687-705 ◽  
Author(s):  
P. L. Barlow
Keyword(s):  
Free Surface ◽  
Carbon Tetrachloride ◽  
Strain Hardening ◽  
Shear Zone ◽  
Chemical Reaction ◽  
Cutting Forces ◽  
Metal Cutting ◽  
The Body ◽  
Surface Barrier ◽  
Rehbinder Effect

It has previously been suggested that the reduction in cutting forces obtained by the presence of fluids such as CCl4 on the backface or free surface of the forming chip was due to diffusion of the fluid into the body of the chip in the region of the shear zone. In the present work, experiments with carbon tetrachloride tagged with carbon-14 and with carbon tetrachloride tagged with chlorine-36 were performed with the object of assessing the extent of diffusion of lubricants into the chip when present on the free surface only. The results obtained disprove former hypotheses and suggest that the reduced cutting force is due solely to chemical reaction at the surface of the chip. Confirmation of the sensitivity of the surface of the deforming shear zone to change in surface condition was obtained by removing metal from this region by an electropolishing technique during slow speed cutting. By varying the electropolishing conditions increased or decreased cutting forces could be obtained. It is proposed that the result both of chemical reaction at the surface and of surface removal is to reduce the strain-hardening rate of the metal undergoing shear by reducing the surface barrier to the flow of dislocations out of the metal. The association of the surface reaction of carbon tetrachloride with a change in the strain-hardening characteristics of the metal in the shear zone leads to a classification of the backface phenomenon as a Rehbinder effect and enables this effect to be more closely defined than was hitherto possible. Evidence is also presented which indicates that the backface effect does not contribute to the reduction in cutting forces during rakeface lubrication and is therefore unimportant in practice where flood lubrication of the cutting region invariably occurs.

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