PALLADIUM-CATALYZED ALLYLATION OF KETONES AND ALDEHYDES WITH ALLYLIC CARBONATES VIA SILYL ENOL ETHERS UNDER NEUTRAL CONDITIONS

1983 ◽  
Vol 12 (8) ◽  
pp. 1325-1326 ◽  
Author(s):  
Jiro Tsuji ◽  
Ichiro Minami ◽  
Isao Shimizu
Keyword(s):  
Enol Ethers ◽  
Silyl Enol Ethers ◽  
Palladium Catalyzed ◽  
Neutral Conditions

scholarly journals Visible-light-driven palladium-catalyzed Dowd–Beckwith ring expansion/C–C bond formation cascade

2021 ◽  
Author(s):  
Li Chen ◽  
Li-Na Guo ◽  
Shuai Liu ◽  
Le Liu ◽  
Xin-Hua Duan
Keyword(s):  
Visible Light ◽  
Bond Formation ◽  
Palladium Catalysis ◽  
Ring Expansion ◽  
Enol Ethers ◽  
Silyl Enol Ethers ◽  
Visible Light Driven ◽  
Palladium Catalyzed

An intermolecular Dowd–Beckwith ring expansion/C–C bond formation is achieved through light-induced palladium catalysis. Not only styrenes but also the electron-rich alkenes such as silyl enol ethers and enamides were also compatible in this reaction.

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