Organometallic high-pressure reactions. 2. Aldol reaction of silyl enol ethers with aldehydes under neutral conditions

1983 ◽  
Vol 105 (23) ◽  
pp. 6963-6965 ◽  
Author(s):  
Yoshinori Yamamoto ◽  
Kazuhiro Maruyama ◽  
Kiyoshi Matsumoto
Keyword(s):  
High Pressure ◽  
Aldol Reaction ◽  
Enol Ethers ◽  
Silyl Enol Ethers ◽  
Neutral Conditions

The Aldol Reaction of Silyl Enol Ethers with Aldehydes in Aqueous Media

1992 ◽  
Vol 33 (12) ◽  
pp. 1625-1628 ◽  
Author(s):  
Shū Kobayashi ◽  
Iwao Hachiya
Keyword(s):  
Aldol Reaction ◽  
Aqueous Media ◽  
Enol Ethers ◽  
Silyl Enol Ethers

Aromatic aldehyde-selective aldol addition with aldehyde-derived silyl enol ethers

2018 ◽  
Vol 54 (4) ◽  
pp. 374-377 ◽  
Author(s):  
Takahiro Kawajiri ◽  
Reiya Ohta ◽  
Hiromichi Fujioka ◽  
Hironao Sajiki ◽  
Yoshinari Sawama
Keyword(s):  
Aromatic Aldehyde ◽  
Aldol Reaction ◽  
Aliphatic Aldehydes ◽  
Enol Ethers ◽  
Silyl Enol Ethers ◽  
Mukaiyama Aldol Reaction ◽  
Mukaiyama Aldol ◽  
Aldol Addition

Unprecedented chemoselectivity between aromatic and aliphatic aldehydes has been achieved in the Mukaiyama aldol reaction using aldehyde-derived silyl enol ethers.

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