scholarly journals Transition Metal-Catalyzed C–C Bond Formation Reactions Using Alkyl Halides

2006 ◽  
Vol 79 (5) ◽  
pp. 663-672 ◽  
Author(s):  
Jun Terao ◽  
Nobuaki Kambe
Keyword(s):  
Transition Metal ◽  
Bond Formation ◽  
Alkyl Halides ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Bond Formation Reactions

Transition-metal catalysed C–N bond activation

2016 ◽  
Vol 45 (5) ◽  
pp. 1257-1272 ◽  
Author(s):  
Quanjun Wang ◽  
Yijin Su ◽  
Lixin Li ◽  
Hanmin Huang
Keyword(s):  
Transition Metal ◽  
Bond Activation ◽  
Bond Formation ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Bond Formation Reactions

Efficient strategies for transition-metal catalyzed C–N bond activation and their applications in new C–X bond formation reactions are summarized.

Unactivated Alkyl Halides in Transition-Metal-Catalyzed C–H Bond Alkylation

ACS Catalysis ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 3268-3292
Author(s):  
Shidheshwar B. Ankade ◽  
Anand B. Shabade ◽  
Vineeta Soni ◽  
Benudhar Punji
Keyword(s):  
Transition Metal ◽  
Alkyl Halides ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

scholarly journals Transition Metal-Catalyzed α-Position Carbon–Carbon Bond Formations of Carbonyl Derivatives

Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 861 ◽  
Author(s):  
Ha-Eun Lee ◽  
Dopil Kim ◽  
Ahrom You ◽  
Myung Hwan Park ◽  
Min Kim ◽  
...  
Keyword(s):  
Transition Metal ◽  
Carbonyl Compounds ◽  
Bond Formation ◽  
Chiral Ligand ◽  
Catalytic Systems ◽  
Carbon Bond ◽  
Carbonyl Derivatives ◽  
Carbon Carbon Bond ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

α-Functionalization of carbonyl compounds in organic synthesis has traditionally been accomplished via classical enolate chemistry. As α-functionalized carbonyl moieties are ubiquitous in biologically and pharmaceutically valuable molecules, catalytic α-alkylations have been extensively studied, yielding a plethora of practical and efficient methodologies. Moreover, stereoselective carbon–carbon bond formation at the α-position of achiral carbonyl compounds has been achieved by using various transition metal–chiral ligand complexes. This review describes recent advances—in the last 20 years and especially focusing on the last 10 years—in transition metal-catalyzed α-alkylations of carbonyl compounds, such as aldehydes, ketones, imines, esters, and amides and in efficient carbon–carbon bond formations. Active catalytic species and ligand design are discussed, and mechanistic insights are presented. In addition, recently developed photo-redox catalytic systems for α-alkylations are described as a versatile synthetic tool for the synthesis of chiral carbonyl-bearing molecules.

Aryl—Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation

ChemInform ◽  
2007 ◽  
Vol 38 (22) ◽  
Author(s):  
Dino Alberico ◽  
Mark E. Scott ◽  
Mark Lautens
Keyword(s):  
Transition Metal ◽  
Bond Formation ◽  
Direct Arylation ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Synthesis of Cyclic Peptides via Transition Metal Catalyzed C-C Bond Formation

2006 ◽  
pp. 50-52
Author(s):  
Dirk T. S. Rijkers ◽  
Hefziba T. ten Brink ◽  
Nourdin Ghalit ◽  
Jan Tois ◽  
Rob M. J. Liskamp
Keyword(s):  
Transition Metal ◽  
Cyclic Peptides ◽  
Bond Formation ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed
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