Unactivated Alkyl Halides in Transition-Metal-Catalyzed C–H Bond Alkylation

ACS Catalysis ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 3268-3292
Author(s):  
Shidheshwar B. Ankade ◽  
Anand B. Shabade ◽  
Vineeta Soni ◽  
Benudhar Punji
Keyword(s):  
Transition Metal ◽  
Alkyl Halides ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

ChemInform Abstract: Transition-Metal-Catalyzed Alkylations of Amines with Alkyl Halides: Photoinduced, Copper-Catalyzed Couplings of Carbazoles.

ChemInform ◽  
2013 ◽  
Vol 44 (39) ◽  
pp. no-no
Author(s):  
Alex C. Bissember ◽  
Rylan J. Lundgren ◽  
Sidney E. Creutz ◽  
Jonas C. Peters ◽  
Gregory C. Fu
Keyword(s):  
Transition Metal ◽  
Alkyl Halides ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Transition-Metal-Catalyzed Alkylations of Amines with Alkyl Halides: Photoinduced, Copper-Catalyzed Couplings of Carbazoles

2013 ◽  
Vol 125 (19) ◽  
pp. 5233-5237 ◽  
Author(s):  
Alex C. Bissember ◽  
Rylan J. Lundgren ◽  
Sidney E. Creutz ◽  
Jonas C. Peters ◽  
Gregory C. Fu
Keyword(s):  
Transition Metal ◽  
Alkyl Halides ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Transition-Metal-Catalyzed Carboxylation of Organic Halides and Their Surrogates with Carbon Dioxide

Synthesis ◽  
2017 ◽  
Vol 50 (01) ◽  
pp. 35-48 ◽  
Author(s):  
Tian-Sheng Mei ◽  
Yue-Gang Chen ◽  
Xue-Tao Xu ◽  
Kun Zhang ◽  
Yi-Qian Li ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Transition Metal ◽  
Value Added ◽  
Alkyl Halides ◽  
Vinyl Halides ◽  
Organic Halides ◽  
Recent Developments ◽  
Benzyl Halides ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Carbon dioxide is not only an essential component of ‘greenhouse gases’, but also an abundant, renewable C1 feedstock in organic synthesis. The catalytic incorporation of carbon dioxide into value-added chemicals to produce carboxylic acids has received enormous attention. This review summarizes recent developments in the transition-metal-catalyzed carboxylation of organic halides and their surrogates, such as aryl, vinyl, and alkyl halides and pseudohalides.1 Introduction2 Carboxylation of Aryl Halides and Pseudohalides3 Carboxylation of Vinyl Halides and Pseudohalides4 Carboxylation of Benzyl Halides and Pseudohalides5 Carboxylation of Allyl Halides and Pseudohalides6 Carboxylation of Propargyl Halides and Pseudohalides7 Carboxylation of Alkyl Halides and Pseudohalides8 Direct Carboxylation of C–H Bonds9 Conclusions and Perspectives

scholarly journals Transition-Metal-Catalyzed Alkyl Heck-Type Reactions

Synthesis ◽  
2019 ◽  
Vol 51 (05) ◽  
pp. 985-1005 ◽  
Author(s):  
Daria Kurandina ◽  
Padon Chuentragool ◽  
Vladimir Gevorgyan
Keyword(s):  
Transition Metal ◽  
Organic Synthesis ◽  
Heck Reaction ◽  
Alkyl Halides ◽  
Analogous Reaction ◽  
Significant Progress ◽  
Alkyl Electrophiles ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

The Heck reaction is one of the most reliable and useful strategies for the construction of C–C bonds in organic synthesis. However, in contrast to the well-established aryl Heck reaction, the analogous reaction employing alkyl electrophiles is much less developed. Significant progress in this area was recently achieved by merging radical-mediated and transition-metal-catalyzed approaches. This review summarizes the advances in alkyl Heck-type reactions from its discovery early in the 1970s up until the end of 2018.1 Introduction2 Pd-Catalyzed Heck-Type Reactions2.1 Benzylic Electrophiles2.2 α-Carbonyl Alkyl Halides2.3 Fluoroalkyl Halides2.4 α-Functionalized Alkyl Halides2.5 Unactivated Alkyl Electrophiles3 Ni-Catalyzed Heck-Type Reactions3.1 Benzylic Electrophiles3.2 α-Carbonyl Alkyl Halides3.3 Unactivated Alkyl Halides4 Co-Catalyzed Heck-Type Reactions5 Cu-Catalyzed Heck-Type Reactions6 Other Metals in Heck-Type Reactions7 Conclusion

Transition-Metal-Catalyzed Alkylations of Amines with Alkyl Halides: Photoinduced, Copper-Catalyzed Couplings of Carbazoles

2013 ◽  
Vol 52 (19) ◽  
pp. 5129-5133 ◽  
Author(s):  
Alex C. Bissember ◽  
Rylan J. Lundgren ◽  
Sidney E. Creutz ◽  
Jonas C. Peters ◽  
Gregory C. Fu
Keyword(s):  
Transition Metal ◽  
Alkyl Halides ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed
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