Molecular Structure of Nitro- and Nitrito-Copper Complexes as Reaction Intermediates in Electrochemical Reduction of Nitrite to Dinitrogen Oxide

1995 ◽  
Vol 68 (2) ◽  
pp. 581-589 ◽  
Author(s):  
Nobutoshi Komeda ◽  
Hirotaka Nagao ◽  
Yoshinori Kushi ◽  
Gin-ya Adachi ◽  
Masatatsu Suzuki ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Electrochemical Reduction ◽  
Copper Complexes ◽  
Reaction Intermediates ◽  
Dinitrogen Oxide

Lateral Adsorbate Interactions Inhibit HCOO- While Promoting CO Selectivity for CO2 Electrocatalysis on Ag

2018 ◽  
Author(s):  
Divya Bohra ◽  
Isis Ledezma-Yanez ◽  
Guanna Li ◽  
Wiebren De Jong ◽  
Evgeny A. Pidko ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Experimental Approach ◽  
Decisive Role ◽  
Experimental Methods ◽  
Reaction Intermediates ◽  
Intermediate Species ◽  
Experimental Knowledge ◽  
Complex Interactions ◽  
Ag Catalysts

<p>The analysis presented in this manuscript helps bridge an important fundamental discrepancy between the existing theoretical and experimental knowledge regarding the performance of Ag catalysts for CO<sub>2</sub> electrochemical reduction (CO<sub>2</sub>ER). The results demonstrate how the intermediate species *OCHO is formed readily en-route the HCOO<sup>– </sup>pathway and plays a decisive role in determining selectivity of a predominantly CO producing catalyst such as Ag. Our theoretical and experimental approach develops a better understanding of the nature of competition as well as the complex interactions between the reaction intermediates leading to CO, HCOO<sup>–</sup> and H<sub>2</sub> during CO<sub>2</sub>ER.</p><p><br></p><p>Details of computational and experimental methods are present in the Supporting Information provided. </p><p><br></p><p><br></p>

Cyclopentadienyl iron xanthate complexes. Crystal and molecular structure and electrochemical reduction of η-C5R5Fe(CO)2(η1-SC(S)OEt) (RH or CH3)

1988 ◽  
Vol 143 (1) ◽  
pp. 59-70 ◽  
Author(s):  
Moisés Morán ◽  
Isabel Cuadrado ◽  
José R. Masaguer ◽  
José Losada ◽  
Concepcion Foces-Foces ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Electrochemical Reduction ◽  
Crystal And Molecular Structure

Lateral Adsorbate Interactions Inhibit HCOO- While Promoting CO Selectivity for CO2 Electrocatalysis on Ag

2018 ◽  
Author(s):  
Divya Bohra ◽  
Isis Ledezma-Yanez ◽  
Guanna Li ◽  
Wiebren De Jong ◽  
Evgeny A. Pidko ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Experimental Approach ◽  
Decisive Role ◽  
Experimental Methods ◽  
Reaction Intermediates ◽  
Intermediate Species ◽  
Experimental Knowledge ◽  
Complex Interactions ◽  
Ag Catalysts

<p>The analysis presented in this manuscript helps bridge an important fundamental discrepancy between the existing theoretical and experimental knowledge regarding the performance of Ag catalysts for CO<sub>2</sub> electrochemical reduction (CO<sub>2</sub>ER). The results demonstrate how the intermediate species *OCHO is formed readily en-route the HCOO<sup>– </sup>pathway and plays a decisive role in determining selectivity of a predominantly CO producing catalyst such as Ag. Our theoretical and experimental approach develops a better understanding of the nature of competition as well as the complex interactions between the reaction intermediates leading to CO, HCOO<sup>–</sup> and H<sub>2</sub> during CO<sub>2</sub>ER.</p><p><br></p><p>Details of computational and experimental methods are present in the Supporting Information provided. </p><p><br></p><p><br></p>

Syntheses and study on nickel and copper complexes with 1,3,5-benzenetricarboxylic acid. Crystal and molecular structure of [Cu3(mdpta)3(btc)](ClO4)3·4H2O

Polyhedron ◽  
2007 ◽  
Vol 26 (3) ◽  
pp. 535-542 ◽  
Author(s):  
Pavel Kopel ◽  
Jiří Kameníček ◽  
Václav Petříček ◽  
Aleš Kurečka ◽  
Božena Kalinska ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Copper Complexes ◽  
Crystal And Molecular Structure ◽  
Acid Crystal ◽  
Benzenetricarboxylic Acid

scholarly journals Electrochemical Reduction of Copper Complexes with Glycine, Alanine and Valine

2021 ◽  
Author(s):  
Paola Pary ◽  
Leandro Nicolas Bengoa ◽  
Leticia A. Azpeitia ◽  
Pablo R. Seré ◽  
José M. Ramallo-López ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Copper Complexes
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