scholarly journals Synergistic Extraction of Copper(II) and Zinc(II) with Tributyl Phosphate and Crown Ether

1986 ◽  
Vol 59 (10) ◽  
pp. 3003-3006 ◽  
Author(s):  
Yuko Hasegawa ◽  
Hirofumi Miyata ◽  
Satoshi Yoshida
1991 ◽  
Vol 7 (Supple) ◽  
pp. 51-54 ◽  
Author(s):  
YOSHIHIRO MEGURO ◽  
HIROSHI MUTO ◽  
ZENKO YOSHIDA

2010 ◽  
Vol 7 (1) ◽  
pp. 43-48
Author(s):  
Bambang Rusdiarso

Synergistic extraction of cobalt(II) with mixture of acyl-pyrazolon (HL) and crown-ether (E) in the Sr(NO3)2 environment has been studied. In this research, HPMBP (phenyl-1-methyl-3-benzoil-4-pyrazolon-5) was used, with three different kinds of  crown-ether, i.e. (benzo-15-crown-5), DB18C6 (dibenzo-18-crown-6) and DB24C8 (dibenzo-24-crown-8), in chloroform. In the bulk environment  of stronsium,  a cobalt coextraction and stronsium occured with species ESrNO3+,Co(PMBP)3-, and E = B15C5,    while Co(PMBP)2E and ESr,Co(PMBP3)2, with E = DB18C6. There was no  coextraction when using crown-ether DB24C8, with the extracted species Co(PMBP)2E. Values of extraction constant presented in log Kex were -6.08 (B15C5), - 4.51,  -12.55 (DB18C6), and - 4.57 (DB24C8), respectively.   Keywords: synergistic, cobalt (II), strontium (II), coextraction.


2001 ◽  
Vol 89 (7) ◽  
Author(s):  
M.L.P. Reddy ◽  
R. Meera

The synergistic extraction of thorium(IV) and uranium(VI) from nitric acid solutions has been investigated using mixtures of 3-phenyl-4-(4-fluorobenzoyl)-5-isoxazolone (HFBPI) and dicyclohexano-18-crown-6 (DC18C6), dibenzo-18-crown-6 (DB18C6) or benzo-15-crown-5 (B15C5). The results demonstrate that these metal ions are extracted into chloroform as Th(FBPI)


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