scholarly journals Palladium-catalyzed Displacement of Aryl Halide by Tin Analogue of Reformatsky Reagent

1985 ◽  
Vol 58 (11) ◽  
pp. 3383-3384 ◽  
Author(s):  
Masanori Kosugi ◽  
Yoshikazu Negishi ◽  
Masayuki Kameyama ◽  
Toshihiko Migita
Keyword(s):  
Aryl Halide ◽  
Reformatsky Reagent ◽  
Palladium Catalyzed

ChemInform Abstract: Palladium-Catalyzed Cyanide Metathesis: Utilization of Benzyl Cyanide as an Operator-Benign Reagent for Aryl Halide Cyanations.

ChemInform ◽  
2012 ◽  
Vol 43 (49) ◽  
pp. no-no
Author(s):  
Qiaodong Wen ◽  
Jisong Jin ◽  
Binbin Hu ◽  
Ping Lu ◽  
Yanguang Wang
Keyword(s):  
Aryl Halide ◽  
Benzyl Cyanide ◽  
Palladium Catalyzed

An Efficient Palladium-Catalyzed α-Arylation of Acetone Below its Boiling Point

Synlett ◽  
2020 ◽  
Vol 31 (15) ◽  
pp. 1532-1536
Author(s):  
Jeffery Richardson ◽  
Simon P. Mutton ◽  
Fionna M. Martin ◽  
Lesley Walton ◽  
Andrew J. Ledgard
Keyword(s):  
Drug Discovery ◽  
Boiling Point ◽  
Aryl Halide ◽  
Ambient Temperatures ◽  
Drug Discovery Program ◽  
Palladium Catalyzed ◽  
Discovery Program

The monoarylation of acetone is a powerful transformation, but is typically performed at temperatures significantly in excess of its boiling point. Conditions described for performing the reaction at ambient temperatures led to significant dehalogenation when applied to a complex aryl halide. We describe our attempts to overcome both issues in the context of our drug-discovery program.

ChemInform Abstract: Rate Enhancement of Palladium-Catalyzed Alkene to Alkenyl and Aryl Halide Couplings Under High Pressure.

ChemInform ◽  
2010 ◽  
Vol 25 (35) ◽  
pp. no-no
Author(s):  
K. VOIGT ◽  
U. SCHICK ◽  
F. E. MEYER ◽  
A. DE MEIJERE
Keyword(s):  
High Pressure ◽  
Aryl Halide ◽  
Rate Enhancement ◽  
Palladium Catalyzed

Rate Enhancement of Palladium-Catalyzed Alkene to Alkenyl and Aryl Halide Couplings under High Pressure

Synlett ◽  
1994 ◽  
Vol 1994 (03) ◽  
pp. 189-190 ◽  
Author(s):  
Katharina Voigt ◽  
Ute Schick ◽  
Frank E. Meyer ◽  
Armin de Meijere
Keyword(s):  
High Pressure ◽  
Aryl Halide ◽  
Rate Enhancement ◽  
Palladium Catalyzed

scholarly journals Recent Advances in the Applications of the Intramolecular Suzuki Cross-coupling Reaction in Cyclization and Heterocyclization: An Update

2020 ◽  
Vol 23 (22) ◽  
pp. 2469-2488 ◽  
Author(s):  
Majid M. Heravi ◽  
Masoumeh Malmir ◽  
Razieh Moradi
Keyword(s):  
Organic Chemistry ◽  
Boronic Acid ◽  
Heterocyclic Compounds ◽  
Aryl Halide ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Synthetic Organic Chemistry ◽  
Previous Review ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed

: The palladium-catalyzed reaction of aryl halide and boronic acid for the formation of C–C bonds so-called Suzuki–Miyaura cross-coupling reaction has many applications in Modern Synthetic Organic Chemistry. In 2013, we emphasized the applications of the intramolecular Suzuki cross-coupling reaction in cyclization and heterocyclization. Due to a plethora relevant papers appeared in the chemical literature, herein, we wish to cover by updating our previous review, the applications of the intramolecular Suzuki cross-coupling reaction in cyclization and heterocyclization leading to various homocyclic and heterocyclic compounds reported during a period of 2013 to 2018.

ChemInform Abstract: Palladium-Catalyzed Cross-Coupling of Indium Homoenolate with Aryl Halide with Wide Functional Group Compatibility.

ChemInform ◽  
2011 ◽  
Vol 42 (20) ◽  
pp. no-no
Author(s):  
Zhi-Liang Shen ◽  
Yin-Chang Lai ◽  
Colin Hong An Wong ◽  
Kelvin Kau Kiat Goh ◽  
Yong-Sheng Yang ◽  
...  
Keyword(s):  
Functional Group ◽  
Aryl Halide ◽  
Cross Coupling ◽  
Palladium Catalyzed

Palladium-catalyzed three-component reaction of N-tosylhydrazone, norbornene and aryl halide

2014 ◽  
Vol 12 (22) ◽  
pp. 3590-3593 ◽  
Author(s):  
Fangdong Hu ◽  
Ying Xia ◽  
Zhenxing Liu ◽  
Chen Ma ◽  
Yan Zhang ◽  
...  
Keyword(s):  
Aryl Halide ◽  
Type Reaction ◽  
Three Component Reaction ◽  
Migratory Insertion ◽  
Palladium Catalyzed

A palladium-catalyzed three-component reaction that involves an intermolecular Heck-type reaction and alkyl palladium carbene migratory insertion has been demonstrated.

Synthesis of Alkoxycarbonyldifluoromethyl-Substituted Semisquarates and Their Transformations

Synthesis ◽  
2018 ◽  
Vol 50 (08) ◽  
pp. 1687-1698 ◽  
Author(s):  
Yoshihiko Yamamoto ◽  
Takashi Kurohara ◽  
Jiang Jiyue ◽  
Masatoshi Shibuya
Keyword(s):  
Carboxylic Acid ◽  
Allylic Alcohol ◽  
Mild Conditions ◽  
Ring Transformations ◽  
Reformatsky Reagent ◽  
Palladium Catalyzed

A novel EtO2CCF2-substituted semisquarate is synthesized from diisopropyl squarate by selective 1,2-addition of the Reformatsky reagent derived from BrCF2CO2Et and subsequent rhenium-catalyzed allylic alcohol rearrangement. The compatibility of the highly reactive EtO2CCF2 group in ring transformations of the obtained semisquarate is investigated. Various EtO2CCF2-substituted, highly functionalized compounds, such as quinones, tetronates, cyclopentenones and a bicyclo-[3.2.0]heptenone, are successfully synthesized by ring transformations of the EtO2CCF2-substituted semisquarate. Also, an allylO2CCF2-substituted semisquarate is prepared and converted into the corresponding tetronate. Subsequent palladium-catalyzed deallylation followed by condensation of the resulting carboxylic acid with several amines under mild conditions affords the corresponding α,α-difluoroamides in good yields.

Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide

2011 ◽  
Vol 47 (16) ◽  
pp. 4778 ◽  
Author(s):  
Zhi-Liang Shen ◽  
Kelvin Kau Kiat Goh ◽  
Colin Hong An Wong ◽  
Yong-Sheng Yang ◽  
Yin-Chang Lai ◽  
...  
Keyword(s):  
Aryl Halide ◽  
Direct Synthesis ◽  
Cross Coupling ◽  
Palladium Catalyzed
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