Palladium-catalyzed three-component reaction of N-tosylhydrazone, norbornene and aryl halide

2014 ◽  
Vol 12 (22) ◽  
pp. 3590-3593 ◽  
Author(s):  
Fangdong Hu ◽  
Ying Xia ◽  
Zhenxing Liu ◽  
Chen Ma ◽  
Yan Zhang ◽  
...  
Keyword(s):  
Aryl Halide ◽  
Type Reaction ◽  
Three Component Reaction ◽  
Migratory Insertion ◽  
Palladium Catalyzed

A palladium-catalyzed three-component reaction that involves an intermolecular Heck-type reaction and alkyl palladium carbene migratory insertion has been demonstrated.

ChemInform Abstract: Palladium-Catalyzed Three-Component Reaction of N-Tosylhydrazone, Norbornene and Aryl Halide.

ChemInform ◽  
2014 ◽  
Vol 45 (43) ◽  
pp. no-no
Author(s):  
Fangdong Hu ◽  
Ying Xia ◽  
Zhenxing Liu ◽  
Chen Ma ◽  
Yan Zhang ◽  
...  
Keyword(s):  
Aryl Halide ◽  
Three Component Reaction ◽  
Palladium Catalyzed

Recent Developments in Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles

Synthesis ◽  
2020 ◽  
Author(s):  
Lili Shi ◽  
Junkai Fu ◽  
Shuangqiu Gao ◽  
Le Chang ◽  
Binglin Wang
Keyword(s):  
Heck Reaction ◽  
Alkyl Radicals ◽  
Type Reaction ◽  
The Past ◽  
Alkyl Electrophiles ◽  
Recent Developments ◽  
Palladium Catalyzed ◽  
Initial Work ◽  
Activated Olefins ◽  
Pseudo Halides

AbstractThe Mizoroki–Heck reaction is considered as one of the most ingenious and widely used methods for constructing C–C bonds. This reaction mainly focuses on activated olefins (styrenes, acrylates, or vinyl ethers) and aryl/vinyl (pseudo) halides. In comparison, the studies on unactivated alkenes and alkyl electrophiles are far less due to the low reactivity, poor selectivity, as well as competitive β-H elimination. In the past years, a growing interest has thus been devoted and significant breakthroughs have been achieved in the employment of unactivated alkenes and alkyl electrophiles as the reaction components, and this type of coupling is called as Heck-type or Heck-like reaction, which distinguishes from the traditional Heck reaction. Herein, we give a brief summary on Heck-type reaction between unactivated alkenes and alkyl electrophlies, covering its initial work, recent advancements, and mechanistic discussions.1 Introduction2 Intramolecular Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles2.1 Cobalt-Catalyzed Intramolecular Heck-Type Reaction2.2 Palladium-Catalyzed Intramolecular Heck-Type Reaction2.3 Nickel-Catalyzed Intramolecular Heck-Type Reaction2.4 Photocatalysis and Multimetallic Protocol for Intramolecular Heck-Type Reaction3 Intermolecular Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles3.1 Electrophilic Trifluoromethylating Reagent as Reaction Partners3.2 Alkyl Electrophiles as Reaction Partners4 Oxidative Heck-Type Reaction of Unactivated Alkenes and Alkyl Radicals5 Conclusions and Outlook

scholarly journals Palladium-catalyzed Tsuji–Trost-type reaction of benzofuran-2-ylmethyl acetates with nucleophiles

RSC Advances ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 909-917
Author(s):  
Antonio Arcadi ◽  
Giancarlo Fabrizi ◽  
Andrea Fochetti ◽  
Francesca Ghirga ◽  
Antonella Goggiamani ◽  
...  
Keyword(s):  
Nucleophilic Substitution ◽  
Type Reaction ◽  
Palladium Catalyzed

The palladium-catalyzed benzylic-like nucleophilic substitution of benzofuran-2-ylmethyl acetate with N, S, O and C soft nucleophiles.

ChemInform Abstract: Palladium-Catalyzed Cyanide Metathesis: Utilization of Benzyl Cyanide as an Operator-Benign Reagent for Aryl Halide Cyanations.

ChemInform ◽  
2012 ◽  
Vol 43 (49) ◽  
pp. no-no
Author(s):  
Qiaodong Wen ◽  
Jisong Jin ◽  
Binbin Hu ◽  
Ping Lu ◽  
Yanguang Wang
Keyword(s):  
Aryl Halide ◽  
Benzyl Cyanide ◽  
Palladium Catalyzed

Palladium‐Catalyzed Three‐Component Reaction of Allenes, Aryl Iodides, and Diazo Compounds: Approach to 1,3‐Dienes

2013 ◽  
Vol 125 (35) ◽  
pp. 9475-9478 ◽  
Author(s):  
Qing Xiao ◽  
Binglong Wang ◽  
Leiming Tian ◽  
Yang Yang ◽  
Jian Ma ◽  
...  
Keyword(s):  
Diazo Compounds ◽  
Aryl Iodides ◽  
Three Component Reaction ◽  
Palladium Catalyzed

A palladium-catalyzed three-component reaction for the preparation of quinazolin-4(3H)-imines

2012 ◽  
Vol 48 (23) ◽  
pp. 2903 ◽  
Author(s):  
Guanyinsheng Qiu ◽  
Gang Liu ◽  
Shouzhi Pu ◽  
Jie Wu
Keyword(s):  
Three Component Reaction ◽  
Palladium Catalyzed
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