scholarly journals The Substituent Effect. XII. Solvolysis of 3′- and 4′-Substituted 1-(4-Biphenylyl)ethyl Chlorides

1978 ◽  
Vol 51 (2) ◽  
pp. 596-600 ◽  
Author(s):  
Yuho Tsuno ◽  
Wei-Yuen Chong ◽  
Yoshihiko Tairaka ◽  
Masami Sawada ◽  
Yasuhide Yukawa
Keyword(s):  
Substituent Effect ◽  
Substituted 1

scholarly journals The Substituent Effect. XI. Solvolysis of 5-, 6-, and 7-Substituted 1-(1-Naphthylethyl) Chlorides

1975 ◽  
Vol 48 (11) ◽  
pp. 3356-3366 ◽  
Author(s):  
Yuho Tsuno ◽  
Masami Sawada ◽  
Takahiro Fujii ◽  
Yoshihiko Tairaka ◽  
Yasuhide Yukawa
Keyword(s):  
Substituent Effect ◽  
Substituted 1

ChemInform Abstract: SUBSTITUENT EFFECT. X. SOLVOLYSIS OF 3- AND 4-SUBSTITUTED 1-(1-NAPHTHYLETHYL) ) CHLORIDES

1976 ◽  
Vol 7 (7) ◽  
pp. no-no
Author(s):  
YUHO TSUNO ◽  
MASAMI SAWADA ◽  
TAKAHIRO FUJII ◽  
YASUHIDE YUKAWA
Keyword(s):  
Substituent Effect ◽  
Substituted 1

Acyclic versus cyclic π-electron delocalization. How is the substituent effect related to π-electron delocalization?

2009 ◽  
Vol 74 (1) ◽  
pp. 115-129 ◽  
Author(s):  
Michał A. Dobrowolski ◽  
Jędrzej Kaniewski ◽  
Tadeusz M. Krygowski ◽  
Michał K. Cyrański
Keyword(s):  
Electron Donor ◽  
Electron Acceptor ◽  
Substituent Effect ◽  
Electron Donors ◽  
Electron Delocalization ◽  
Benzene Derivatives ◽  
Phenol Derivatives ◽  
Stabilization Energies ◽  
Derivatives Of ◽  
Substituted 1

Substituent effect stabilization energies were estimated for sets of 27 para-substituted phenol derivatives, meta- and para-homodisubstituted benzene derivatives, trans-substituted ethenes, 4-substituted 1-hydroxy-1,3-cyclohexadienes and 1,4-homodisubstituted 1,3-cyclohexadienes based on the optimizations at the B3LYP/6-311+G** DFT level of theory. The following substituents were taken into account: C≡CH, C(CN)3, CF3, CH2NH2, CH3, CH=CH2, CHO, Cl, CN, COCH3, COCl, CONH2, COOCH3, COOH, F, NH2, NHCH3, N(CH3)2, NHOH, NO, NO2, OCH3, OH, Ph, H, SH, SO2CN. For hydroxyethenes and phenol derivatives the electron-acceptor substituents stabilize the systems, whereas the electron-donors lead to their destabilization. Both electron-acceptor and electron-donor substituents destabilize homodisubstituted ethene and meta- and para-homodisubstituted benzene species. The strongest destabilization is observed for derivatives of ethene, a weaker one for derivatives of cyclohexadiene and the weakest for benzene derivatives.

Substituent effect in electrochemical and ferricyanide oxidations of para-substituted 1-benzyl-3-carbamoyl-1,4-dihydropyridines

1983 ◽  
Vol 48 (5) ◽  
pp. 1408-1421 ◽  
Author(s):  
Františka Pavlíková-Raclová ◽  
Josef Kuthan
Keyword(s):  
Electrochemical Oxidation ◽  
Rate Constants ◽  
Substituent Effect ◽  
Potassium Ferricyanide ◽  
Rotating Disc Electrode ◽  
Disc Electrode ◽  
Rotating Disc ◽  
Half Wave ◽  
Substituted 1 ◽  
Dihydropyridine Derivatives

Half-wave potentials E1/2 of electrochemical oxidation of the title 1,4-dihydropyridine derivatives with the substituents N(CH3)2, OCH3, CH3, H, F, Cl, COOCH3, and CN have been measured on platinum rotating disc electrode in aqueous and anhydrous dimethylformamide, and apparent rate constants k2 of their oxidation with potassium ferricyanide have been measured in water at 298 K. The two quantities (E1/2 and k2) have been correlated both mutually and with empirical σp constants of the substituents. The found correlation relations have been discussed with respect to mechanism of the two transformations investigated.

scholarly journals The Substituent Effect. X. Solvolysis of 3- and 4-Substituted 1-(1-Naphthylethyl) Chlorides

1975 ◽  
Vol 48 (11) ◽  
pp. 3347-3355 ◽  
Author(s):  
Yuho Tsuno ◽  
Masami Sawada ◽  
Takahiro Fujii ◽  
Yasuhide Yukawa
Keyword(s):  
Substituent Effect ◽  
Substituted 1

scholarly journals The Substituent Effect. 14. The Solvolysis of 6- and 7-Substituted 1-(2-NaphthyI)ethyl Chlorides

1979 ◽  
Vol 52 (10) ◽  
pp. 3033-3042 ◽  
Author(s):  
Yuho Tsuno ◽  
Masami Sawada ◽  
Takahiro Fujii ◽  
Yasuhide Yukawa
Keyword(s):  
Substituent Effect ◽  
Substituted 1
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