scholarly journals Studies on Stable Free Radicals. XI. ESR Spectra of Stable Nitroxide Biradicals

1972 ◽  
Vol 45 (6) ◽  
pp. 1764-1766 ◽  
Author(s):  
Toshimasa Toda ◽  
Eiko Mori ◽  
Keisuke Murayama
Keyword(s):  
Free Radicals ◽  
Esr Spectra ◽  
Stable Free Radicals ◽  
Stable Nitroxide

scholarly journals Abnormal Hyperfine Splitting in the ESR Spectra of α,α,γ,γ-Tetraphenylallyl-type Organic Stable Free Radicals

1972 ◽  
Vol 45 (2) ◽  
pp. 371-375 ◽  
Author(s):  
Kohji Watanabe ◽  
Jun Yamauchi ◽  
Hiroaki Ohya-Nishiguchi ◽  
Yasuo Deguchi ◽  
Hideo Takaki
Keyword(s):  
Free Radicals ◽  
Hyperfine Splitting ◽  
Esr Spectra ◽  
Stable Free Radicals

Pyridyl-Substituted Thioaminyl Stable Free Radicals:  Isolation, ESR Spectra, and Magnetic Characterization1

1998 ◽  
Vol 63 (23) ◽  
pp. 8295-8303 ◽  
Author(s):  
Yozo Miura ◽  
Shinya Kurokawa ◽  
Masaaki Nakatsuji ◽  
Kenjiro Ando ◽  
Yoshio Teki
Keyword(s):  
Free Radicals ◽  
Esr Spectra ◽  
Stable Free Radicals

scholarly journals Studies on Stable Free Radicals. XII. ESR Spectra of 2-t-ButylaminotroponeN-Oxyl Radicals

1972 ◽  
Vol 45 (6) ◽  
pp. 1852-1854 ◽  
Author(s):  
Toshimasa Toda ◽  
Eiko Mori ◽  
Keisuke Murayama
Keyword(s):  
Free Radicals ◽  
Esr Spectra ◽  
Stable Free Radicals

The Use of Stable Free Radicals to Determine Motion in Polymeric Systems

1975 ◽  
Vol 48 (5) ◽  
pp. 1078-1089 ◽  
Author(s):  
Wilmer G. Miller ◽  
Zorica Veksli
Keyword(s):  
Glass Transition ◽  
Free Radicals ◽  
Diffusion Coefficients ◽  
Molecular Motion ◽  
Translational Diffusion ◽  
Glassy Polymers ◽  
Spin Labels ◽  
Polymeric Systems ◽  
Stable Free Radicals ◽  
Stable Nitroxide

Abstract The application of thermally and chemically stable nitroxide free radicals to a variety of motional problems in polymeric systems has been investigated. Solvents do not cause significant motion in glassy polymers until the glass transition is lowered to the temperature of measurement. With nonsolvents the results depend on the nature of the sample preparation as well as on the polymer-solvent pair. Molecular motion at the surface of a polymer immersed in a nonsolvent was investigated by means of surface-labeled latex spheres. The application of nitroxides as spin labels to the measurement of translational diffusion coefficients is explored and discussed. Finally, the application of the technique to adsorption and motion of surfactants and polymers onto surfaces is reported.

Synthesis and Application of Stable Nitroxide Free Radicals Fused with Carbocycles and Heterocycles

2019 ◽  
Vol 23 (4) ◽  
pp. 480-501 ◽  
Author(s):  
Balázs Bognár ◽  
Györgyi Úr ◽  
Cecília Sár ◽  
Olga H. Hankovszky ◽  
Kálmán Hideg ◽  
...  
Keyword(s):  
Free Radicals ◽  
Free Radical ◽  
Building Blocks ◽  
Spin Labels ◽  
Spin Probes ◽  
Electroactive Materials ◽  
The Past ◽  
Synthetic Methodologies ◽  
Stable Free Radicals ◽  
Stable Nitroxide

Stable nitroxide free radicals have traditionally been associated with 2,2,6,6- tetramethylpiperidine-1-oxyl (TEMPO) or its 4-substituted derivatives as relatively inexpensive and readily accessible compounds with limited possibilities for further chemical modification. Over the past two decades, there has been a resurgence of interest in stable free radicals with proper functionalization tuned for various applications. The objective of this review is to present recent results with synthetic methodologies to achieve stable nitroxide free radicals fused with aromatic carbocycles and heterocycles. There are two main approaches for accessing stable nitroxide free radicals fused with arenes, e.g., isoindoline- like nitroxides: further functionalization and oxidation of phthalimide or inventive functionalization of pyrroline nitroxide key compounds. The latter also offers the constructions of versatile heterocyclic scaffolds (furan, pyrrole, thiophene, 1,2-thiazole, selenophene, pyrazole, pyrimidine, pyridine, pyridazine, 1,5-benzothiazepine) that are fused with pyrroline or tetrahydropyridine nitroxide rings. The possible applications of these new stable nitroxide free radicals, such as covalent spin labels and noncovalent spin probes of proteins and nucleic acids, profluorescent probes, building blocks for construction of dual active drugs and electroactive materials, and substances for controlled free radical polymerization, are discussed.

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