scholarly journals The Thermal Decomposition of Dimethyl Ether in the Presence of Hydrogen Sulfide

1961 ◽  
Vol 34 (3) ◽  
pp. 328-334 ◽  
Author(s):  
Naomi Imai ◽  
Osamu Toyama
Keyword(s):  
Thermal Decomposition ◽  
Hydrogen Sulfide ◽  
Dimethyl Ether

Pyrolysis of ethane in the presence of hydrogen sulfide. Rates of formation of ethylene, hydrogen, and methane

1970 ◽  
Vol 48 (11) ◽  
pp. 1782-1785 ◽  
Author(s):  
P. R. McLean ◽  
D. J. McKenney
Keyword(s):  
Thermal Decomposition ◽  
Hydrogen Sulfide ◽  
Quantitative Data ◽  
Methane Formation ◽  
Partial Product ◽  
Complex Mechanism ◽  
Product Analysis ◽  
Hydrogen Formation

Rates of formation of ethylene, hydrogen, and methane have been measured at 630 °C for the thermal decomposition of ethane at pressures between 100 and 620 Torr, with various pressures (approximately 1 to 100 Torr) of added hydrogen sulfide. The effect of the H2S was to increase the rate of methane formation and to decrease the rate of ethylene and hydrogen formation. Rates of formation of all three of these gases decreased with increasing hydrogen sulfide pressures. The quantitative data obtained and the partial product analysis indicate that a complex mechanism is operative. Possible qualitative explanations for the observations are discussed.

Influence of Nitric Oxide on the Thermal Decomposition of Dimethyl Ether. Gaseous Catalysis

Nature ◽  
1936 ◽  
Vol 138 (3491) ◽  
pp. 546-547 ◽  
Author(s):  
P. F. GAY ◽  
MORRIS W. TRAVERS
Keyword(s):  
Nitric Oxide ◽  
Thermal Decomposition ◽  
Dimethyl Ether

On the thermal decomposition of dimethyl ether

1937 ◽  
Vol 33 ◽  
pp. 756 ◽  
Author(s):  
P. F. Gay ◽  
Morris W. Travers
Keyword(s):  
Thermal Decomposition ◽  
Dimethyl Ether

scholarly journals Roaming radicals in the thermal decomposition of dimethyl ether: Experiment and theory

2011 ◽  
Vol 158 (4) ◽  
pp. 618-632 ◽  
Author(s):  
R. Sivaramakrishnan ◽  
J.V. Michael ◽  
A.F. Wagner ◽  
R. Dawes ◽  
A.W. Jasper ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Dimethyl Ether

On reaction kinetics for the thermal decomposition of hydrogen sulfide

AIChE Journal ◽  
1999 ◽  
Vol 45 (2) ◽  
pp. 383-389 ◽  
Author(s):  
Kunal Karan ◽  
Anil K. Mehrotra ◽  
Leo A. Behie
Keyword(s):  
Thermal Decomposition ◽  
Hydrogen Sulfide ◽  
Reaction Kinetics
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