scholarly journals The Adsorption of Non-Polar Gases on Alkali Halide Crystals. II. Calculations of The Adsorption Behaviour of Non-Polar Gases on Cubic Sodium Chloride

1957 ◽  
Vol 30 (3) ◽  
pp. 236-243 ◽  
Author(s):  
Teruo Hayakawa
1998 ◽  
Vol 4 (1) ◽  
pp. 23-33 ◽  
Author(s):  
Heather C. Allen ◽  
Martha L. Mecartney ◽  
John C. Hemminger

Electron beam damage is a significant limitation for transmission electron microscopy (TEM) studies of beam-sensitive samples. An approach for studying surface reactions on alkali halide crystals using 200 kV TEM is presented. Experiments were designed to monitor the reaction of NaCl crystals with HNO3 gas followed by water vapor to form solid NaNO3. During beam damage experiments, TEM micrographs record structural changes to both NaCl and NaNO3, including dislocation loops, void formation, and decomposition. Sample decomposition can be successfully minimized by a combination of commonly used techniques: (1) focusing the beam adjacent to the area of interest, (2) lowering the electron density, (3) choosing to image larger (micrometer- versus submicrometer-sized) alkali halide crystals, and (4) lowering temperature by the use of a liquid nitrogen cooling stage. From these results, additional studies were designed that monitored sequential experiments. Sensitive micrometer-sized sodium chloride single crystals before and after exposure to nitric acid vapor and water vapor and the subsequent growth of submicrometer-sized sodium nitrate single crystals could then be successfully imaged using TEM.


1962 ◽  
Vol 15 (4) ◽  
pp. 504 ◽  
Author(s):  
JR Hanscomb

Doubt exists as to the mechanism responsible for electrical breakdown in alkali halide crystals at temperatures where the breakdown strength has generally been found to fall with rise in temperature. As thermal breakdown may be involved, experiments designed to examine this possibility in sodium chloride at 350 �0 have been conducted. It is shown that when linearly rising voltage transients are applied the dependence of breakdown strength on electrical conductivity, time, and energy input is in agreement with the impulse thermal theory for times to breakdown of the order of milliseconds. Conduction of heat is found to be an important factor as the time to breakdown is increased. Effects, such as dendrite growth, which are seen after breakdown with 10-second transients, are also discussed.


1997 ◽  
Vol 92 (6) ◽  
pp. 1029-1033
Author(s):  
A. BATANA ◽  
J. BRUNO ◽  
R.W. MUNN

2014 ◽  
Vol 252 (2) ◽  
pp. 380-385 ◽  
Author(s):  
A. Gektin ◽  
S. Gridin ◽  
S. Vasyukov ◽  
A. Vasil'ev ◽  
A. Belsky ◽  
...  

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