Advanced Membrane Materials for CO2 Separation from Natural Gas

2019 ◽  
pp. 112-149
Author(s):  
A.K. Zulhairun ◽  
N. Yusof ◽  
W.N.W. Salleh ◽  
F. Aziz ◽  
A.F. Ismail
Keyword(s):  
Natural Gas ◽  
Co2 Separation ◽  
Membrane Materials

Performance and Cost Analysis of Advanced Gas Turbine Cycles With Precombustion CO2 Capture

2008 ◽  
Vol 131 (2) ◽  
Author(s):  
Stéphanie Hoffmann ◽  
Michael Bartlett ◽  
Matthias Finkenrath ◽  
Andrei Evulet ◽  
Tord Peter Ursin
Keyword(s):  
High Pressure ◽  
Power Plant ◽  
Natural Gas ◽  
Gas Turbine ◽  
Co2 Capture ◽  
Gas Turbines ◽  
High Efficiency ◽  
Combined Cycle ◽  
Co2 Separation ◽  
The Cost

This paper presents the results of an evaluation of advanced combined cycle gas turbine plants with precombustion capture of CO2 from natural gas. In particular, the designs are carried out with the objectives of high efficiency, low capital cost, and low emissions of carbon dioxide to the atmosphere. The novel cycles introduced in this paper are comprised of a high-pressure syngas generation island, in which an air-blown partial oxidation reformer is used to generate syngas from natural gas, and a power island, in which a CO2-lean syngas is burnt in a large frame machine. In order to reduce the efficiency penalty of natural gas reforming, a significant effort is spent evaluating and optimizing alternatives to recover the heat released during the process. CO2 is removed from the shifted syngas using either CO2 absorbing solvents or a CO2 membrane. CO2 separation membranes, in particular, have the potential for considerable cost or energy savings compared with conventional solvent-based separation and benefit from the high-pressure level of the syngas generation island. A feasibility analysis and a cycle performance evaluation are carried out for large frame gas turbines such as the 9FB. Both short-term and long-term solutions have been investigated. An analysis of the cost of CO2 avoided is presented, including an evaluation of the cost of modifying the combined cycle due to CO2 separation. The paper describes a power plant reaching the performance targets of 50% net cycle efficiency and 80% CO2 capture, as well as the cost target of 30$ per ton of CO2 avoided (2006 Q1 basis). This paper indicates a development path to this power plant that minimizes technical risks by incremental implementation of new technology.

Toluene impurity effects on CO2 separation using a hollow fiber membrane for natural gas

2011 ◽  
Vol 369 (1-2) ◽  
pp. 490-498 ◽  
Author(s):  
Imona C. Omole ◽  
Dhaval A. Bhandari ◽  
Stephen J. Miller ◽  
William J. Koros
Keyword(s):  
Natural Gas ◽  
Hollow Fiber ◽  
Hollow Fiber Membrane ◽  
Co2 Separation ◽  
Fiber Membrane ◽  
Impurity Effects

scholarly journals Combination of surfactants and organic compounds for boosting CO2 separation from natural gas by clathrate hydrate formation

Fuel ◽  
2014 ◽  
Vol 122 ◽  
pp. 206-217 ◽  
Author(s):  
Marvin Ricaurte ◽  
Christophe Dicharry ◽  
Xavier Renaud ◽  
Jean-Philippe Torré
Keyword(s):  
Natural Gas ◽  
Organic Compounds ◽  
Hydrate Formation ◽  
Clathrate Hydrate ◽  
Co2 Separation

scholarly journals DEVELOPMENT OF MESOPOROUS MEMBRANE MATERIALS FOR CO2 SEPARATION

2003 ◽  
Author(s):  
Wei-Heng Shih ◽  
Tejas Patil ◽  
Qiang Zhao
Keyword(s):  
Co2 Separation ◽  
Membrane Materials ◽  
Mesoporous Membrane

Functionalized ionic liquid membranes for CO2 separation

2018 ◽  
Vol 54 (90) ◽  
pp. 12671-12685 ◽  
Author(s):  
Hongshuai Gao ◽  
Lu Bai ◽  
Jiuli Han ◽  
Bingbing Yang ◽  
Suojiang Zhang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Natural Gas ◽  
Flue Gas ◽  
Co2 Separation ◽  
Liquid Membranes ◽  
Functionalized Ionic Liquid

It is imperative to develop efficient, reversible and economic technologies for separating CO2 which mainly comes from flue gas, natural gas and syngas.

Influence of CO2 Nucleation Rate Towards Cryogenic Separation Technologies in Bulk CO2 Separation from Natural Gas

2014 ◽  
Author(s):  
A.A. Md Jalil ◽  
K. Rostani ◽  
R. Ahmad Samawe ◽  
N.A. Othman ◽  
M.A. Esa
Keyword(s):  
Natural Gas ◽  
Nucleation Rate ◽  
Co2 Separation

Molten Carbonate Fuel Cells for Retrofitting Postcombustion CO2 Capture in Coal and Natural Gas Power Plants

2018 ◽  
Vol 15 (3) ◽  
Author(s):  
Maurizio Spinelli ◽  
Stefano Campanari ◽  
Stefano Consonni ◽  
Matteo C. Romano ◽  
Thomas Kreutz ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Natural Gas ◽  
Co2 Capture ◽  
Power Plants ◽  
Combined Cycle ◽  
Co2 Separation ◽  
Molten Carbonate ◽  
Promising Alternative ◽  
Molten Carbonate Fuel Cells

The state-of-the-art conventional technology for postcombustion capture of CO2 from fossil-fueled power plants is based on chemical solvents, which requires substantial energy consumption for regeneration. A promising alternative, available in the near future, is the application of molten carbonate fuel cells (MCFC) for CO2 separation from postcombustion flue gases. Previous studies related to this technology showed both high efficiency and high carbon capture rates, especially when the fuel cell is thermally integrated in the flue gas path of a natural gas-fired combined cycle or an integrated gasification combined cycle plant. This work compares the application of MCFC-based CO2 separation process to pulverized coal fired steam cycles (PCC) and natural gas combined cycles (NGCC) as a “retrofit” to the original power plant. Mass and energy balances are calculated through detailed models for both power plants, with fuel cell behavior simulated using a 0D model calibrated against manufacturers' specifications and based on experimental measurements, specifically carried out to support this study. The resulting analysis includes a comparison of the energy efficiency and CO2 separation efficiency as well as an economic comparison of the cost of CO2 avoided (CCA) under several economic scenarios. The proposed configurations reveal promising performance, exhibiting very competitive efficiency and economic metrics in comparison with conventional CO2 capture technologies. Application as a MCFC retrofit yields a very limited (<3%) decrease in efficiency for both power plants (PCC and NGCC), a strong reduction (>80%) in CO2 emission and a competitive cost for CO2 avoided (25–40 €/ton).

Membrane Separation of CO2 from Natural Gas: A State-of-the-Art Review on Material Development

2013 ◽  
Vol 333 ◽  
pp. 135-147 ◽  
Author(s):  
Ahmad Abdul Latif ◽  
Jimoh K. Adewole ◽  
Suzylawati Binti Ismail ◽  
Leo Choe Peng ◽  
Abdullah S. Sultan
Keyword(s):  
Natural Gas ◽  
Large Scale ◽  
Membrane Separation ◽  
Primary Source ◽  
Reference Source ◽  
Separation Performance ◽  
Separation Processes ◽  
Membrane Materials ◽  
Material Development ◽  
Separation Of Gas Mixtures

Natural gas (NG) processing and membrane technology are two very important fields that are of great significance due to increasing demand for energy as well as separation of gas mixtures. While NG is projected to be the number one primary source of energy by 2050, membrane separation is a commercially successful competitor to other separation techniques for energy efficient gas separation processes [1]. Most of the NG produced in the world is coproduced with acid gases such as CO2which need to be removed to increase the caloric value of NG. A comprehensive review of research efforts in CO2separation from natural gas is required to capture details of the current scientific and technological progresses on the development of new membrane materials with better separation performance, and the improvement of properties of the existing ones. This paper presents the progress that has been achieved in eliminating the limitations that dominate the large scale application of membrane materials at the present time. Various polymers that have been developed to resist plasticization and the method employed to fabricate these polymers are highlighted. Also the range of plasticization pressures (together with corresponding selectivities and permeabilities at these pressures) that have so far been achieved by these fabrication methods is presented. It is believed that this review will serve as a good reference source especially for research in design and development of membrane materials with better resistance to CO2-induced plasticization.

scholarly journals DEVELOPMENT OF MESOPOROUS MEMBRANE MATERIALS FOR CO2 SEPARATION

2002 ◽  
Author(s):  
Wei-Heng Shih ◽  
Qiang Zhao ◽  
Nanlin Wang
Keyword(s):  
Co2 Separation ◽  
Membrane Materials ◽  
Mesoporous Membrane
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