Preparation of sulfonated polyether ether ketone (SPEEK) and optimization of degree of sulfonation for using in microbial fuel cells

2017 ◽  
Vol 5 (38) ◽  
pp. 20497-20504 ◽  
Author(s):  
G. Gnana kumar ◽  
Arumugam Manthiram

The use of SrZrO3@TiO2 nanocuboids as an inorganic filler in SPEEK membranes enhances their performance in DMFCs with a power density higher than that achieved with a Nafion 117 membrane.


2014 ◽  
Vol 595 ◽  
pp. 19-23 ◽  
Author(s):  
Shao Jie Lu ◽  
Xu Liu ◽  
Zi Qing Cai ◽  
Xiao Yu Meng ◽  
Qiong Zhou ◽  
...  

The montmorillonite (MMT)/multi walled carbon nanotube (MCNTs)/sulfonated polyether ether ketone (sPEEK) nanocomposite membrane were prepared by a method of solution casting for fuel cells application.The MMT and MCNTs were modified with sodium sulfanilateand poly (styrene sulfonic acid) (PSSA), respectively. The proton conductivity of theas-prepared membranes containing 0.5wt.% PSSA grafted MCNTs (PSS-g-MCNTs) and 0.5wt.% sulfonatedmontmorillonite (sMMT) increased by 0.013 Scm−1compared to the plain sPEEK.The tensile strength and yield strength of which increased by 34.37MPa and 34.20MPa relative to the 1.0 wt.% PSS-g-MCNTs loaded sPEEK, which indicated that PSS-g-MCNTs and sMMT may generate a proton conducting cocontinuous networkwithin the SPEEK matrix.


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