Eco-friendly approach for Direct Blue 273 removal from an aqueous medium

2014 ◽  
pp. 169-186
Keyword(s):  
2019 ◽  
Vol 63 (4) ◽  
Author(s):  
Juan Antonio Lozano-Alvarez ◽  
Juan Jáuregui-Rincón ◽  
Iliana Medina-Ramírez ◽  
Claudio Frausto-Reyes ◽  
Rogelio Salinas-Gutiérrez

The interaction among Xanthan (XANT) and three azo dyes: Direct blue 1 (DB1), Direct red 81 (DR81), and Direct black 22 (DB22) was studied. The Xanthan-dye-Al product was formed after the addition of AlCl3 to a Xanthan-Dye adduct containing solution. It was proposed that polyhydroxyoxoaluminum clusters named CAL-13 and CAL-30 react with this adduct producing a Xanthanate aluminum network, XANT-Al, and as a consequence a decrease in dye concentration in an aqueous medium was observed. The removal efficiencies obtained were the following: DB1 (99 %), DB22 (99 %) and DR81 (94 %), demonstrating that this dye removal method is very efficient. The Zimm-Bragg model adequately described the experimental data and the order observed in the Ku (nucleation) and U (aggregation) parameters from this model was the following: DB1>DB22> DR81. Evidence suggests that physicochemical properties of dyes such as charge, molecular weight, aggregation ability and the capacity of XANT-Al to trap dye molecules are involved in the high removal values. Moreover, the dye binding mechanisms include: electrostatic, hydrogen bonding and hydrophobic interactions that determine the magnitude of the parameters Ku and U. These findings suggest that the XANT polymer is a good option to remove azo dyes from an aqueous medium.


2005 ◽  
Vol 123 ◽  
pp. 341-344
Author(s):  
A. Khaldoun ◽  
F. González-Caballero ◽  
J. G. López-Durán ◽  
N. Mahrach ◽  
M. L. Kerkeb

2020 ◽  
Author(s):  
Keyword(s):  

2017 ◽  
Vol 39 (1) ◽  
pp. 46-52
Author(s):  
T. SAVCHENKO ◽  
◽  
A. GRECHANOVSKY ◽  
A. BRIK ◽  
N. DUDCHENKO

2019 ◽  
Author(s):  
Chem Int

The removal of Cd(II) and Pb(II) ions from aqueous medium was studied using potato peels biomass. The adsorption process was evaluated using Atomic Absorption Spectrophotometer (AAS). The Vibrational band of the potato peels was studied using Fourier Transform Infrared Spectroscopy (FTIR). The adsorption process was carried out with respect to concentration, time, pH, particle size and the thermodynamic evaluation of the process was carried at temperatures of 30, 40, 50 and 60(0C), respectively. The FTIR studies revealed that the potato peels was composed of –OH, -NH, –C=N, –C=C and –C-O-C functional groups. The optimum removal was obtained at pH 8 and contact time of 20 min. The adsorption process followed Freundlich adsorption and pseudo second-order kinetic models with correlation coefficients (R2) greater than 0.900. The equilibrium adsorption capacity showed that Pb(II) ion was more adsorbed on the surface of the potato peels biomass versus Cd (II) ion (200.91 mg/g > 125.00 mg/g). The thermodynamic studies indicated endothermic, dissociative mechanism and spontaneous adsorption process. This study shows that sweet potato peels is useful as a low-cost adsorbent for the removal of Cd(II) and Pb(II) ions from aqueous medium.


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