Pt/Pd–Ethynyl Bond Containing Fluorescent Molecular Architectures as Sensors for Nitroaromatics

2012 ◽  
pp. 275-316 ◽  
Keyword(s):  
Molecular Architectures

Catalyst-Control over Sixfold Stereogenicity

2020 ◽  
Author(s):  
Xingxing Wu ◽  
Reto M. Witzig ◽  
Rodolphe Beaud ◽  
Christian Fischer ◽  
Daniel Häussinger ◽  
...  
Keyword(s):  
Conformational Analysis ◽  
Higher Order ◽  
Binary Codes ◽  
Rotational Barriers ◽  
Molecular Architectures

Governing higher-order stereogenicity is a long-standing goal in stereoselective catalysis, because it allows to achieve selectivity for more than a twofold number of stereoisomers per stereogenic unit. Current methods warrant control over the power of two stereoisomers and the configurations are routinely assigned using the descriptors ( R ) and ( S ), or related binary codes. In contrast, conformational analysis ranges beyond this dualistic treatment of stereoisomerism, which constitutes an unmet challenge for catalyst stereocontrolled processes. Herein, we now report that sixfold stereogenicity can be governed by stereoselective catalysis. By controlling a configurationally stable stereogenic axis with six large rotational barriers, a catalytic [2+2+2]-cyclotrimerization selectively governs the formation of one out of six stereoisomers with up to 0:0:2:98:0:0 stereocontrol. The underpinnings of conformational analysis and stereoselective catalysis are thereby conceptually reunited. Novel molecular architectures featuring distinct chemical topologies and unexplored chemical designs are anticipated from catalystcontrol over higher-order stereogenicities

Differentiation and Functionalization of Adjacent, Remote C–H Bonds

2019 ◽  
Author(s):  
Hang Shi ◽  
Lu Yi ◽  
Jiang Weng ◽  
Katherine Bay ◽  
Xiangyang Chen ◽  
...  
Keyword(s):  
Catalytic System ◽  
Functional Group ◽  
Hydrocinnamic Acid ◽  
Molecular Architectures ◽  
Site Selective ◽  
Developing Strategies

<p>Site-selective functionalizations of C–H bonds will ultimately afford chemists transformative tools for editing and constructing complex molecular architectures<sup>1-4</sup>. Towards this goal, developing strategies to activate C–H bonds that are distal from a functional group is essential<sup>4-6</sup>. In this context, distinguishing remote C–H bonds on adjacent carbon atoms is an extraordinary challenge due to the lack of electronic or steric bias between the two positions. Herein, we report the design of a catalytic system leveraging a remote directing template and a transient norbornene mediator to selectively activate a previously inaccessible remote C–H bond that is one bond further away. The generality of this approach has been demonstrated with a range of heterocycles, including a complex anti-leukemia agent, and hydrocinnamic acid substrates.</p>

Recent Advances in the Total Synthesis of Clavaminols

Synthesis ◽  
2018 ◽  
Vol 50 (23) ◽  
pp. 4569-4576
Author(s):  
Tian Jin ◽  
Lu Zhao ◽  
Zhe-Bin Zheng ◽  
Xiao Liu ◽  
Liang Sun ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Research Groups ◽  
Total Syntheses ◽  
New Class ◽  
Recent Advances ◽  
Molecular Architectures ◽  
Synthetic Approaches ◽  
Long Chain

Clavaminols are a new class of long-chain 2-amino-3-­alkanols that mostly contain 2R,3S-configurations. Owing to their interesting molecular architectures and promising activities, they have ­become popular targets for synthetic organic chemists. In this review, we highlight 12 total syntheses of clavaminols from different research groups during the period 2009 to 2018.1 Introduction2 Synthetic Approaches toward Clavaminols2.1 Total Synthesis by Chemla and Colleagues (2009)2.2 Total Synthesis by Greck and Colleagues (2010)2.3 Total Synthesis by Sutherland and Zaed (2011)2.4 Total Synthesis by Huang and Colleagues (2011)2.5 Total Synthesis by Kotora and Colleagues (2012)2.6 Total Synthesis by Kumar and Colleagues (2013)2.7 Total Synthesis by Prabhavathi Devi and Colleagues (2013 and 2016)2.8 Total Synthesis by Sarabia and Colleagues (2014)2.9 Total Synthesis by Mohapatra and Colleagues (2016)2.10 Total Synthesis by Lu and Colleagues (2016)2.11 Total Synthesis by Jin and Colleagues (2017)2.12 Total Synthesis by Kumar Pandey and Colleagues (2018)3 Conclusion

Tailoring molecular architectures of Fe phthalocyanine on nanocarbon supports for high oxygen reduction performance

2015 ◽  
Vol 3 (18) ◽  
pp. 10013-10019 ◽  
Author(s):  
Shiming Zhang ◽  
Heyou Zhang ◽  
Xing Hua ◽  
Shengli Chen
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Alkaline Solution ◽  
Electrocatalytic Activity ◽  
Reduction Reaction ◽  
High Oxygen ◽  
Molecular Architectures

Tailored molecular architectures of FePc on nanocarbon supports from nanorods to uniform shells exhibit excellent electrocatalytic activity for the oxygen reduction reaction in alkaline solution.

Comparison of MukB homodimer versus MukBEF complex molecular architectures by electron microscopy reveals a higher-order multimerization

2005 ◽  
Vol 333 (3) ◽  
pp. 694-702 ◽  
Author(s):  
Kyoko Matoba ◽  
Mitsuyoshi Yamazoe ◽  
Kouta Mayanagi ◽  
Kosuke Morikawa ◽  
Sota Hiraga
Keyword(s):  
Electron Microscopy ◽  
Higher Order ◽  
Molecular Architectures

scholarly journals Continuous distribution model for the investigation of complex molecular architectures near interfaces with scattering techniques

2011 ◽  
Vol 110 (10) ◽  
pp. 102216 ◽  
Author(s):  
Prabhanshu Shekhar ◽  
Hirsh Nanda ◽  
Mathias Lösche ◽  
Frank Heinrich
Keyword(s):  
Continuous Distribution ◽  
Distribution Model ◽  
Molecular Architectures

Bistable mixed-valence molecular architectures for bit storage

1994 ◽  
Vol 183 (1) ◽  
pp. 45-59 ◽  
Author(s):  
Nathalie Guihery ◽  
Gérard Durand ◽  
Marie-Bernadette Lepetit
Keyword(s):  
Mixed Valence ◽  
Molecular Architectures
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