Supramolecular Complex Design and Function for Photodynamic Therapy and Solar Energy Conversion via Hydrogen Production: Common Requirements for Molecular Architectures for Varied Light-Activated Processes

2012 ◽  
pp. 268-313
Keyword(s):  
Photodynamic Therapy ◽  
Hydrogen Production ◽  
Solar Energy ◽  
Energy Conversion ◽  
Solar Energy Conversion ◽  
Supramolecular Complex ◽  
Complex Design ◽  
Activated Processes ◽  
Molecular Architectures ◽  
And Function

scholarly journals Design of BODIPY dyes as triplet photosensitizers: electronic properties tailored for solar energy conversion, photoredox catalysis and photodynamic therapy

2021 ◽  
Author(s):  
Elena Bassan ◽  
Andrea Gualandi ◽  
Pier Giorgio Cozzi ◽  
Paola Ceroni
Keyword(s):  
Heavy Metal ◽  
Photodynamic Therapy ◽  
Solar Energy ◽  
Metal Complexes ◽  
Energy Conversion ◽  
Electronic Properties ◽  
Solar Energy Conversion ◽  
Photoredox Catalysis

BODIPYs offer a versatile platform to build organic triplet photosensitisers for PDT, TTA upconversion and photocatalysis. Tuning their properties provides the opportunity of replacing heavy-metal complexes and can lead to improved sustainability.

Spatial distribution of active sites on a ferroelectric PbTiO3 photocatalyst for photocatalytic hydrogen production

2017 ◽  
Vol 198 ◽  
pp. 463-472 ◽  
Author(s):  
Rengui Li ◽  
Yue Zhao ◽  
Can Li
Keyword(s):  
Spatial Distribution ◽  
Hydrogen Production ◽  
Solar Energy ◽  
Energy Conversion ◽  
Electric Fields ◽  
Charge Separation ◽  
Active Sites ◽  
Solar Energy Conversion ◽  
Photogenerated Electrons ◽  
The Right

The separation of photogenerated charge carries is a challenging issue in artificial photocatalyst systems for solar energy conversion. It has been reported that spatial charge separation can take place between different facets of semiconductor-based crystals with regular morphology and facets, which could be used to rationally deposit cocatalysts on the right facets. However, the spatial separation of photogenerated electrons and holes is still a big challenge for a particulate photocatalyst without regular morphology and specific facets. In this work, we demonstrated that photogenerated electrons and holes can be regularly separated on ferroelectric PbTiO3 photocatalyst even without regular morphology and facets. The reduction cocatalyst and oxidation cocatalyst could be selectively formed on different sites via an in situ photochemical deposition method. It is found that the photoactivity and hydrogen production for PbTiO3 with spatially separated dual-cocatalysts is remarkably enhanced to more than 100 times greater compared to native PbTiO3, which is much higher than that the case of dual-cocatalysts with a random distribution. The intrinsic electric fields and spontaneous electric polarization in the bulk of PbTiO3 are proposed to play important roles in the spatial distribution of active sites on irregular PbTiO3 particles. Our work emphasizes the essential roles of two important factors, efficient charge separation strategy and the location of dual-cocatalysts on the right sites, to construct integrated artificial photocatalyst systems for solar energy conversion.

scholarly journals NANOTECHNOLOGY MATERIALS FOR SOLAR ENERGY CONVERSION

2013 ◽  
Vol 4 (2) ◽  
Author(s):  
Svetlana Pelemiš ◽  
Igor Hut
Keyword(s):  
Hydrogen Production ◽  
Solar Energy ◽  
Energy Conversion ◽  
Production Technology ◽  
Energy Production ◽  
Scientific Community ◽  
Sustainable Energy ◽  
Solar Energy Conversion ◽  
Common Word ◽  
Paper Briefly

Nanotechnology is a common word these days, although only 15 years ago it was a quite obscure term used almost exclusively in scientific community. It is a fact that nanotechnology is widely present today with numerous applications, especially regarding novel materials. This is a technology that draws a lot of attention not only in the scientific community but also among investors, governments and industry. There is a great deal of expectations connected with it and especially, amongst others, concerning sustainable energy production. This paper briefly explores some of possible implementations of nanotechnology for new and improved energy conversion methods, considering a need for this to be done without doing harm to our environment. Focus is placed on advanced photovoltaic and hydrogen production technology.

Formation, Detection, and Function of Oxygen Vacancy in Metal Oxides for Solar Energy Conversion

2021 ◽  
pp. 2109503
Author(s):  
Zhiliang Wang ◽  
Rijia Lin ◽  
Yuning Huo ◽  
Hexing Li ◽  
Lianzhou Wang
Keyword(s):  
Solar Energy ◽  
Oxygen Vacancy ◽  
Metal Oxides ◽  
Energy Conversion ◽  
Solar Energy Conversion ◽  
And Function
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