Mesoporous Hybrid Titania and Silica F ilms Prepared Via Post-Synthesis Grafting of a Luminescent Zinc Complex

Keyword(s):  
Author(s):  
Daniela Aiello ◽  
Luca Malfatti ◽  
Tongjit Kidchob ◽  
Rosario Aiello ◽  
Flaviano Testa ◽  
...  

2018 ◽  
Vol 21 (7) ◽  
pp. 462-467
Author(s):  
Babak Sadeghi

Aim and Objective: Ultrafine Ag/ZnO nanotetrapods (AZNTP) have been prepared successfully using silver (I)–bis (oxalato) zinc complex and 1, 3-diaminopropane (DAP) with a phase separation system, and have been injected into a diethyl/water solution. Materials and Methods: This crystal structure and lattice constant of the AZNTP obtained were investigated by means of a SEM, XRD, TEM and UV-vis spectrum. Results: The results of the present study demonstrated the growth and characterization AZNTP for humidity sensing and DAP plays a key role in the determination of particle morphology. AZNTP films with 23 nm in arm diameter have shown highly sensitive, quick response sensor material that works at room temperature.


Author(s):  
Xiaoling Bao ◽  
Jianhong Liu ◽  
Qingshu Zheng ◽  
Lixin Duan ◽  
Yuzhu Zhang ◽  
...  

2021 ◽  
Vol 1643 ◽  
pp. 462072
Author(s):  
Canhong Zhu ◽  
Jiani Wu ◽  
Xueting Jin ◽  
Yinghua Yan ◽  
Chuan-Fan Ding ◽  
...  

Nanomaterials ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 46
Author(s):  
Jae Hyun Kim ◽  
Joohoon Kim

Here, we report a post-synthesis functionalization of the shell of Au nanoclusters (NCs) synthesized using glutathione as a thiolate ligand. The as-synthesized Au NCs are subjected to the post-synthesis functionalization via amidic coupling of dopamine on the cluster shell to tailor photoluminescence (PL) and electrochemiluminescence (ECL) features of the Au NCs. Because the NCs’ PL at ca. 610 nm is primarily ascribed to the Au(I)-thiolate (SG) motifs on the cluster shell of the NCs, the post-synthesis functionalization of the cluster shell enhanced the PL intensity of the Au NCs via rigidification of the cluster shell. In contrast to the PL enhancement, the post-synthesis modification of the cluster shell does not enhance the near-infrared (NIR) ECL of the NCs because the NIR ECL at ca. 800 nm is ascribed to the Au(0)-SG motifs in the metallic core of the NCs.


Author(s):  
Maciej Trejda ◽  
Magdalena Drobnik ◽  
Ardian Nurwita

AbstractMesoporous silica of SBA-15 type was modified for the first time with 3-(trihydroxysiyl)-1-propanesulfonic acid (TPS) by post-synthesis modification involving microwave or conventional heating in order to generate the Brønsted acidic centers on the material surface. The samples structure and composition were examined by low temperature N2 adsorption/desorption, XRD, HRTEM, elemental and thermal analyses. The surface properties were evaluated by esterification of acetic acid with n-hexanol used as the test reaction. A much higher efficiency of TPS species incorporation was reached with the application of microwave radiation for 1 h than conventional modification for 24 h. It was found that the structure of mesoporous support was preserved after modification using both methods applied in this study. Materials obtained with the use of microwave radiation showed a superior catalytic activity and high stability.


RSC Advances ◽  
2016 ◽  
Vol 6 (21) ◽  
pp. 17474-17482 ◽  
Author(s):  
Pierpaolo Minei ◽  
Elisabetta Fanizza ◽  
Antonio M. Rodríguez ◽  
Ana B. Muñoz-García ◽  
Paola Cimino ◽  
...  

A red light and concentrated zinc complex embedded in PMMA yields a cost-effective and efficient luminescent solar concentrator.


2010 ◽  
Vol 63 (8) ◽  
pp. 1312
Author(s):  
X. Xue ◽  
B. F. Abrahams ◽  
R.-G. Xiong ◽  
X.-Z. You

The reaction of N,N�-dicyanohydrazine with ZnCl2 and NaN3 in water unexpectedly affords 5-aminotetrazolato hydroxo zinc rather than a zinc complex with bis(tetrazolyl)hydrazine. An N–N bond cleavage has occurred in the Demko–Sharpless' tetrazole synthesis.


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