expansion with a heterodyne laser interferometer (laser probe). Demodulation is obtained with specific electronics. The magnitude and phase of the surface vibration are given with a second lock-in amplifier (lock-in amplifier 1) and stored in a microcomputer that also drives the scanning units. With this multi-acquisition microscope, the typical duration of an experiment in order to obtain a set of five low noise images is about 15 minutes. The resolution of the SThEM is given by the size at the photothermal source (radius of the optical beam: 5 /xm here). 4.1. Application to the study of thin films The first example concerns the observation of subsurface thin layers. In order to demonstrate the capacity for subsurface investigation we successively vapour deposited a 200 nm thick SiC>2 and 100 nm thick aluminium layers onto a polycrystalline nickel substrate (Fig. 8a). The bright strip on the right part of the image (Fig. 8b) reveals the presence of the subsurface SiC>2 layer which is optically invisible. This image has been obtained at 220 kHz modulation frequency of the excitation beam. The image contrast corresponds to about 25° phase shift. As the SThEM makes it possible to observe the subsurface we decided to use it for the detection of thin films delamination. We used a 1 /xm thick DLC film deposited on a steel substrate. Several lines of Vickers indentations were performed under an applied load of 4.5N. A different spacing (25 to 140 pim) between indentations has been taken for each line. The SEM and thermoelastic images of the indentations spaced 25 /xm are shown in Fig. 9. Due to the film delamination, an optically invisible bright area between the indentations (Fig. 9a) was observed by the SThEM at 100 kHz operating frequency (Fig. 9b). It is an indication of the excessive heating resulting from the film delamination. The latter is due to the tensile residual stresses which develop around each indentation. The bright area (film delamination) could not be detected both in the case of a single indentation or when the spacing between indentations was higher than 40 /xm. In the latter case

2014 ◽  
pp. 210-212
2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jiaze Yin ◽  
Lu Lan ◽  
Yi Zhang ◽  
Hongli Ni ◽  
Yuying Tan ◽  
...  

AbstractPhotothermal microscopy has enabled highly sensitive label-free imaging of absorbers, from metallic nanoparticles to chemical bonds. Photothermal signals are conventionally detected via modulation of excitation beam and demodulation of probe beam using lock-in amplifier. While convenient, the wealth of thermal dynamics is not revealed. Here, we present a lock-in free, mid-infrared photothermal dynamic imaging (PDI) system by MHz digitization and match filtering at harmonics of modulation frequency. Thermal-dynamic information is acquired at nanosecond resolution within single pulse excitation. Our method not only increases the imaging speed by two orders of magnitude but also obtains four-fold enhancement of signal-to-noise ratio over lock-in counterpart, enabling high-throughput metabolism analysis at single-cell level. Moreover, by harnessing the thermal decay difference between water and biomolecules, water background is effectively separated in mid-infrared PDI of living cells. This ability to nondestructively probe chemically specific photothermal dynamics offers a valuable tool to characterize biological and material specimens.


2021 ◽  
Author(s):  
Jiaze Yin ◽  
Lu Lan ◽  
Yi Zhang ◽  
Hongli Ni ◽  
Yuying Tan ◽  
...  

Abstract Photothermal microscopy has enabled highly sensitive label-free imaging of absorbers, from metallic nanoparticles to chemical bonds. Photothermal signals are conventionally detected via modulation of excitation beam and demodulation of probe beam using lock-in amplifier. While convenient, the wealth of thermal dynamic is not revealed. Here, we present a lock-in free, mid-infrared photothermal dynamic imaging (PDI) system by MHz digitization and match filtering at harmonics of modulation frequency. Thermal-dynamic information is acquired at nanosecond resolution within single pulse excitation. Our method not only increases the imaging speed by two orders of magnitude, but also obtains four-fold enhancement of signal-to-noise ratio over lock-in counterpart, enabling high-throughput metabolism analysis at single-cell level. Moreover, by harnessing the thermal decay difference between water and biomolecules, water background is effectively separated in mid-infrared PDI of living cells. This ability to nondestructively probe chemically specific photothermal dynamics offers a valuable tool to characterize biological and material specimens.


2011 ◽  
Vol 306-307 ◽  
pp. 274-279
Author(s):  
Qing Tao ◽  
Yan Wei Sui ◽  
Sun Zhi ◽  
Wei Song

AlN and TiN thin films are widely used in electronic devices and acoustic material and other fields because of its unique merit, the preparation of nitride thin films by using the arc ion plating has not been a systematic and deep study. The article presents our research procedure which the AlN and TiN thin films are deposited on stainless steel substrate by arc ion plating (AIP). The characteristics of thin films, for example microstructure, morphology, composition analysis and hardness, are examined and analyzed. The results showed that: Droplet-like particles appear in the microstructure of nitride thin films, and the grain size of droplet-like particles in AlN thin films is greater than in TiN thin films. The micro-hardness of nitride films preparation in experiment has improved significantly, and establish firmly basic for extending the application field of nitride film.


2016 ◽  
Vol 23 (1) ◽  
pp. 70-81 ◽  
Author(s):  
Kristian Myhre ◽  
Jonathan Burns ◽  
Harry Meyer ◽  
Nathan Sims ◽  
Rose Boll

2019 ◽  
Vol 11 (14) ◽  
pp. 1682 ◽  
Author(s):  
Torsten Geldsetzer ◽  
Shahid K. Khurshid ◽  
Kerri Warner ◽  
Filipe Botelho ◽  
Dean Flett

RADARSAT Constellation Mission (RCM) compact polarimetry (CP) data were simulated using 504 RADARSAT-2 quad-pol SAR images. These images were used to samples CP data in three RCM modes to build a data set with co-located ocean wind vector observations from in situ buoys on the West and East coasts of Canada. Wind speeds up to 18 m/s were included. CP and linear polarization parameters were related to the C-band model (CMOD) geophysical model functions CMOD-IFR2 and CMOD5n. These were evaluated for their wind retrieval potential in each RCM mode. The CP parameter Conformity was investigated to establish a data-quality threshold (>0.2), to ensure high-quality data for model validation. An accuracy analysis shows that the first Stokes vector (SV0) and the right-transmit vertical-receive backscatter (RV) parameters were as good as the VV backscatter with CMOD inversion. SV0 produced wind speed retrieval accuracies between 2.13 m/s and 2.22 m/s, depending on the RCM mode. The RCM Medium Resolution 50 m mode produced the best results. The Low Resolution 100 m and Low Noise modes provided similar results. The efficacy of SV0 and RV imparts confidence in the continuity of robust wind speed retrieval with RCM CP data. Three image-based case studies illustrate the potential for the application of CP parameters and RCM modes in operational wind retrieval systems. The results of this study provide guidance to direct research objectives once RCM is launched. The results also provide guidance for operational RCM data implementation in Canada’s National SAR winds system, which provides near-real-time wind speed estimates to operational marine forecasters and meteorologists within Environment and Climate Change Canada.


2008 ◽  
Vol 23 (6) ◽  
pp. 1604-1613 ◽  
Author(s):  
M.J. Cordill ◽  
N.R. Moody ◽  
W.W. Gerberich

Dynamic indentation techniques are often used to determine mechanical properties as a function of depth by continuously measuring the stiffness of a material. The dynamics are used by superimposing an oscillation on top of the monotonic loading. Of interest was how the oscillation affects the measured mechanical properties when compared to a quasi-static indent run at the same loading conditions as a dynamic. Single crystals of nickel and NaCl as well as a polycrystalline nickel sample and amorphous fused quartz and polycarbonate have all been studied. With respect to dynamic oscillations, the result is a decrease of the load at the same displacement and thus lower measured hardness values of the ductile crystalline materials. It has also been found that the first 100 nm of displacement are the most affected by the oscillating tip, an important length scale for testing thin films, nanopillars, and nanoparticles.


2021 ◽  
Vol 1 (12 (109)) ◽  
pp. 22-28
Author(s):  
Aladin Eko Purkuncoro ◽  
Rudy Soenoko ◽  
Dionysius Joseph Djoko Herry Santjojo ◽  
Yudy Surya Irawan

Carbon thin films on SKD11 steel were deposited by 40 kHz frequency plasma sputtering technique using a waste of battery carbon rods in argon plasma, and their mechanical properties were investigated by various target-substrate distances (1 cm, 1.7 cm, 2 cm, and 2.4 cm). The power used is 340 watts, the vacuum time is 90 minutes, and the gas flow rate is 80 ml/minute. The deposition time of carbon in plasma sputtering is 120 minutes with the initial temperature (temperature during vacuum) of 28 oC and the final temperature (the temperature after plasma sputtering) is 300 oC. The hardness value of SKD11 steel deposited with carbon thin films on SKD11 with target-substrate distance was tested using the Vickers microhardness test. Testing the thickness of the carbon thin films on the SKD11 steel substrate was carried out using a Nikon type 59520 optical microscope. Qualitative analysis of the thickness of the carbon thin films on the SKD11 steel substrate at a scale of 20 μm is shown by an optical microscope. Qualitatively, the thin film at a distance of 1.7 cm looks the brightest and thickest than other distance variations. Based on the Vickers microhardness test and Nikon type 59520 optical microscope, at the distance of 1 cm to 1.7 cm, the average thickness and hardness increased from 10,724 μm (286.6 HV) to 13,332 μm (335.9 HV). Furthermore, at the variation of the distance from 1.7 cm to 2.4 cm, the average thickness and hardness continued to decrease from 13.332 μm (335.9 HV) to 7.257 μm (257.3 HV). The possibility of interrupting atoms colliding with argon atoms in inert conditions increases at a long distance, thus causing the deposition flux on the SKD11 steel substrate to decrease


1974 ◽  
Vol 20 (8) ◽  
pp. 1009-1012 ◽  
Author(s):  
Robert L Berger ◽  
Walter S Friauf ◽  
Horace E Cascio

Abstract A precision thermistor bridge and thermistor is described for use in a thermal titration calorimeter or a high-speed stopped- or continuous-flow calorimeter of the Roughton type. These are compared and evaluated with regard to several other types of detectors, including the platinum resistance thermometer, thermocouple, transistor thermometer, and capacitance thermometers. At this time the best detection for our purpose seems to be a specially constructed 20-100 kΩ thermistor used in conjunction with a new ac lock-in amplifier bridge. The sensitivity of the system is equivalent to a peak-to-peak noise of 25 x 10-6 °C, with a 100-ms time constant and 1 µW power dissipation in the thermistor. Long-term drift of the bridge, without an oven, was 1 x 10-6 °C/min.


1995 ◽  
Vol 49 (6) ◽  
pp. 819-824 ◽  
Author(s):  
Jun Shen ◽  
Andreas Mandelis ◽  
Andreas Othonos ◽  
Joseph Vanniasinkam

The recently developed photothermal technique of quadrature photopyroelectric spectroscopy (Q-PPES) has been applied to measurements of amorphous Si thin films deposited on crystalline Si substrates. Direct, meaningful comparisons have been made between purely optical transmission in-phase (IP-PPES) spectra, and purely thermal-wave sub-gap spectra with the use of a novel noncontacting PPES instrument to record lock-in in-phase and quadrature spectra, respectively. FT-IR transmission spectra have also been obtained for a comparison with this IP-PPES optical method. The results of the present work showed that the FT-IR method performs the worst in terms of spectral resolution of thin films and sub-bandgap defect/impurity absorptions inherent in the Si wafer substrate. The optical IP-PPES channel, however, albeit more sensitive than the FT-IR technique, fails to resolve spectra from surface films thinner than 2100 Å, but is sensitive to sub-bandgap absorptions. The thermal-wave Q-PPES channel is capable of resolving thin-film spectra well below 500 Å thick and exhibits strong signal levels from the crystalline Si sub-bandgap absorptions. Depending on the surface thin-film orientation toward, or away from, the direction of the incident radiation, the estimated minimum mean film thickness resolvable spectroscopically by Q-PPES is either 40 Å or 100 Å, respectively.


Author(s):  
Abhishek Nirjar ◽  
Andrew Tylecote

Small and medium enterprises in the Indian software development industry, like their larger counterparts, are mostly low on the value ladder. This chapter examines the difficulties confronting them in moving up the ladder, and the strategies and circumstances conducive to success, drawing on three case studies. Human resource development emerges as central. Though SMEs have meager resources for moving up, compared to large firms, they have a greater incentive to do so—and this organizational interest accords with the interests and motivations of their employees for career development. It is found that the keys to success are to treat employees as co-investors in their own human capital, to form an effective “community of practice” across the firm, and to find market opportunities which “stretch” the firm in the right direction and to the right extent. For the last of these the main contribution is made by existing clients, but an important role may be played by venture capitalists, particularly those which are U.S.-based.


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