Effect of Graphene Nanosheets (GNS) and Graphite Nanoplatelets (GNP) on the Mechanical Properties of Epoxy Nanocomposites

2013 ◽  
Vol 5 (3) ◽  
pp. 260-266 ◽  
Author(s):  
M. M. Shokrieh ◽  
M. Esmkhani ◽  
H. R. Shahverdi ◽  
F. Vahedi
Keyword(s):  
Mechanical Properties ◽  
Graphene Nanosheets ◽  
Graphite Nanoplatelets ◽  
Epoxy Nanocomposites

Moisture Effect on Mechanical Properties of Graphene/Epoxy Nanocomposites

2016 ◽  
Vol 32 (6) ◽  
pp. 673-682 ◽  
Author(s):  
H.-K. Liu ◽  
Y.-C. Wang ◽  
T.-H. Huang
Keyword(s):  
Mechanical Properties ◽  
Graphene Oxide ◽  
Moisture Absorption ◽  
Graphene Nanosheets ◽  
Salt Water ◽  
Testing Machine ◽  
Weight Fraction ◽  
Epoxy Nanocomposites ◽  
Moisture Effect ◽  
Superior Mechanical Properties

Abstract2-D graphene nanosheets (GNS) not only have superior mechanical properties, but stacking of GNS in composites is expected to inhibit moisture absorption. In this paper, moisture effect on tensile strength of graphene/epoxy nanocomposites is investigated. Two kinds of graphene reinforcements are used including graphene oxide (GO) and reduced graphene oxide (RGO) with reinforcement weight fraction WGO or WRGO in the range of 0.5 to 3.0wt%. A dispersion agent acetone is added in nanocomposites to enhance graphene dispersion. To evaluate moisture influence, those nanocomposites are soaked in two kinds of liquid including deionized water (DIW) and salt water (saline solution) for seven kinds of soaking periods of time including 24, 48, 72, 100, 400 hours, 30 days, and 60 days. After soaking test, diffusion coefficients of various composites are evaluated; besides tensile strengths of composites are measured by microforce testing machine. In order to correlate the strength with microstructure evolution, several techniques are adopted to analyze morphologies and functionalities of reinforcements and fracture surface of composites. They include Raman spectroscope, X-ray photoelectron spectroscope, and SEM. 2-D GNS are found to effectively enhance nanocomposites by moisture attack, and their corresponding reinforcing mechanisms are proposed.

Enhanced mechanical properties of ammonia-modified graphene nanosheets/epoxy nanocomposites

RSC Advances ◽  
2015 ◽  
Vol 5 (36) ◽  
pp. 28098-28104 ◽  
Author(s):  
Dong-Dong Zhang ◽  
Dong-Lin Zhao ◽  
Ran-Ran Yao ◽  
Wei-Gang Xie
Keyword(s):  
Mechanical Properties ◽  
Epoxy Matrix ◽  
Graphene Nanosheets ◽  
Amine Functionalization ◽  
Epoxy Nanocomposites ◽  
Obvious Effect ◽  
Mechanical Performances ◽  
Modified Graphene ◽  
Matrix Nanocomposites

The amine-functionalization of GNSs with ammonia had an obvious effect on the mechanical performances of epoxy matrix nanocomposites.

Effect of Graphene Structure on Mechanical Properties of Graphene/Epoxy Nanocomposites

2013 ◽  
Vol 873 ◽  
pp. 496-502 ◽  
Author(s):  
Dong Dong Zhang ◽  
Dong Lin Zhao ◽  
Bin He
Keyword(s):  
Mechanical Properties ◽  
Functional Group ◽  
Graphene Nanosheets ◽  
Rapid Expansion ◽  
Surface Functional Group ◽  
Sonication Time ◽  
Epoxy Nanocomposites ◽  
Natural Graphite ◽  
Molding Method ◽  
Layer Stacking

Graphene nanosheets (GNSs) were mass-produced from flake natural graphite by oxidation, rapid expansion and ultrasonic treatment. The effects of ultrasonic times on the morphology and structure of GNSs and mechanical properties of GNS/epoxy nanocomposites were systematically investigated. GNS/epoxy nanocomposites were fabricated by ultrasonication and cast molding method. The mechanical properties of GNS/epoxy nanocomposites were influenced by the specific surface area, layer stacking and oxygen-containing functional group contents of GNSs. GNSs had excellent exfoliation degree when the sonication time was 15 h and there were some slightly changes on surface functional group comparing with 0 h sonication graphene and 5 h sonication graphene. When the sonication time was 15 h, the tensile strength and flexural strength of GNS/epoxy nanocomposites reached the highest value of 60.9 MPa and 91.33 MPa, which were increased by 25.3% and 30.94%, respectively, compared with pristine epoxy. The stress-strain curves of tensile testing demonstrated that extending the sonication time of GNSs can increased the fracture toughness of GNS/epoxy nanocomposites.

scholarly journals Mechanical Properties of Hybrid Graphene Nanoplatelet-Nanosilica Filled Unidirectional Basalt Fibre Composites

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1468
Author(s):  
Ummu Raihanah Hashim ◽  
Aidah Jumahat ◽  
Mohammad Jawaid
Keyword(s):  
Mechanical Properties ◽  
Polymer Composites ◽  
Glass Fibre ◽  
Graphene Nanosheets ◽  
High Surface ◽  
High Surface Area ◽  
High Strength ◽  
Basalt Fibre ◽  
Graphene Nanoplatelet ◽  
Dispersion State

Basalt fibre (BF) is one of the most promising reinforcing natural materials for polymer composites that could replace the usage of glass fibre due to its comparable properties. The aim of adding nanofiller in polymer composites is to enhance the mechanical properties of the composites. In theory, the incorporation of high strength and stiffness nanofiller, namely graphene nanoplatelet (GNP), could create superior composite properties. However, the main challenges of incorporating this nanofiller are its poor dispersion state and aggregation in epoxy due to its high surface area and strong Van der Waals forces in between graphene sheets. In this study, we used one of the effective methods of functionalization to improve graphene’s dispersion and also introducing nanosilica filler to enhance platelets shear mechanism. The high dispersive silica nanospheres were introduced in the tactoids morphology of stacked graphene nanosheets in order to produce high shear forces during milling and exfoliate the GNP. The hybrid nanofiller modified epoxy polymers were impregnated into BF to evaluate the mechanical properties of the basalt fibre reinforced polymeric (BFRP) system under tensile, compression, flexural, and drop-weight impact tests. In response to the synergistic effect of zero-dimensional nanosilica and two-dimensional graphene nanoplatelets enhanced the mechanical properties of BFRP, especially in Basalt fibre + 0.2 wt% GNP/15 wt% NS (BF-H0.2) with the highest increment in modulus and strength to compare with unmodified BF. These findings also revealed that the incorporation of hybrid nanofiller contributed to the improvement in the mechanical properties of the composite. BF has huge potential as an alternative to the synthetic glass fibre for the fabrication of mechanical components and structures.

Effects of ionic liquid types on the tribological, mechanical, and thermal properties of ionic liquid modified graphene/polyimide shape memory composites

2021 ◽  
pp. 095400832199676
Author(s):  
Yuting Ouyang ◽  
Qiu Zhang ◽  
Xiukun Liu ◽  
Ruan Hong ◽  
Xu Xu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Ionic Liquid ◽  
Composite Materials ◽  
Shape Memory ◽  
Recovery Rate ◽  
Shape Recovery ◽  
Graphene Nanosheets ◽  
Mechanical And Thermal Properties ◽  
Thermal And Mechanical Properties ◽  
Modified Graphene

Different ionic liquid modified graphene nanosheets (IG) were induced into polyimide (PI) to improve the tribological, thermal, and mechanical properties of shape memory IG/PI composites. The results demonstrated that when using 1-aminoethyl-3-methylimidazole bromide to modify graphene nanosheets (IG-1), the laser-driven shape recovery rate of IG-1/PI composites (IGPI-1) reached 73.02%, which was 49.36% higher than that of pure PI. In addition, the IGPI-1 composite materials reached the maximum shape recovery rate within 15 s. Additionally, under dry sliding, the addition of IG can significantly improve the tribological properties of composite materials. IGPI-1 exhibited the best self-lubricating properties. Compared with pure PI, the friction coefficient (0.19) and wear rate (2.62 × 10–5) mm3/Nm) were reduced by 44.1% and 24.2%, respectively, and the T10% of IGPI-1 increased by 32.2°C. The Tg of IGPI-1 reached 256.5°C, which was 8.4°C higher than that of pure PI. In addition, the tensile strength and modulus of IGPI-1 reached 82.3 MPa and 1.18 GPa, which were significantly increased by 33.6% and 29.8%, respectively, compared with pure PI. We hope that this work will be helpful for the preparation of shape memory materials with excellent tribological, thermal, and mechanical properties.

Experimental study on mechanical properties of polypropylene nanocomposites reinforced with a hybrid graphene/PP-g-MA/kenaf fiber by response surface methodology

2021 ◽  
pp. 009524432110153
Author(s):  
Jaber Mirzaei ◽  
Abdolhossein Fereidoon ◽  
Ahmad Ghasemi-Ghalebahman
Keyword(s):  
Mechanical Properties ◽  
Response Surface Methodology ◽  
Elastic Modulus ◽  
Response Surface ◽  
Graphene Nanosheets ◽  
Hot Press ◽  
Kenaf Fiber ◽  
Polypropylene Nanocomposites ◽  
Kenaf Fibers ◽  
Internal Mixer

In this study, the mechanical properties of polypropylene (PP)-based nanocomposites reinforced with graphene nanosheets, kenaf fiber, and polypropylene-grafted maleic anhydride (PP-g-MA) were investigated. Response surface methodology (RSM) based on Box–Behnken design (BBD) was used as the experimental design. The blends fabricated in three levels of parameters include 0, 0.75, and 1.5 wt% graphene nanosheets, 0, 7.5, and 15 wt% kenaf fiber, and 0, 3, and 6 wt% PP-g-MA, prepared by an internal mixer and a hot press machine. The fiber length was 5 mm and was being constant for all samples. Tensile, flexural, and impact tests were conducted to determine the blend properties. The purpose of this research is to achieve the highest mechanical properties of the considered nanocomposite blend. The addition of graphene nanosheets to 1 wt% increased the tensile, flexural, and impact strengths by 16%, 24%, and 19%, respectively, and an addition up to 1.5 wt% reduced them. With further addition of graphene nanosheets until 1.5 wt%, the elastic modulus was increased by 70%. Adding the kenaf fiber up to 15 wt% increased the elastic modulus, tensile, flexural, and impact strength by 24%, 84%, 18%, and 11%, respectively. The addition of PP-g-MA has increased the adhesion, dispersion and compatibility of graphene nanosheets and kenaf fibers with matrix. With 6 wt% PP-g-MA, the tensile strength and elastic modulus were increased by 18% and 75%, respectively. The addition of PP-g-MA to 5 wt% increased the flexural and impact strengths by 10% and 5%, respectively. From the entire experimental data, the optimum values for elastic modulus, as well as, tensile, flexural, and impact strengths in the blends were obtained to be 4 GPa, 33.7896 MPa, 57.6306 MPa, and 100.1421 J/m, respectively. Finally, samples were studied by FE-SEM to check the dispersion of graphene nanosheets, PP-g-MA and kenaf fibers in the polymeric matrix.

Mechanical properties and toughening mechanisms of epoxy/graphene nanocomposites

2015 ◽  
Vol 35 (3) ◽  
pp. 257-266 ◽  
Author(s):  
Rahim Eqra ◽  
Kamal Janghorban ◽  
Habib Daneshmanesh
Keyword(s):  
Mechanical Properties ◽  
Fracture Surface ◽  
Flexural Strength ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Graphene Nanosheets ◽  
Flexural Modulus ◽  
Mechanical Tests ◽  
Toughening Mechanism ◽  
Graphene Nanocomposites

Abstract Because of extraordinary physical, chemical and mechanical properties, graphene nanosheets (GNS) are suitable fillers for optimizing the properties of different polymers. In this research, the effect of GNS content (up to 1 wt.%) on tensile and flexural properties, morphology of fracture surface, and toughening mechanism of epoxy were investigated. Results of mechanical tests showed a peak for tensile and flexural strength of samples with 0.1 wt.% GNS such that the tensile and flexural strength improved by 13% and 3.3%, respectively. The Young’s modulus and flexural modulus increased linearly with GNS content, although the behavior of the Young’s modulus was more remarkable. Morphological investigations confirmed this behavior because the GNS dispersion in the epoxy matrix was uniform at lower contents and agglomerated at higher contents. Finally, microscopical observation showed that the major toughening mechanism of graphene-epoxy nanocomposites was crack path deflection, which changed the mirror fracture surface of the pure epoxy to rough surface.

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